Controlled interpenetration of 44networks: syntheses and structures of two Cu3-cluster coordination polymers

2018 ◽  
Vol 74 (11) ◽  
pp. 1540-1546
Author(s):  
Guanghui Sun ◽  
Weilian Xie ◽  
Hong Xiao ◽  
Guohai Xu
Keyword(s):  
Hydrogen Bond ◽  
Coordination Polymers ◽  
Variable Temperature ◽  
Three Dimensional ◽  
Copper Nitrate ◽  
Ferromagnetic Coupling ◽  
Interpenetrating Network ◽  
Magnetic Studies ◽  
Underlying Factor ◽  
Hydrogen Bond Interactions

The reaction of copper nitrate and triethanolamine with benzene-1,4-dicarboxylic acid (bdcH2) or 4,4′-[1,4-phenylenebis(oxy)]dibenzoic acid (podaH2) leads to the formation of poly[bis(μ4-benzene-1,4-dicarboxylato-κ4O1:O1′:O4:O4)bis{μ2-[bis(2-hydroxyethyl)amino]ethanolato-κ4N,O,O′,O′′:κO}tricopper(II)], [Cu3(C8H4O4)2(C6H14NO3)2] or [Cu3(μ4-bdc)2(teaH2)2] (I), and poly[bis{μ4-4,4′-[1,4-phenylenebis(oxy)]dibenzoato-κ4O:O′:O′′:O′′}bis{μ2-[bis(2-hydroxyethyl)amino]ethanolato-κ4N,O,O′,O′′:κO}tricopper(II)], [Cu3(C20H12O6)2(C6H14NO3)2] or [Cu3(μ4-poda)2(teaH2)2], (II). The two representative compounds contain a well-established Cu3cluster supporting a given 44network. The ligand length is the underlying factor that controls the degree of interpenetration. Controlled interpenetration can be facile to realise by elongating protocols. CompoundIshows a non-interpenetrating 44network, whereasIIfeatures a threefold interpenetrating network. Furthermore, similar hydrogen-bond interactions extend the different interpenetrating 44networks into three-dimensional supramolecular topologies. Variable-temperature magnetic studies showed a ferromagnetic coupling behaviour in the two complexes.

scholarly journals Crystal structure of 4-{[(1H-1,2,4-triazol-1-yl)methyl]sulfanyl}phenol

2014 ◽  
Vol 70 (10) ◽  
pp. o1106-o1106
Author(s):  
Yong-Le Zhang ◽  
Chuang Zhang ◽  
Wei Guo ◽  
Jing Wang
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bond ◽  
Hydrogen Bonds ◽  
Benzene Ring ◽  
Title Compound ◽  
Three Dimensional ◽  
Triazole Ring ◽  
Hydrogen Bond Interactions ◽  
Compound C ◽  
Dimensional Network

In the title compound, C9H9N3OS, the plane of the benzene ring forms a dihedral angle of 33.40 (5)° with that of the triazole group. In the crystal, molecules are linked by O—H...N hydrogen bonds involving the phenol –OH group and one of the unsubstituted N atoms of the triazole ring, resulting in chains along [010]. These chains are further extended into a layer parallel to (001) by weak C—H...N hydrogen-bond interactions. Aromatic π–π stacking [centroid–centroid separation = 3.556 (1) Å] between the triazole rings links the layers into a three-dimensional network.

Two CoII coordination polymers of biphenyl-2,2′,5,5′-tetracarboxylic acid with flexible N-donor ligands: syntheses, structures and magnetic properties

2019 ◽  
Vol 75 (8) ◽  
pp. 1073-1083 ◽  
Author(s):  
Feng Su ◽  
Cheng-Yong Zhou ◽  
Lin-Tao Wu ◽  
Xi Wu ◽  
Jing Su ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Three Dimensional ◽  
Donor Ligands ◽  
Tetracarboxylic Acid ◽  
X Ray Diffraction ◽  
Magnetic Studies ◽  
Orbital Contribution ◽  
X Ray ◽  
3D Network ◽  
Methyl Benzene

