Production of Potash and N‐Mg Compound Fertilizer via Mineral Shoenite from Kun Te Yi Salt Lake: Phase Diagrams of the Quaternary System (NH 4 ) 2 SO 4 ‐MgSO 4 ‐K 2 SO 4 ‐H 2 O in the Isothermal Evaporation and Crystallization Process

Author(s):  
Cheng LI ◽  
Xueqing CHEN ◽  
Hongfei GUO ◽  
Xue ZHOU ◽  
Jilin CAO
2012 ◽  
Vol 549 ◽  
pp. 437-440 ◽  
Author(s):  
Shi Qiang Wang ◽  
Ya Fei Guo ◽  
Tian Long Deng

Solubilities of the reciprocal quaternary system (Li+, Mg2+//Cl-, SO42-–H2O) at 273.15K were calculated using Pitzer and its extended HW model. The values of the Pitzer single-salt parameters β(0), β(1), β(2)and Cφfor LiCl, MgCl2, Li2SO4, and MgSO4, the mixed ion-interaction parameters θLi,Mg, θCl,SO4, ψLi,Mg,Cl, ψLi,Mg,SO4, ψLi,Cl,SO4and ψMg,Cl,SO4, and the Debye–Hückel parameter Aφin the system at 273.15K were derived either temperature-dependent equation or through fitting solubility data of the ternary system by multiple linear regression method. Based on the Jänecke indexes, the phase diagram was plotted. This study affords the necessary parameters for solubility predictions of complicated systems and establishes a theoretical basis for the separation of these valuable minerals from salt lake brine.


2010 ◽  
Vol 84 (6) ◽  
pp. 1533-1538 ◽  
Author(s):  
NIE Zhen ◽  
BU Lingzhong ◽  
ZHENG Mianping ◽  
ZHANG Yongsheng

2014 ◽  
Vol 1015 ◽  
pp. 405-408
Author(s):  
Bai Hui Bu ◽  
Fei Li ◽  
Ya Fei Guo ◽  
Shi Qiang Wang ◽  
Tian Long Deng

It is well known that phase equilibria and phase diagrams can successfully guide the comprehensive utilization of the salt lake resources. The researches on phase chemistry and thermal chemistry of the calcium-containing brine system are essential to promote the development of brines. In this paper, the progresses on the phase chemistry and thermal chemistry of the calcium-containing brine system around the world from 2007 up to now were summarized. The problems existed and the new trends in the future were also carried out.


2019 ◽  
Vol 134 ◽  
pp. 136-145 ◽  
Author(s):  
Cheng Li ◽  
Jing-Xue Wu ◽  
Hong-Fei Guo ◽  
Bin Zhao ◽  
Ji-Lin Cao

2016 ◽  
Vol 61 (1) ◽  
pp. 450-457 ◽  
Author(s):  
Shuai-Yong Dou ◽  
Hong-Fei Guo ◽  
Bin Zhao ◽  
Chun-Yan Xue ◽  
Ji-Lin Cao

2014 ◽  
Vol 1015 ◽  
pp. 401-404
Author(s):  
Long Li ◽  
Dao Lin Gao ◽  
Jiang Ping Zeng ◽  
Ya Fei Guo ◽  
Tian Long Deng

Salt lake brine resource is one of the strategic resources in the western of China. Phase equilibria and phase diagrams are the theoretic foundation for the exploitation of salt lake brine resources. Hence, studies for the stable and metastable phase equilibria of lithium-containing salt-water systems are of the great importance for the development of salt lake brine resources. In this paper, the stable and metastable phase equilibria of lithium-containing salt-water systems were summarized, and the problems existed at present and the new trends in the future are also discussed.


2014 ◽  
Vol 88 (s1) ◽  
pp. 161-162
Author(s):  
Xuekui WANG ◽  
Jinggang DONG ◽  
Jianjun YUAN ◽  
Zuoliang SHA

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