In situ measurements of the orthorhombic-to-trigonal transition inBaSi2sunder high-pressure and high-temperature conditions

1997 ◽  
Vol 55 (1) ◽  
pp. 132-135 ◽  
Author(s):  
Motoharu Imai ◽  
Toshiyuki Hirano ◽  
Takumi Kikegawa ◽  
Osamu Shimomura
1998 ◽  
Vol 278-281 ◽  
pp. 612-617 ◽  
Author(s):  
Bogdan F. Palosz ◽  
Svetlana Stelmakh ◽  
Stanislaw Gierlotka ◽  
M. Aloszyna ◽  
Roman Pielaszek ◽  
...  

2004 ◽  
Vol 59 (2) ◽  
pp. 202-215 ◽  
Author(s):  
Holger Emme ◽  
Tanja Nikelski ◽  
Thomas Schleid ◽  
Rainer Pöttgen ◽  
Manfred Heinrich Möller ◽  
...  

The new orthorhombic meta-oxoborates RE(BO2)3 (≡REB3O6) (RE = Dy-Lu) have been synthesized under high-pressure and high-temperature conditions in a Walker-type multianvil apparatus at 7.5 GPa and 1100 °C. They are isotypic to the known ambient pressure phase Tb(BO2)3, space group Pnma. In contrast to Dy(BO2)3, which was also obtained in small amounts under high-temperature conditions, the preparation of the higher orthorhombic homologues RE(BO2)3 (RE = Ho-Lu) was only possible using high-pressure. The meta-oxoborates RE(BO2)3 (RE = Dy-Er) were synthesized as pure products, whereas the orthorhombic phases with RE = Tm-Lu were only obtained as byproducts. With the exception of Yb(BO2)3 it was possible to establish single crystal data for all compounds. The results of temperature-resolved in-situ powder-diffraction measurements, DTA, IR-spectroscopic investigations, and magnetic properties are also presented.


2002 ◽  
Vol 116 (5) ◽  
pp. 2166-2174 ◽  
Author(s):  
A. V. Talyzin ◽  
L. S. Dubrovinsky ◽  
T. Le Bihan ◽  
U. Jansson

1998 ◽  
Vol 69 (7) ◽  
pp. 2720-2724 ◽  
Author(s):  
Yoshihisa Suzuki ◽  
Tsutomu Sawada ◽  
Satoru Miyashita ◽  
Hiroshi Komatsu

2012 ◽  
Vol 66 (2) ◽  
pp. 233-236 ◽  
Author(s):  
Erwei Qiao ◽  
Haifei Zheng ◽  
Changxing Long

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