Two CoII-based coordination polymers, namely poly[(μ4-biphenyl-2,2′,5,5′-tetracarboxylato){μ2-1,3-bis[(1H-imidazol-1-yl)methyl]benzene}dicobalt(II)], [Co2(C16H6O8)(C14H14N4)2] n or [Co2(o,m-bpta)(1,3-bimb)2] n (I), and poly[[aqua(μ4-biphenyl-2,2′,5,5′-tetracarboxylato){1,4-bis[(1H-imidazol-1-yl)methyl]benzene}dicobalt(II)] dihydrate], {[Co2(C16H6O8)(C14H14N4)2(H2O)2]·4H2O} n or {[Co2(o,m-bpta)(1,4-bimb)2(H2O)2]·4H2O} n (II), were synthesized from a mixture of biphenyl-2,2′,5,5′-tetracarboxylic acid, i.e. [H4(o,m-bpta)], CoCl2·6H2O and N-donor ligands under solvothermal conditions. The complexes were characterized by IR spectroscopy, elemental analysis, single-crystal X-ray diffraction and powder X-ray diffraction analysis. The bridging (o,m-bpta)4− ligands combine with CoII ions in different μ4-coordination modes, leading to the formation of one-dimensional chains. The central CoII atoms display tetrahedral [CoN2O2] and octahedral [CoN2O4] geometries in I and II, respectively. The bis[(1H-imidazol-1-yl)methyl]benzene (bimb) ligands adopt trans or cis conformations to connect CoII ions, thus forming two three-dimensional (3D) networks. Complex I shows a (2,4)-connected 3D network with left- and right-handed helical chains constructed by (o,m-bpta)4− ligands. Complex II is a (4,4)-connected 3D novel network with ribbon-like chains formed by (o,m-bpta)4− linkers. Magnetic studies indicate an orbital contribution to the magnetic moment of I and II due to the longer Co...Co distances. An attempt has been made to fit the χM T results to the magnetic formulae for mononuclear CoII complexes, the fitting indicating the presence of weak antiferromagnetic interactions between the CoII ions.

A two-dimensional copper(II) coordination polymer based on 2-propyl-1H-imidazole-4,5-dicarboxylic acid

2015 ◽  
Vol 71 (2) ◽  
pp. 152-154 ◽  
Author(s):  
Di-Chang Zhong ◽  
Hua-Bin Guo ◽  
Ji-Hua Deng ◽  
Ping Lian ◽  
Xu-Zhong Luo
Keyword(s):  
Hydrogen Bond ◽  
Carboxylic Acid ◽  
Dicarboxylic Acid ◽  
Three Dimensional ◽  
Acid Group ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
Carboxylic Acid Group ◽  
X Ray ◽  
Hydrogen Bond Interactions

Single-crystal X-ray diffraction analysis of poly[bis(μ2-5-carboxy-2-propyl-1H-imidazole-4-carboxylato-κ3N3,O4:O5)copper(II)], [Cu(C8H9N2O4)2)]n, indicates that one carboxylic acid group of the 2-propyl-1H-imidazole-4,5-dicarboxylic acid (H3PDI) ligand is deprotonated. The resulting H2PDI−anion, acting as a bridge, connects the CuIIcations to form a two-dimensional (4,4)-connected layer. Adjacent layers are further linked through interlayer hydrogen-bond interactions, resulting in a three-dimensional supramolecular structure.

Diimidazolium aquapentakis(nitrato)neodymate(III)

2006 ◽  
Vol 62 (4) ◽  
pp. m854-m856
Author(s):  
Hui Zhang ◽  
Yanmei Wu ◽  
Liang Fang
Keyword(s):  
Hydrogen Bond ◽  
Title Compound ◽  
Three Dimensional ◽  
Asymmetric Unit ◽  
Hydrogen Bond Interactions ◽  
Dimensional Network

The asymmetric unit of the title compound, (Him)2[Nd(NO3)5H2O] (Him is 1H-imidazolium, C3H5N2), contains one [Nd(NO3)5H2O]2− anion and two imdidazolium cations. Nd is coordinated by 11 O atoms. N—H...O and O—H...O hydrogen-bond interactions link cations and anions, forming a three-dimensional network.

