scholarly journals Dichlorido(pyridine-κN)[2-(pyridinium-1-yl)acetato-κO]zinc(II)

2012 ◽  
Vol 68 (4) ◽  
pp. m485-m485
Author(s):  
Zhang Qun ◽  
Chen Jin-Xiang
Keyword(s):  
Title Complex ◽  
Carboxylate Ligand ◽  
Coordination Geometry ◽  
Tetrahedral Coordination ◽  
Pyridine Ligand ◽  
Cl Atoms ◽  
Distorted Tetrahedral Coordination

In the title complex, [ZnCl2(C5H5N)(C7H7NO2)], the ZnIIatom adopts a distorted tetrahedral coordination geometry [the smallest angle being 105.22 (15)° and the widest angle being 115.60 (16)°] that is formed from one monodentate carboxylate ligand, one pyridine ligand and two Cl atoms.

scholarly journals Bis[μ-1,3-bis(1H-imidazol-1-yl)propane-κ2N3:N3′]bis(dichloridozinc) dihydrate

2014 ◽  
Vol 70 (5) ◽  
pp. m184-m184
Author(s):  
Xiao-Juan Wang ◽  
Yun-Long Feng
Keyword(s):  
Zinc Complex ◽  
Complex Molecule ◽  
Dimensional Structure ◽  
Water Molecules ◽  
Coordination Geometry ◽  
Tetrahedral Coordination ◽  
Lattice Water ◽  
Bridging Ligand ◽  
Cl Atoms ◽  
Distorted Tetrahedral Coordination

The title hydrated complex, [Zn2Cl4(C9H12N4)2]·2H2O, is a discrete dinuclear zinc complex with 1,3-bis(1H-imidazol-1-yl)propane as the bridging ligand. The complex molecule lies about a crystallographic inversion centre. The ZnIIatom exhibits a distorted tetrahedral coordination geometry defined by two imidazole N atoms and two Cl atoms. O—H...Cl hydrogen bonding between the lattice water molecules and the terminal Cl atoms of the molecule lead to a two-dimensional structure extending parallel to (100).

Redetermination of [bis(2-pyridyl)amine-N,N′]copper(II) diperchlorate

2000 ◽  
Vol 57 (1) ◽  
pp. m25-m27 ◽  
Author(s):  
Miao Du ◽  
Xian-He Bu ◽  
Lin-Hong Weng ◽  
Xue-Bing Leng ◽  
Ya-Mei Guo
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonds ◽  
Coordination Sphere ◽  
Chain Structure ◽  
Title Complex ◽  
Coordination Geometry ◽  
Tetrahedral Coordination ◽  
A Chain ◽  
Distorted Tetrahedral Coordination ◽  
Close Contacts

In the crystal structure of the title complex, [Cu(C10H9N3)2](ClO4)2, the CuIIcenter is four-coordinated by the nitrogen donors of the pyridine rings of the ligand, bis(2-pyridyl)amine. The crystal structure reveals that the CuN4coordination sphere has a distorted tetrahedral coordination geometry with a crystallographicC2axis through the CuIIcenter. The perchlorate anions link the complex cations to form a chain structure through C—H...O close contacts and N—H...O hydrogen bonds.

scholarly journals Crystal structure of bis[μ-bis(diphenylphosphanyl)methane-κ2P:P′]-μ-chlorido-chlorido-1κCl-(1-phenylthiourea-2κS)disilver acetonitrile hemisolvate

2015 ◽  
Vol 71 (6) ◽  
pp. m133-m134 ◽  
Author(s):  
Arunpatcha Nimthong-Roldán ◽  
Janejira Ratthiwal ◽  
Yupa Wattanakanjana
Keyword(s):  
Hydrogen Bonds ◽  
Chloride Ion ◽  
Title Complex ◽  
Coordination Geometry ◽  
Supramolecular Architecture ◽  
Tetrahedral Coordination ◽  
Complex Molecules ◽  
Close Proximity ◽  
Crystal Complex ◽  
Distorted Tetrahedral Coordination

In the dinuclear title complex, [Ag2Cl2(C7H8N2S)(C25H22P2)2]·0.5CH3CN, each AgIion displays a distorted tetrahedral coordination geometry with two P atoms from two bis(diphenylphosphanyl)methane (dppm) ligands, one bridging chloride ion, one terminal chloride ion and one terminal S atom from theN,N′-phenylthiourea (ptu) ligand. The dppm ligands and the bridging chloride ion force the two Ag atoms into close proximity, with a short Ag...Ag separation of 3.2064 (2) Å. In the crystal, complex molecules are linked by N—H...Cl hydrogen bonds forming a dimer. The dimers are linkedviaweak C— H...Cl hydrogen bonds forming a two-dimensional supramolecular architecture in theyzplane. In addition, an intramolecular N—H...Cl hydrogen bond is observed.

