An ensemble Monte Carlo code has been developed for the simulation of hole relaxation
processes in a GaAs/AlAs quantum well. The code includes a realistic k.p model of the
valence subbands and corresponding wavefunctions. Intra- and inter-subband phonon
scattering rates are calculated for polar and non-polar interactions via both optical and
acoustic modes. The code is used to simulate the cooling of non-equilibrium
photogenerated hole populations. A lifetime of 90 fs is extracted for optical phonon
mediated depopulation of the 4th subband at 77K. By contrast, the 2nd subband
exhibits fast re-population, but slow de-population, with extracted lifetimes of up to
160 ps. The slow depopulation is attributed to the small energy separation of the 1st and
2nd subbands (less than the optical phonon energy) and the large density of states in the
2nd subband off-zone-centre minimum.