(2,2′-Bipyridine-κ2N,N′)bis(4-formylbenzoato-κO1)copper(II)
The title mononuclear CuIIcomplex, [Cu(C8H5O3)2(C10H8N2)], is comprised of a CuIIcation, two 4-formylbenzoate (L−) ligands and a 2,2′-bipyridine (bipy) ligand. The CuIIion and bipy ligand lie on a crystallographic twofold rotation axis; the CuIIion is coordinated by two N atoms from one bipy ligand and two O atoms from two different carboxylate groups of twoL−ligands, exhibiting effectively a distorted square-planar geometry. The complex molecules are interlinked to generate two-dimensional supramolecular layers in theabplane, formed by C—H...O hydrogen bonds, where the O acceptor is the O atom from the carboxylate group not involved in coordination to the CuIIion. The two-dimensional layers are stacked in a sequenceviaC—H...O hydrogen-bonding interactions where the formyl O atom acts as acceptor.