The combustion mechanism, which consisting of 22 species and 23 reaction equations, and three discrete models such as inertia, combusting, modification droplet, are employed for the investigation of gas-solid combustion in magnesium-aluminum based propellant ducted rocket based on thermal performance calculation. And path lines, temperature distribution, sediments are discussed after the computing method is validated by direct-connect experimentation and the flow field information, which obtained by numerical method and coincided with currently conclusions. The results indicated that the proposed method is reliable and practicable.