scholarly journals Crystal structure of a new mixed-metal coordination polymer consisting of NiII piperidine-dithiocarbamate and pentanuclear CuI—I cluster units

2018 ◽  
Vol 74 (2) ◽  
pp. 233-236
Author(s):  
Kento Himoto ◽  
Toshiya Horii ◽  
Shoki Oda ◽  
Shimpei Suzuki ◽  
Kunihisa Sugimoto ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Coordination Polymer ◽  
Chain Structure ◽  
Mirror Plane ◽  
Zigzag Chain ◽  
Coordination Geometry ◽  
Tetrahedral Coordination ◽  
Square Planar ◽  
Cluster Unit ◽  
Distorted Tetrahedral Coordination

A new heterometallic CuI–NiII coordination polymer, poly[[tetra-μ3-iodido-μ2-iodido-bis(μ3-piperidine-1-dithiocarbamato)propionitrilepentacopper(I)nickel(II)] chloroform monosolvate], {[CuI 5NiIII5(C6H10NS2)2(C3H5N)]·CHCl3} n , has been synthesized and structurally characterized. This coordination polymer consists of an NiII mononuclear unit of NiII(Pip-dtc)2 (Pip-dtc− is piperidine-1-dithiocarbamate) and a pentanuclear copper(I) cluster unit of Cu5I5(CH3CH2CN). The NiII ion, which lies on an inversion centre, is surrounded by four S atoms in a square-planar coordination geometry while all CuI ions have distorted tetrahedral coordination geometries. In the pentanuclear copper(I) cluster unit, a mirror plane passes through one CuI ion and three I ions. All the S atoms in NiII(Pip-dtc) are also coordinated by the CuI ions, forming an infinite zigzag chain structure along the b-axis direction. The chains are weakly connected by solvent CHCl3 molecules via Cl...I [3.653 (1) Å] and Cl...S [3.4370 (1) Å] short-contact interactions.

Redetermination of [bis(2-pyridyl)amine-N,N′]copper(II) diperchlorate

2000 ◽  
Vol 57 (1) ◽  
pp. m25-m27 ◽  
Author(s):  
Miao Du ◽  
Xian-He Bu ◽  
Lin-Hong Weng ◽  
Xue-Bing Leng ◽  
Ya-Mei Guo
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonds ◽  
Coordination Sphere ◽  
Chain Structure ◽  
Title Complex ◽  
Coordination Geometry ◽  
Tetrahedral Coordination ◽  
A Chain ◽  
Distorted Tetrahedral Coordination ◽  
Close Contacts

In the crystal structure of the title complex, [Cu(C10H9N3)2](ClO4)2, the CuIIcenter is four-coordinated by the nitrogen donors of the pyridine rings of the ligand, bis(2-pyridyl)amine. The crystal structure reveals that the CuN4coordination sphere has a distorted tetrahedral coordination geometry with a crystallographicC2axis through the CuIIcenter. The perchlorate anions link the complex cations to form a chain structure through C—H...O close contacts and N—H...O hydrogen bonds.

scholarly journals Crystal structure of (benzenecarbothioamide-κS)chloridobis(triphenylphosphane-κP)silver(I)

2014 ◽  
Vol 70 (9) ◽  
pp. m310-m311 ◽  
Author(s):  
Wattana Ruangwut ◽  
Chaveng Pakawatchai
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bond ◽  
Hydrogen Bonds ◽  
Chloride Ion ◽  
Mixed Ligand ◽  
Title Complex ◽  
Coordination Geometry ◽  
Tetrahedral Coordination ◽  
Distorted Tetrahedral Coordination

In the mononuclear mixed-ligand title complex, [AgCl(C7H7NS)(C18H15P)2], the AgIion is four coordinated by one S atom of a benzenecarbothioamide ligand, two P atoms of two triphenylphosphane ligands and one chloride ion, displaying a distorted tetrahedral coordination geometry. In the crystal, pairs of N—H...Cl hydrogen bonds form inversion dimers. An intramolecular N—H...Cl hydrogen bond is also observed.

Mehrfachbindungen zwischen Hauptgruppenelementen und Übergangsmetallen, LXXIX. / Multiple Bonds between Main Group Elements and Transition Metals, LXXIX.

