Effect of growth temperature on the structural and optical properties of CdS:O thin films for CdTe solar cells

Author(s):  
N. K. Das ◽  
J. Chakrabartty ◽  
S. F. U. Farhad ◽  
M. A. Matin ◽  
N. Amin
Coatings ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 1392
Author(s):  
Oleksii Diachenko ◽  
Jaroslav Kováč ◽  
Oleksandr Dobrozhan ◽  
Patrik Novák ◽  
Jaroslav Kováč ◽  
...  

Copper oxide thin films were obtained using pulsating spray pyrolysis method. The morphological, structural, and optical properties of fabricated films were studied. X-ray analysis revealed that the CuO thin films are single-phase. The study of films morphology by SEM and AFM methods showed that the obtained films have a fairly high surface roughness and contain grains of different shapes and sizes. It was found that the obtained films of copper oxide have high values of the absorption coefficient, which confirms the possibility of their use as absorbing layers for solar cells. The obtained values of the optical band gap of the material are in the range from 1.45 eV to 1.60 eV. Raman spectroscopy revealed three modes A1g, B1g, and B2g, of the crystal structure of monoclinic CuO. The devices based on p-type copper oxide are promising for solar cells fabrication because they can reduce production costs, due to their low cost and inexpensive production methods compared to silicon solar cells fabrication.


2001 ◽  
Vol 668 ◽  
Author(s):  
K. Nakamura ◽  
M. Gotoh ◽  
T. Fujihara ◽  
T. Toyama ◽  
H. Okamoto

ABSTRACTThe structural and optical properties of CdS/CdTe(S) interface region of 2-μm thick CdS/CdTe solar cells have been studied in conjunction with photovoltaic performances of the solar cells. The properties are found to be crucially influenced by the annealing temperature and oxygen concentration of the CdCl2 treatment. An increase in VOC and F.F. found in the solar cells with the CdCl2 treatment at < 360°C is interpreted as due to suppression of interdiffusion of sulfur and tellurium at the CdS/CdTe(S) interface. On the other hand, the electromodulated photoluminescence with UV light excitation (UVE-EMPL) study reveals that the increasing VOC due to increasing oxygen concentration to 5% is likely to be caused by an increase in the built-in electric field in n+-CdTe1−xSx just adjacent to the CdS/CdTe(S) interface. As a result of the modification of the process parameters, we have achieved the conversion efficiency of 13.6% (VOC: 0.817V, JSC: 23.0 mA/cm2, F.F.: 0.725) using 2.3-μm thick PV active layer without anti-reflection coating.


Sign in / Sign up

Export Citation Format

Share Document