Monoclinic structure and nonstoichiometry of `KAlSiO4-O1'
2013 ◽
Vol 69
(4)
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pp. 334-336
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Keyword(s):
X Ray
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Crystals of KAlSiO4-O1(potassium aluminium silicate) were synthesized using a flux method and analysed utilizing single-crystal X-ray diffraction and electron microprobe analysis. Both methods confirm that the crystals are nonstoichiometric according to K1−xAl1−xSi1+xO4withx= 0.04 (1). KAlSiO4-O1is closely related to the stuffed derivatives of tridymite, although the topology of the Si/Al-ordered framework is different. Six-membered rings of UUDDUD and UUUDDD (U = up and D = down; ratio 2:1) configurations are present in layers parallel to theabplane. In contrast, the framework of tridymite exhibits UDUDUD rings. The crystals are affected by inversion, pseudo-orthorhombic and pseudo-hexagonal twinning.
2006 ◽
Vol 632
(8-9)
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pp. 1496-1500
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Keyword(s):
2009 ◽
Vol 44
(4)
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pp. 581-587
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1983 ◽
Vol 47
(343)
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pp. 219-220
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Keyword(s):
1976 ◽
Vol 35
(1)
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pp. 10-16
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Keyword(s):
Keyword(s):
1985 ◽
Vol 49
(350)
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pp. 103-105
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