scholarly journals Bis{3,5-di-tert-butyl-N-[(4-dimethylamino)phenyl]salicylaldiminato}cobalt(II)

IUCrData ◽  
2017 ◽  
Vol 2 (4) ◽  
Author(s):  
C. Vidya Rani ◽  
L. Mitu ◽  
G. Chakkaravarthi ◽  
G. Rajagopal
Keyword(s):  
Hydrogen Bonds ◽  
Molecular Conformation ◽  
Title Complex ◽  
Dihedral Angles ◽  
Coordination Geometry ◽  
Minor Components ◽  
Tetrahedral Coordination ◽  
Aromatic Rings ◽  
Complex Molecules ◽  
Distorted Tetrahedral Coordination

In the title complex [systematic name: bis(2,4-di-tert-butyl-6-{N-[4-(dimethylamino)phenyl]carboximidoyl}phenolato)cobalt(II)], [Co(C23H31N2O)2], the cobalt(II) atom is coordinated by pairs of O and N atoms in a distorted tetrahedral coordination geometry. The dihedral angles formed by the aromatic rings of the same ligand are 51.99 (11) and 36.58 (9)°. The molecular conformation features weak intramolecular C—H...O hydrogen bonds. In the crystal, inversion-related pairs of complex molecules are linked into dimers by weak C—H...π interactions. The methyl C atoms oftert-butyl groups have rotational disorder, with site occupancies of 0.647 (7) and 0.617 (6) for the major components and 0.353 (7) and 0.383 (6) for the minor components. One of the methyl C atoms of the dimethylamino groups is also disordered over two orientations, with an occupancy ratio of 0.75 (4):0.25 (4).

scholarly journals Synthesis and Characterisation of Zinc(II) Complex With 2-Amino-5-bromopyridine Ligand

2017 ◽  
Author(s):  
Fitriani
Keyword(s):  
Ir Spectroscopy ◽  
Elemental Analysis ◽  
Coordination Geometry ◽  
Tetrahedral Coordination ◽  
Visible Absorption ◽  
X Ray ◽  
X Ray Crystallography ◽  
Uv Visible ◽  
Cl Atoms ◽  
Distorted Tetrahedral Coordination

The synthesis and characterisation of zinc(II) complex with 2-amino-5-bromopyridine (C5H5BrN2) ligand have been described. The complex was structurally characterised via X-ray crystallography, in the title compound, (2-amino-5-bromopyridinium) [ZnCl¬3(2-amino-5-bromopyridine)] or which is also called (C5H6BrN2) [ZnCl3(C5H5BrN2)]¬. The Zn(II) atom is four-coordinated by three Cl atoms and one imine N-atom of 2-amino-5-bromopyridine ligand, forming a distorted tetrahedral coordination geometry. The complex was also investigated by elemental analysis, 1H NMR, IR spectroscopy and UV-Visible absorption. The protonation behaviour upon coordination is discussed.

scholarly journals Crystal structure of (benzenecarbothioamide-κS)chloridobis(triphenylphosphane-κP)silver(I)

2014 ◽  
Vol 70 (9) ◽  
pp. m310-m311 ◽  
Author(s):  
Wattana Ruangwut ◽  
Chaveng Pakawatchai
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bond ◽  
Hydrogen Bonds ◽  
Chloride Ion ◽  
Mixed Ligand ◽  
Title Complex ◽  
Coordination Geometry ◽  
Tetrahedral Coordination ◽  
Distorted Tetrahedral Coordination

In the mononuclear mixed-ligand title complex, [AgCl(C7H7NS)(C18H15P)2], the AgIion is four coordinated by one S atom of a benzenecarbothioamide ligand, two P atoms of two triphenylphosphane ligands and one chloride ion, displaying a distorted tetrahedral coordination geometry. In the crystal, pairs of N—H...Cl hydrogen bonds form inversion dimers. An intramolecular N—H...Cl hydrogen bond is also observed.

