Anionic effect of chloride, fluoride, and sulfide ions on the viscosity of slag melt

2017 ◽  
Vol 100 (6) ◽  
pp. 2543-2552 ◽  
Author(s):  
Sunghee Lee ◽  
Dong Joon Min

Crystals ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 888
Author(s):  
Helin Fan ◽  
Ruixiang Wang ◽  
Zhifeng Xu ◽  
Huamei Duan ◽  
Dengfu Chen

Synthetic rutile was prepared from titanium slag melt with low energy consumption and a small amount of additive (B2O3) in our previous work. The modification mechanism of titanium slag was not clear enough. The migration and enrichment behaviors of Ca and Mg elements during cooling and crystallization of boron-bearing titanium slag melt were characterized by XRF, FESEM, EMPA, and XPS. Results show that when additive (B2O3) is added, Ti elements are migrated and enriched in the area to generate rutile, while Ca, Mg, and B elements are migrated and enriched in another area to generate borate. With the additive (B2O3) amount increased, Ca and Mg element migration is complete and more thorough. Additive (B2O3) promotes rutile formation and inhibits the formation of anosovite during cooling and crystallization of titanium slag melt. With the additive (B2O3) amount increasing from 0% to 6%, the proportion of Ti3+ in the modified titanium slag reduces from 9.15% to 0%, and the proportion of Ti4+ increases from 90.85% to 100% under the same cooling and crystallization condition. The result will lay the foundation for the efficient preparation of synthetic rutile by adding B2O3 to the titanium slag melt.







2021 ◽  
Vol 543 ◽  
pp. 148795
Author(s):  
Qian Zhang ◽  
Shuming Wen ◽  
Qicheng Feng ◽  
Junbo Liu


Nanomaterials ◽  
2019 ◽  
Vol 9 (11) ◽  
pp. 1525
Author(s):  
Sergey Vorobyev ◽  
Elena Vishnyakova ◽  
Maxim Likhatski ◽  
Alexander Romanchenko ◽  
Ivan Nemtsev ◽  
...  

Carey Lea silver hydrosol is a rare example of very concentrated colloidal solutions produced with citrate as only protective ligands, and prospective for a wide range of applications, whose properties have been insufficiently studied up to now. Herein, the reactivity of the immobilized silver nanoparticles toward oxidation, sulfidation, and sintering upon their interaction with hydrogen peroxide, sulfide ions, and chlorocomplexes of Au(III), Pd(II), and Pt(IV) was investigated using SEM and X-ray photoelectron spectroscopy (XPS). The reactions decreased the number of carboxylic groups of the citrate-derived capping and promoted coalescence of 7 nm Ag NPs into about 40 nm ones, excluding the interaction with hydrogen peroxide. The increased nanoparticles form loose submicrometer aggregates in the case of sulfide treatment, raspberry-like micrometer porous particles in the media containing Pd(II) chloride, and densely sintered particles in the reaction with inert H2PtCl6 complexes, probably via the formation of surface Ag-Pt alloys. The exposure of Ag NPs to HAuCl4 solution produced compact Ag films along with nanocrystals of Au metal and minor Ag and AgCl. The results are promising for chemical ambient temperature sintering and rendering silver-based nanomaterials, for example, for flexible electronics, catalysis, and other applications.



RSC Advances ◽  
2013 ◽  
Vol 3 (47) ◽  
pp. 25410 ◽  
Author(s):  
Liudmil Antonov ◽  
Vera Deneva ◽  
Vanya Kurteva ◽  
Daniela Nedeltcheva ◽  
Aurelien Crochet ◽  
...  
Keyword(s):  


1994 ◽  
Vol 107 (2) ◽  
pp. 189-199 ◽  
Author(s):  
A. Andreev ◽  
V. Ivanova ◽  
K. Kirilov ◽  
G. Passage


Author(s):  
Ольга Степанівна Худоярова ◽  
Ольга Анатоліївна Гордієнко ◽  
Тетяна Іванівна Сидорук ◽  
Тарас Сергійович Тітов ◽  
Анатолій Петрович Ранський


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