trans-Dichlorobis(tri-m-tolylphosphine)palladium(II)

2006 ◽  
Vol 62 (7) ◽  
pp. m1603-m1605 ◽  
Author(s):  
Reinout Meijboom ◽  
Alfred Muller ◽  
Andreas Roodt
Keyword(s):  
Title Compound ◽  
Cone Angle ◽  
Geometric Parameters ◽  
Planar Geometry ◽  
Square Planar ◽  
Effective Cone

In the title compound, trans-[PdCl2{P(C7H7)3}2], where P(C7H7)3 is tri-m-tolylphosphine, the Pd atom is on an inversion centre, resulting in a trans-square-planar geometry. Selected geometric parameters are Pd—P and Pd—Cl distances of 2.3289 (4) and 2.2897 (4) Å, respectively, and a P—Pd—Cl angle of 87.77 (2)°. The effective cone angle for the tri-m-tolylphosphine is calculated to be 165°.

trans-Dichlorobis[tris(4-fluorophenyl)phosphine]palladium(II) toluene solvate

2006 ◽  
Vol 62 (4) ◽  
pp. m894-m896
Author(s):  
Reinout Meijboom ◽  
Alfred Muller ◽  
Andreas Roodt ◽  
J. Marthinus Janse van Rensburg
Keyword(s):  
Title Compound ◽  
Rotation Axis ◽  
Cone Angle ◽  
Planar Geometry ◽  
Toluene Molecule ◽  
Square Planar ◽  
Effective Cone

The title compound, trans-[PdCl2{P(C6H4F)3}2]·C7H8, where P(C6H4F)3 is tris(4-fluorophenyl)phosphine, crystallizes with both molecules in special positions. The trans-[PdCl2{P(C6H4F)3}2] molecule lies on an inversion centre, resulting in a distorted trans square-planar geometry. The Pd—P and Pd—Cl distances are 2.3398 (12) and 2.2955 (13) Å, respectively, and the P—Pd—Cl angle is 87.58 (5)°. The effective cone angle for the tris(4-fluorophenyl)phosphine group was calculated to be 152°. The toluene molecule lies on a twofold rotation axis.

scholarly journals trans-Bis[(2-bromophenyl)diphenylphosphane-κP]carbonylchloridorhodium(I)

2012 ◽  
Vol 68 (4) ◽  
pp. m510-m510
Author(s):  
Frederick P. Malan ◽  
Rehana Malgas-Enus ◽  
Reinout Meijboom
Keyword(s):  
Title Compound ◽  
Geometric Parameters ◽  
Planar Geometry ◽  
Inversion Symmetry ◽  
Square Planar ◽  
Carbonyl Chloride

The title compound,trans-[RhCl(C18H14BrP)2(CO)], has a slightly disordered square-planar geometry with the Rh ionIsituated on an inversion the centre and carbonyl–chloride disorder observed as a result of the crystallographic inversion symmetry. Selected geometric parameters include: Rh—P = 2.3430 (8) Å, Rh—Cl = 2.434 (3) Å, Rh—C = 1.722 (8) Å, P—Rh—P = 180.00 (3)°, P—Rh—Cl = 95.40 (7)°, 84.60 (7)° and Rh—C—O = 177.9 (8)°.

{1-[2-(Methylamino)ethyliminomethyl]naphthalen-2-olato}thiocyanatocopper(II)

2006 ◽  
Vol 62 (7) ◽  
pp. m1533-m1534 ◽  
Author(s):  
Han-Na Hou
Keyword(s):  
Schiff Base ◽  
Schiff Base Ligand ◽  
Title Compound ◽  
Planar Geometry ◽  
Asymmetric Unit ◽  
Thiocyanate Anion ◽  
Square Planar

The title compound, [Cu(C14H15N2O)(NCS)], is a mononuclear copper(II) complex, with two molecules in the asymmetric unit. The CuII ion is coordinated by one O and two N atoms of a Schiff base ligand, and by one N atom of a thiocyanate anion, forming a square-planar geometry.

scholarly journals trans-Dichloridobis[dicyclohexyl(phenyl)phosphane-κP]palladium(II)

2012 ◽  
Vol 68 (4) ◽  
pp. m404-m404 ◽  
Author(s):  
Andrew R. Burgoyne ◽  
Reinout Meijboom ◽  
Hezron Ogutu
Keyword(s):  
Long Range ◽  
Title Compound ◽  
Phenyl Ring ◽  
Planar Geometry ◽  
Dalton Trans ◽  
Bond Lengths ◽  
Monomeric Complex ◽  
Square Planar

The title compound, [PdCl2{P(C6H11)2(C6H5)}2], forms a monomeric complex with atrans-square-planar geometry. The Pd—P bond lengths are 2.3343 (5) Å, as the Pd atom lies on an inversion centre, while the Pd—Cl bond lengths are 2.3017 (4) Å. The observed structure was found to be closely related to [PdCl2{P(C6H11)3}2] [Grushinet al.(1994).Inorg. Chem.33, 4804–4806], [PdBr2{P(C6H11)3}2] [Clarkeet al.(2003).Dalton Trans.pp. 4393–4394] and [PdCl2P(C6H11)2(C7H7)}2] [Vuotiet al.(2008).Eur. J. Inorg. Chem.pp. 397–407] (C6H11is cyclohexyl and C7H7iso-tolyl). One of the cyclohexyl rings is disordered with the phenyl ring in a 0.587 (9):413 (9) ratio. Five long-range C—H...Cl interactions were observed within the structure.

scholarly journals trans-Dichloridobis(4-methoxyaniline-κN)palladium(II)

2009 ◽  
Vol 65 (6) ◽  
pp. m673-m673 ◽  
Author(s):  
Volodimir Bon ◽  
Svitlana Orysyk ◽  
Vasyl Pekhnyo
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonds ◽  
Title Compound ◽  
Planar Geometry ◽  
Coordination Environment ◽  
Square Planar ◽  
A Chain

In the title compound, [PdCl2(C7H9NO)2], the Pd atom is situated on a crystallographic centre of inversion. The coordination environment of the Pd atom shows a slightly distorted square-planar geometry. The crystal structure exhibits weak intermolecular Pd...Cl interactions, with Pd...Cl distances of 3.6912 (6) Å. A chain-like arrangement of molecules realized by intermolecular N—H...Cl hydrogen bonds is observed along [010].