1990 ◽  
Vol 45 (7) ◽  
pp. 937-942 ◽  
Author(s):  
Eberhardt Herdtweck ◽  
Paul Kiprof ◽  
Wolfgang A. Herrmann ◽  
Josef G. Kuchler ◽  
Ian Degnan
Keyword(s):  
Crystal Structure ◽  
Equatorial Plane ◽  
Structural Data ◽  
Chain Structure ◽  
Methyl Groups ◽  
Zigzag Chain ◽  
Coordination Geometry ◽  
Multiple Bonds ◽  
Main Group Elements ◽  
Trigonal Bipyramidal

Trimethylstannyl perrhenate, (CH3)3SnOReO3 (2), synthesized from dirheniumheptoxide and tetramethyltin, has a zigzag-chain crystal structure. This structure originates from catenation of individual molecules via the tin atom to a perrhenate group of another molecule. The tin atom thus forms the center of a trigonal-bipyramidal coordination geometry, with two oxygen atoms adopting apical positions while three methyl groups define the equatorial plane. The Re—O—Sn bonds alternate between linear and slightly bent. The zigzag-aggregation of the chain-structure results from the tetrahedral [ReO4] subunits. Ionic contributions to the Re—O—Sn bonds are not evident from the structural data, nor do data obtained from solution indicate any ionization such as [(CH3)3Sn]+[ReO4]⁻. Following the synthesis of the title compound 2, the heavier congener triphenylplumbyl perrhenate (5) has been synthesized from Re2O7 and Pb(C6H5)4.

scholarly journals Crystal structure of (N1-benzyl-N1,N2,N2-trimethylethane-1,2-diamine-κ2N,N′)dichloridomercury(II)

2014 ◽  
Vol 70 (9) ◽  
pp. 118-120 ◽  
Author(s):  
Sudesh T. Manjare ◽  
Harkesh B. Singh ◽  
Ray J. Butcher
Keyword(s):  
Crystal Structure ◽  
Dihedral Angle ◽  
Coordination Sphere ◽  
Tertiary Amine ◽  
Title Compound ◽  
Chelate Ring ◽  
Zigzag Chain ◽  
Tetrahedral Coordination ◽  
Puckering Parameters ◽  
Distorted Tetrahedral Coordination

In the structure of the title compound, [HgCl2(C12H20N2)], the HgIIatom has a distorted tetrahedral coordination sphere defined by two tertiary amine N-atom donors, as well as two Cl−anions [the dihedral angle between the N—Hg—N and Cl—Hg—Cl planes is 82.80 (9)°]. The five-membered chelate ring adopts an envelope conformation, with puckering parameters ofQ(2) = 0.446 (6) Å and ϕ(2) = 88.8 (6)°, with the two amine CH3substituents on opposite sides of the ring. In the crystal, the molecules are linked by C—H...Cl interactions into a zigzag chain parallel to [101].

A one-dimensional coordination polymer formed from the reaction of 1,1-diphenyl-3,3′-[(1R,2R)-cyclohexane-1,2-diylbis(azanediyl)]dibut-2-en-1-one with MnCl2·4H2O

2013 ◽  
Vol 70 (1) ◽  
pp. 16-18
Author(s):  
Qi-Long Zhang ◽  
Lu-Tai Pan
Keyword(s):  
Coordination Polymer ◽  
Chain Structure ◽  
Chloride Ions ◽  
Tetrahedral Coordination ◽  
Coordination Environment ◽  
One Dimensional ◽  
Phenyl Rings ◽  
Chiral Schiff Base ◽  
Chloride Ligands ◽  
Distorted Tetrahedral Coordination

In the title coordination polymer,catena-poly[[dichloridomanganese(II)]-μ-1,1-diphenyl-3,3′-[(1R,2R)-cyclohexane-1,2-diylbis(azaniumylylidene)]dibut-1-en-1-olate-κ2O:O′], [MnCl2(C26H30N2)]n, synthesized by the reaction of the chiral Schiff base ligand 1,1-diphenyl-3,3′-[(1R,2R)-cyclohexane-1,2-diylbis(azanediyl)]dibut-2-en-1-one (L) with MnCl2·4H2O, the asymmetric unit contains one crystallographically unique MnIIion, one unique spacer ligand,L, and two chloride ions. Each MnIIion is four-coordinated in a distorted tetrahedral coordination environment by two O atoms from twoLligands and by two chloride ligands. The MnIIions are bridged byLligands to form a one-dimensional chain structure along theaaxis. The chloride ligands are monodentate (terminal). The ligand is in the zwitterionic enol form and displays intramolecular ionic N+—H...O−hydrogen bonding and π–π interactions between pairs of phenyl rings which strengthen the chains.

scholarly journals Crystal structure and Hirshfeld-surface analysis of (benzenecarbothioamide-κS)bromidobis(triphenylphosphane-κP)silver(I)

2016 ◽  
Vol 72 (7) ◽  
pp. 984-987
Author(s):  
Wattana Ruangwut ◽  
Saowanit Saithong ◽  
Chaveng Pakawatchai
Keyword(s):  
Crystal Structure ◽  
Mixed Solvent ◽  
Hirshfeld Surface ◽  
Title Complex ◽  
Mononuclear Complex ◽  
Coordination Geometry ◽  
Tetrahedral Coordination ◽  
Bromide Ion ◽  
Structure Inversion ◽  
Distorted Tetrahedral Coordination