[N,N′-Bis(4-chlorobenzyl)propane-1,2-diamine]dichloridozinc(II)

2007 ◽  
Vol 63 (11) ◽  
pp. m2763-m2763
Author(s):  
Shu-Ping Yang ◽  
Li-Jun Han ◽  
Da-Qi Wang ◽  
Hai-Tao Xia
Keyword(s):  
Hydrogen Bonds ◽  
Title Complex ◽  
Coordination Geometry ◽  
Tetrahedral Coordination ◽  
A Chain ◽  
Cl Atoms

In the title complex, [ZnCl2(C17H20Cl2N2)], the ZnII atom is coordinated by two Cl atoms and two N atoms of the N,N′-bis(4-chlorobenzyl)propane-1,2-diamine ligand, and displays a tetrahedral coordination geometry. Two N—H...Cl hydrogen bonds link the molecules into a chain of R 2 2(8) rings.

scholarly journals [1H-1,2,4-Triazole-5(4H)-thione-κS]bis(triphenylphosphane-κP)(nitrato-κO)silver(I) methanol monosolvate

2014 ◽  
Vol 70 (2) ◽  
pp. m61-m62 ◽  
Author(s):  
Yupa Wattanakanjana ◽  
Sureeporn Palamae ◽  
Jenejira Ratthiwan ◽  
Ruthairat Nimthong
Keyword(s):  
Hydrogen Bonds ◽  
Title Complex ◽  
Coordination Geometry ◽  
Supramolecular Architecture ◽  
Two Dimensional ◽  
Tetrahedral Coordination ◽  
Crystal Complex ◽  
Solvent Molecules ◽  
A Chain ◽  
Distorted Tetrahedral Coordination

In the title complex, [Ag(NO3)(C2H3N3S)(C18H15P)2]·CH3OH, the AgIion exhibits a distorted tetrahedral coordination geometry formed by two P atoms from two triphenylphosphine ligands, one S atom from a 1H-1,2,4-triazole-5(4H)-thione ligand and one O atom from a nitrate ion. In the crystal, complex and solvent molecules are linked by O—H...O and N—H...O hydrogen bonds forming a chain along theb-axis direction. The chains are linked by weak C—H...O hydrogen bonds forming a two-dimensional supramolecular architecture parallel to (001). In addition, an intramolecular N—H...O hydrogen bond is observed.

Bis{2-[1-(benzylimino)ethyl]-5-methoxyphenol}dichlorozinc(II)

2006 ◽  
Vol 62 (7) ◽  
pp. m1548-m1549
Author(s):  
Xing-You Xu ◽  
Tong-Tao Xu ◽  
Shuai-Shuai Ni ◽  
Jian Gao ◽  
Da-Qi Wang
Keyword(s):  
Schiff Base ◽  
Hydrogen Bonds ◽  
Schiff Base Ligand ◽  
Title Complex ◽  
Hydroxyl Groups ◽  
Coordination Geometry ◽  
Tetrahedral Coordination ◽  
Intramolecular Hydrogen ◽  
Hydroxy Groups ◽  
Distorted Tetrahedral Coordination

The title complex, [ZnCl2(C16H17NO2)2], displays a distorted tetrahedral coordination geometry around the ZnII ion. The Schiff base inner salt, (benzylimino)ethyl-5-methoxyphenol, coordinates in a monodentate manner to the ZnII ion via the deprotonated hydroxy groups. The protonated imino groups form intramolecular hydrogen bonds with the deprotonated hydroxyl groups of the same Schiff base ligand.

scholarly journals Synthesis and structure of the mercury chloride complex of 2,2′-(2-bromo-5-tert-butyl-1,3-phenylene)bis(1-methyl-1H-benzimidazole)

2017 ◽  
Vol 73 (3) ◽  
pp. 341-344 ◽  
Author(s):  
Varsha Rani ◽  
Harkesh B. Singh ◽  
Ray J. Butcher
Keyword(s):  
Metal Cation ◽  
Chloride Complex ◽  
Mercury Chloride ◽  
Coordination Geometry ◽  
Tetrahedral Coordination ◽  
Bond Angles ◽  
Axis Direction ◽  
Tert Butyl ◽  
Cl Atoms ◽  
Distorted Tetrahedral Coordination

In the title mercury complex,catena-poly[[dichloridomercury(II)]-μ-2,2′-(2-bromo-5-tert-butyl-1,3-phenylene)bis(1-methyl-1H-benzimidazole)-κ2N3:N3′], [HgCl2(C26H25BrN4)]n, the HgIIatom is coordinated by two Cl atoms and by two N atoms from two 2,2′-(2-bromo-5-tert-butyl-1,3-phenylene)bis(1-methyl-1H-benzimidazole) ligands. The metal cation adopts a distorted tetrahedral coordination geometry with with bond angles around mercury of 100.59 (15)° [N—Hg—N] and 126.35 (7)° [Cl—Hg—Cl]. This arrangement gives rise to a zigzag helical 1-D polymer propagating along theb-axis direction.

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