QUANTUM CHEMICAL ASPECTS OF SOME PROBLEMS IN BIOINORGANIC CHEMISTRY. III. SOME LIGAND PROPERTIES OF METAL COMPLEXES: POPULATION ANALYSIS

1981 ◽  
Vol 373 (1 Fourth Intern) ◽  
pp. 37-50 ◽  
Author(s):  
I. Fischer-Hjalmars ◽  
A. Henriksson-Enflo
Keyword(s):  
Metal Complexes ◽  
Quantum Chemical ◽  
Population Analysis ◽  
Bioinorganic Chemistry

Novel Chemotherapeutic Agents - The Contribution of Scorpionates

2020 ◽  
Vol 26 (41) ◽  
pp. 7452-7475 ◽  
Author(s):  
Marta A. Andrade ◽  
Luísa M.D.R.S. Martins
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Anticancer Agents ◽  
Medicinal Chemistry ◽  
Bioinorganic Chemistry ◽  
Chemotherapeutic Agents ◽  
Great Role ◽  
Anticancer Properties ◽  
Scorpionate Ligands

: The development of safe and effective chemotherapeutic agents is one of the uppermost priorities and challenges of medicinal chemistry and new transition metal complexes are being continuously designed and tested as anticancer agents. Scorpionate ligands have played a great role in coordination chemistry, since their discovery by Trofimenko in the late 1960s, with significant contributions in the fields of catalysis and bioinorganic chemistry. Scorpionate metal complexes have also shown interesting anticancer properties, and herein, the most recent (last decade) and relevant scorpionate complexes reported for application in medicinal chemistry as chemotherapeutic agents are reviewed. The current progress on the anticancer properties of transition metal complexes bearing homo- or hetero- scorpionate ligands, derived from bis- or tris-(pyrazol-1-yl)-borate or -methane moieties is highlighted.

scholarly journals Preface from the Guest Editor of Special Issue “Quantum-Chemical Modeling and Design of Chelate and Macrocyclic Metal Complexes”

2020 ◽  
Vol 21 (7) ◽  
pp. 2339
Author(s):  
Oleg V. Mikhailov
Keyword(s):  
Metal Complexes ◽  
Crown Ethers ◽  
Guest Editor ◽  
Special Interest ◽  
Quantum Chemical ◽  
Chemical Compounds ◽  
Quantum Chemical Modeling ◽  
Special Issue ◽  
Chemical Modeling ◽  
Elemental Chemistry

As is known, in the last fifty years of coordination of inorganic and organo-elemental chemistry, chemical compounds formed by chelating or macrocyclic organic and organo-elemental ligands (in particular, crown ethers, cryptands, calixarenes, cucurbituryls, porphyrins, and their various derivatives) and ions of various p-, d- and f-elements, have become of special interest [...]

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