trans-Dichlorobis[tris(4-fluorophenyl)phosphine]palladium(II) toluene solvate
2006 ◽
Vol 62
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pp. m894-m896
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The title compound, trans-[PdCl2{P(C6H4F)3}2]·C7H8, where P(C6H4F)3 is tris(4-fluorophenyl)phosphine, crystallizes with both molecules in special positions. The trans-[PdCl2{P(C6H4F)3}2] molecule lies on an inversion centre, resulting in a distorted trans square-planar geometry. The Pd—P and Pd—Cl distances are 2.3398 (12) and 2.2955 (13) Å, respectively, and the P—Pd—Cl angle is 87.58 (5)°. The effective cone angle for the tris(4-fluorophenyl)phosphine group was calculated to be 152°. The toluene molecule lies on a twofold rotation axis.
2006 ◽
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2006 ◽
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2007 ◽
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2012 ◽
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2007 ◽
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