1,1′-Bis(diphenylphosphino)cobaltocenium tetrafluoridoborate
2007 ◽
Vol 63
(11)
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pp. m2730-m2730
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The title compound, [Co(C17H14P)2]BF4, was obtained by the anion exchange of 1,1′-bis(diphenylphosphino)cobaltocenium chloride with sodium tetrafluoroborate. Both the cation and anion lie on crystallographic twofold axes which run through the CoIII ion, and both the B atom and one F atom of the anion, respectively. Three of the F atoms of the BF4 − anion are disordered equally over two sites. The two diphenylphosphine ligands are trans to each other with respect to the CoIII ion. The crystal structure contains weak C—H...F interactions.
1997 ◽
Vol 212
(3)
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2006 ◽
Vol 61
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pp. 979-982
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Keyword(s):
2015 ◽
Vol 71
(12)
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pp. o917-o918
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2012 ◽
Vol 68
(6)
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pp. m745-m745
2012 ◽
Vol 68
(6)
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pp. o1857-o1857
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Keyword(s):
2007 ◽
Vol 63
(11)
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pp. o4278-o4278
Keyword(s):