Symmetry constraints, molecular recognition and crystal engineering. Comparative structural studies of urea–butanedioic and urea–E-butanedioic acid (2:1) cocrystals

1996 ◽  
Vol 52 (6) ◽  
pp. 1048-1056 ◽  
Author(s):  
V. Videnova-Adrabińska
Keyword(s):  
Hydrogen Bond ◽  
Crystal Engineering ◽  
Three Dimensional ◽  
Structural Studies ◽  
Hydrogen Bond Interaction ◽  
Space Group ◽  
One Dimensional ◽  
Hydrogen Bond Interactions ◽  
Symmetry Constraints ◽  
Butanedioic Acid

The crystal structures of two urea–dicarboxylic acid (2:1) cocrystals have been determined. Urea–butanedioic acid forms monoclinic crystals, space group P21/c (No. 14), with a = 5.637 (4), b = 8.243 (3), c = 12.258 (3) Å, β = 96.80 (5)°, V = 565.6 (8) Å3, Z = 2. Urea–E-butenedioic acid also forms monoclinic crystals, space group P21/c (No. 14), with a = 5.540 (1), b = 8.227 (1), c = 12.426 (3) Å, β = 97.22 (3)°, V = 561.9 (2) Å3, Z = 2. The geometry and the conformation of both molecular aggregates and the three-dimensional networks formed are very similar. The two strongest hydrogen-bond interactions are constrained in the formation of the heteroaggregates, the third hydrogen-bond interaction is used to self-associate the heteroaggregates in one-dimensional chains, whereas the next three weaker hydrogen bonds interconnect the chains into well organized three-dimensional networks.

μ-4,4′-Bipyridine-κ2N:N′-bis[tetraaqua(4,4′-bipyridine-κN)dimanganese(II)] bis(4-aminobenzoate) bis(perchlorate)–4,4′-bipyridine–water (1/2/4): a supramolecular system constructed by π–π and hydrogen-bond interactions

2012 ◽  
Vol 68 (9) ◽  
pp. m255-m258 ◽  
Author(s):  
Jun Wang ◽  
Junlin Gao ◽  
Wenhua Zhao
Keyword(s):  
Hydrogen Bond ◽  
Three Dimensional ◽  
Water Molecules ◽  
Supramolecular System ◽  
Zigzag Chain ◽  
Manganese Compound ◽  
Face To Face ◽  
Hydrogen Bond Interactions ◽  
Distorted Octahedral ◽  
Bipy Molecule

The title dinuclear manganese compound, [Mn2(C10H8N2)3(H2O)8](C7H6NO2)2(ClO4)2·2C10H8N2·4H2O, (I), has an inversion center located midway between the MnIIions. Each MnIIion has a distorted octahedral coordination environment, defined by two mutuallycisN atoms from two different 4,4′-bipyridine (4,4′-bipy) ligands and four O atoms from four water molecules. The asymmetric unit contains cationic [Mn(4,4′-bipy)1.5(H2O)4]2+, one isolated 4,4′-bipy molecule, one 4-aminobenzoate ion, one disordered perchlorate ion and two uncoordinated water molecules. In the dinuclear manganese cationic unit, one 4,4′-bipy acts as a bidentate bridging ligand between two MnIIions, while the other two act only as monodentate terminal ligands, giving rise to a `Z-type' [Mn2(4,4′-bipy)3(H2O)8] host unit. These host units are linked to each otherviaface-to-face π–π stacking interactions between monodentate terminal 4,4′-bipy ligands, generating a zigzag chain. The corners of these chains, defined by Mn(OH)4units, are surrounded by the solvent water molecules and the carboxylate O atoms of the 4-aminobenzoate ions, and all of these are connected to each otherviastrong O—H...O hydrogen-bond interactions, leading to a three-dimensional grid network with a large cavity running along thebaxis of the unit cell. The isolated 4,4′-bipy molecules, the 4-aminobenzoate and perchlorate anions and the water molecules are encapsulated in the cavities by numerous hydrogen-bond interactions.

scholarly journals Crystal structures of threeortho-substitutedN-acylhydrazone derivatives

2017 ◽  
Vol 73 (12) ◽  
pp. 1946-1951 ◽  
Author(s):  
H. Purandara ◽  
Sabine Foro ◽  
B. Thimme Gowda
Keyword(s):  
Hydrogen Bond ◽  
Crystal Structures ◽  
Nitro Group ◽  
Structural Parameters ◽  
Three Dimensional ◽  
Torsion Angles ◽  
Molecular Conformations ◽  
Hydrogen Bond Interactions ◽  
Dimensional Network ◽  
Phenyl Rings

