[5,10,15,20-Tetrakis(2,6-dimethoxyphenyl)porphyrinato]nickel(II)–toluene–dichloromethane (3/2/4):a mixed solvate
2007 ◽
Vol 63
(11)
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pp. m2824-m2824
The crystal structure, electronic spectroscopy, and 1H NMR data for the title compound, [Ni(C52H44N4O8)]·0.67C7H8·1.33CH2Cl2, are reported. The compound was prepared by the reaction of nickel(II) acetate with the ligand in refluxing glacial acetic acid. The asymmetric unit consists of 1.5 nickel porphyrins, two dichloromethane molecules and one toluene molecule. One of the nickel–porphyrinate molecules is located on an inversion center and is planar in the solid state, while the other assumes a saddle-shaped geometry. In both cases, the nickel ion is four-coordinate.
2016 ◽
Vol 72
(5)
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pp. 760-763
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2018 ◽
Vol 74
(2)
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pp. 201-205
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2006 ◽
Vol 61
(10-11)
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pp. 588-594
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2019 ◽
Vol 75
(11)
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pp. 1808-1811
2013 ◽
Vol 69
(2)
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pp. m86-m86
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2015 ◽
Vol 71
(5)
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pp. 463-465
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2014 ◽
Vol 70
(11)
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pp. 424-426
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2014 ◽
Vol 70
(10)
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pp. o1133-o1134
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