Selective Fluorescence Determination of Amoxicillin Antibiotic Based on Inner Filter Effect of Glutathione-Capped@CdTe Quantum Dots With Cobalt as a Mediating Agent

2019 ◽  
Vol 19 (14) ◽  
pp. 5369-5375
Author(s):  
Behzad Rezaei ◽  
Fatemeh Hajtaghi Khorasgani ◽  
Hamid Reza Jamei ◽  
Ali Asghar Ensafi
2020 ◽  
Vol 98 (5) ◽  
pp. 222-227
Author(s):  
Keke Ning ◽  
Guoqiang Xiang ◽  
Cuicui Wang ◽  
Jingxing Wang ◽  
Xiaohong Qiao ◽  
...  

In this work, poly(sodium 4-styrenesulfonate) (PSS) modified molybdenum disulfide quantum dots (MoS2-PSS QDs) were synthesized via a simple hydrothermal method using l-cysteine and anhydrous sodium molybdate as precursors and PSS as a modification reagent, and a selective and sensitive fluorescent sensing method for the determination of p-nitrophenol (p-NP) based on their UV emission was developed. The obtained MoS2-PSS QDs have an obvious UV emission peak (390 nm) with quantum yield of 5.13%. The strong absorption peak of p-NP at 400 nm has large spectral overlap with the UV emission peak (390 nm) of MoS2-PSS QDs. Because of this p-NP absorption, the fluorescence of MoS2-PSS QDs at 390 nm is quenched with the introduction of p-NP via the inner filter effect (IFE) and the decreased fluorescence intensity was linearly proportional to the p-NP concentration in the range of 1–20 μmol/L, leading to a detection limit of 0.13 μmol/L for p-NP. The MoS2 QDs-based fluorescent probe for p-NP is sensitive and selective and was successfully applied in the determination of p-NP in the pond water samples with satisfactory results.


2012 ◽  
Vol 173 ◽  
pp. 477-482 ◽  
Author(s):  
Qiang Zhang ◽  
Yuanyuan Qu ◽  
Meng Liu ◽  
Xinliang Li ◽  
Jiti Zhou ◽  
...  

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