To explore the effect of the nature of substitutions on the structural parameters and hydrogen-bond interactions inN-acylhydrazone derivatives, the crystal structures of threeortho-substitutedN-acylhydrazone derivatives, namely (E)-N-{2-[2-(2-chlorobenzylidene)hydrazinyl]-2-oxoethyl}-4-methylbenzenesulfonamide, C16H16ClN3O3S (I), (E)-N-{2-[2-(2-methylbenzylidene)hydrazinyl]-2-oxoethyl}-4-methylbenzenesulfonamide, C17H19N3O3S (II), and (E)-N-{2-[2-(2-nitrobenzylidene)hydrazinyl]-2-oxoethyl}-4-methylbenzenesulfonamide, C16H16N4O5S (III), have been determined. The structures of the three compounds display similar molecular conformations and hydrogen-bond patterns. The hydrazone part of the molecule, C—C—N—N=C, is almost planar in all the compounds, with the C—C—N—N and C—N—N=C torsion angles being 179.5 (3) and 177.1 (3)°, respectively, in (I), −179.4 (2) and −177.1 (3)° in (II) and −179.7 (2) and 173.4 (2)° in (III). The two phenyl rings on either side of the chain are approximately parallel to each other. In the crystal, the molecules are linked to each otherviaN—H...O hydrogen bonds, forming ribbons withR22(8) andR22(10) ring motifs. The introduction of electron-withdrawing groups (by a chloro or nitro group) to produce compounds (I) or (III) results in C—H...O hydrogen-bonding interactions involving the sulfonyl O atoms of adjacent ribbons, forming layers parallel to theabplane in (I) or a three-dimensional network in (III). In (III), one O atom of the nitro group is disordered over two orientations with refined occupancy ratio of 0.836 (12):0.164 (12).

Novel one- and two-dimensional ZnIIcoordination polymers based on a versatile 3,6-bis(pyridin-4-yl)phenanthrene-9,10-dione ligand

2015 ◽  
Vol 71 (12) ◽  
pp. 1089-1095
Author(s):  
Guoxia Jin ◽  
Jia Wang ◽  
Qidi Wu ◽  
Zheng Han ◽  
Jianping Ma
Keyword(s):  
Hydrogen Bond ◽  
Hydrothermal Reaction ◽  
Three Dimensional ◽  
Two Dimensional ◽  
One Dimensional ◽  
Hydrogen Bond Interactions ◽  
Dimensional Network ◽  
Left And Right ◽  
Solvent Systems ◽  
Single Crystal Analysis

Two new ZnIIcoordination polymers, namely,catena-poly[[dibromidozinc(II)]-μ-[3,6-bis(pyridin-4-yl)phenanthrene-9,10-dione-κ2N:N′]], [ZnBr2(C24H14N2O2)]n, (1), and poly[[bromido[μ3-10-hydroxy-3,6-bis(pyridin-4-yl)phenanthren-9-olato-κ3N:N′:O9]zinc(II)] hemihydrate], {[ZnBr(C24H15N2O2)]·0.5H2O}n, (2), have been synthesized through hydrothermal reaction of ZnBr2and a 60° angular phenanthrenedione-based linker,i.e.3,6-bis(pyridin-4-yl)phenanthrene-9,10-dione, in different solvent systems. Single-crystal analysis reveals that polymer (1) features one-dimensional zigzag chains connected by weak C—H...π and π–π interactions to form a two-dimensional network. The two-dimensional networks are further stacked in anABABfashion along theaaxis through C—H...O hydrogen bonds. LayersAandBcomprise left- and right-handed helical chains, respectively. Coordination polymer (2) displays a wave-like two-dimensional layered structure with helical chains. In this compound, there are two opposite helical –Zn–HL– chains [HLis 10-hydroxy-3,6-bis(pyridin-4-yl)phenanthren-9-olate] in adjacent layers. The layers are packed in anABABsequence and are further connected through O—H...Br and O—H...O hydrogen-bond interactions to form a three-dimensional framework. In (1) and (2), the mutidentateLand HLligands exhibits different coordination modes.

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