The title complex, [AgBr(C7H7NS)(C18H15P)2], was obtained from the reaction of silver(I) bromide with benzenecarbothioamide (C7H7NS) and triphenylphosphane (C18H15P) in the mixed solvent of acetonitrile and ethanol. The mononuclear complex exhibits a distorted tetrahedral coordination geometry about the metal atom, arising from one S atom of a benzenecarbothioamide ligand, two P atoms of two triphenylphosphane molecules and one bromide ion. An intramolecular N—H...Br hydrogen bond is observed and in the crystal structure, inversion dimers linked by pairs of N—H...Br and C—H...Br hydrogen bonds are observed. In addition, C—H...π interactions occur, leading to [101] chains. Hirshfeld-surface analyses are presented and discussed.

scholarly journals Crystal structure of bis[μ-1,2-bis(diphenylphosphanyl)ethane-κ2P:P′]bis[(N,N′-diethylthiourea-κS)iodidocopper(I)]

2015 ◽  
Vol 71 (9) ◽  
pp. m154-m155
Author(s):  
Ladawan Khongsichan ◽  
Arunpatcha Nimthong-Roldán ◽  
Chaveng Pakawatchai ◽  
Sumpun Wongnawa
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bond ◽  
Hydrogen Bonds ◽  
Title Complex ◽  
Coordination Geometry ◽  
Tetrahedral Coordination ◽  
Complex Molecules ◽  
Iodide Ion ◽  
Distorted Tetrahedral Coordination

The binuclear title complex, [Cu2I2(C26H24P2)2(C5H12N2S)2], lies about an inversion centre. The CuIatom displays a distorted tetrahedral coordination geometry defined by one S atom of anN,N′-diethylthiourea ligand, two P atoms derived from two bridging 1,2-bis(diphenylphosphanyl)ethane (dppe) ligands and one iodide ion. The dppe ligand bridges two symmetry-related CuIions, forming a 10-membered Cu2P4C4ring. An intramolecular N—H...I hydrogen bond is noted. In the crystal, N—H...I hydrogen bonds link complex molecules into layers parallel to (-101).

A 2-D Zn(II) coordination polymer based on 4,5-imidazoledicarboxylate and bis(benzimidazole) ligands: synthesis, crystal structure and fluorescence properties

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Xinzhao Xia ◽  
Lixian Xia ◽  
Geng Zhang ◽  
Yuxuan Jiang ◽  
Fugang Sun ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Coordination Polymer ◽  
Zigzag Chain ◽  
Supramolecular Framework ◽  
X Ray Diffraction ◽  
Hydrothermal Conditions ◽  
Hydrogen Bond Interaction ◽  
X Ray ◽  
New Type ◽  
Solid State Fluorescence

Abstract In this work, a new type of zinc(II) coordination polymer {[Zn(HIDC)(BBM)0.5]·H2O} n (Zn-CP) was synthesized using 4,5-imidazoledicarboxylic acid (H3IDC) and 2,2-(1,4-butanediyl)bis-1,3-benzimidazole (BBM) under hydrothermal conditions. Its structure has been characterized by infrared spectroscopy, elemental analysis and single crystal X-ray diffraction analysis. The Zn(II) ion is linked by the HIDC2− ligand to form a zigzag chain by chelating and bridging, and then linked by BBM to form a layered network structure. Adjacent layers are further connected by hydrogen bond interaction to form a 3-D supramolecular framework. The solid-state fluorescence performance of Zn-CP shows that compared with free H3IDC ligand, its fluorescence intensity is significantly enhanced.

Bis(2,9-dimethyl-1,10-phenanthroline)copper(I) tetraphenylborate dichloromethane solvate

2007 ◽  
Vol 63 (3) ◽  
pp. m800-m802 ◽  
Author(s):  
William T. Eckenhoff ◽  
Tomislav Pintauer
Keyword(s):  
Bond Length ◽  
Dihedral Angle ◽  
Title Compound ◽  
Stacking Interactions ◽  
Coordination Geometry ◽  
Tetrahedral Coordination ◽  
Π Stacking ◽  
Distorted Tetrahedral Coordination

In the title compound, [Cu(C14H12N2)2]C24H20B·CH2Cl2, CuI is chelated by two 2,9-dimethyl-1,10-phenanthroline (2,9-Me2phen) ligands, in a distorted tetrahedral coordination geometry. The average Cu—N bond length is 2.032 Å, and the interligand dihedral angle is 77.60 (6)°. The complexes form π–π stacking interactions between 2,9-Me2phen ligands, with a perpendicular interplanar separation of 3.652 (5) Å.

Sign in / Sign up

Export Citation Format

Share Document