Bis(2-formylphenolato-κ2 O,O′)nickel(II)

2006 ◽  
Vol 62 (5) ◽  
pp. m1038-m1039 ◽  
Author(s):  
Yan-Guo Li ◽  
Hong-Ji Chen
Keyword(s):  
Title Compound ◽  
Planar Geometry ◽  
Nitrate Hexahydrate ◽  
Square Planar ◽  
Mononuclear Structure

The title compound, [Ni(C7H5O2)2], exhibits a mononuclear structure in which the central NiII atom is located on an inversion centre and is coordinated by four O atoms from two salicylaldehyde ligands in a distorted square-planar geometry. The complex was obtained by the reaction of salicylaldehyde and nickel(II) nitrate hexahydrate in ethanol, using 3-amino-1,2-propanediol as a growth-directing reagent.

{2,4-Dibromo-6-[2-(dimethylamino)ethyliminomethyl]phenolato}thiocyanatonickel(II)

2006 ◽  
Vol 62 (5) ◽  
pp. m1130-m1131 ◽  
Author(s):  
Xin-Zhi Sun ◽  
Jin-Sheng Shi
Keyword(s):  
Title Compound ◽  
Tridentate Ligand ◽  
Planar Geometry ◽  
Thiocyanate Anion ◽  
Square Planar

The title compound, [Ni(C11H13Br2N2O)(NCS)], is a mononuclear nickel(II) compound. The square-planar geometry of the NiII atom is provided by one O and two N atoms of the tridentate ligand and one N atom of the thiocyanate anion.

Chloro(triphenylphosphine)(tropolonato)palladium(II)

2006 ◽  
Vol 62 (5) ◽  
pp. m974-m976 ◽  
Author(s):  
Gideon Steyl
Keyword(s):  
Title Compound ◽  
Interplanar Distance ◽  
Planar Geometry ◽  
Metal Centre ◽  
Stacking Interaction ◽  
Π Stacking ◽  
Square Planar ◽  
Π Stacking Interaction ◽  
New Type

The title compound, [Pd(C7H5O2)Cl(C18H15P)], is a new type of α-diketone palladium(II) complex containing a tertiary arylphosphine. It crystallizes with a distorted square-planar geometry about the palladium(II) metal centre. The most important bond distances and angles include Pd—O (trans P) = 2.0481 (12) Å, Pd—O (trans Cl) = 2.0016 (12) Å, Pd—P = 2.2268 (4) Å, Pd—Cl = 2.2770 (5) Å, O—Pd—O = 80.22 (5)° and O—C—C—O = 3.7 (2)°. A π–π stacking interaction is observed between neighbouring tropolonate groups, with an interplanar distance of 3.377 (6) Å.

catena-Poly[[bis(4-methoxybenzoato)copper(II)]-μ-1,1′-(oxydiethylene)diimidazole-κ2 N 3:N 3′]

2007 ◽  
Vol 63 (11) ◽  
pp. m2866-m2866
Author(s):  
Guo-Hua Wei ◽  
Lai-Ping Zhang ◽  
Ji-Cheng Ma ◽  
Jin Yang
Keyword(s):  
Title Compound ◽  
Chain Structure ◽  
Infinite Chain ◽  
Planar Geometry ◽  
Terminal Ligand ◽  
Square Planar

In the title compound, [Cu(C7H4O3)2(C10H14N4O)] n , the CuII atom lies on a centre of symmetry and is four-coordinated by two N atoms from two 1,1′-(oxydiethylene)diimidazole (BIE) ligands and two O atoms from two 4-methoxybenzoate anions in a square-planar geometry. Each BIE ligand links two CuII atoms to form an infinite chain structure along the c axis. The 4-methoxybenzoate anion, as a terminal ligand, attaches to both sides of the BIE–CuII chains.

scholarly journals (Acetylacetonato-κ2O,O′)carbonyl[tris(4-chlorophenyl)phosphane-κP]rhodium(I)

2012 ◽  
Vol 68 (4) ◽  
pp. m509-m509
Author(s):  
Nathan C. Antonels ◽  
Reinout Meijboom
Keyword(s):  
Steric Hindrance ◽  
Title Compound ◽  
Chelate Ring ◽  
Planar Geometry ◽  
Square Planar

The title compound, [Rh(C5H7O2)(C18H12Cl3P)(CO)], contains the bidentate acetylacetonate ligand coordinated to the RhIatom, forming a chelate ring [Rh—O = 2.0327 (15) and 2.0613 (14) Å]. The RhIatom is additionally coordinated by one P [Rh—P = 2.2281 (6) Å] and one carbonyl C [Rh—C = 1.812 (2) Å] atom, resulting in a slightly distorted square-planar geometry. The molecules are packed to minimize steric hindrance with the phosphanes positioned above and below the slightly distorted square geometrical plane.

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