A New Turbomachine for Clean and Sustainable Hydrocarbon Cracking

Author(s):  
Dylan Rubini ◽  
Liping Xu ◽  
Budimir Rosic ◽  
Harri Johannesdahl

Abstract Decarbonising highly energy-intensive industrial processes is imperative if nations are to comply with 2050 greenhouse gas emissions. This is a significant challenge for high-temperature industrial processes, such as hydrocarbon cracking, and there have been limited developments thus far. The novel concept presented in this study aims to replace the radiant section of a hydrocarbon cracking plant with a novel turbo-reactor. Rather than using heat from the combustion of natural gas, the novel turbo-reactor can be driven by an electric motor powered by renewable electricity. Switching the fundamental energy transfer mechanism from surface heat exchange to mechanical energy transfer significantly increases the exergy efficiency of the process. Theoretical analysis and numerical simulations show that the ultra-high aerodynamic loading rotor is able to impart substantial mechanical energy into the feedstock without excess temperature difference and metal temperature magnitude. The required enthalpy rise can be supplied within a reactor volume 500 times smaller than that for a conventional furnace. A significantly lower wall surface temperature, supersonic gas velocities and a shorter primary gas path enable a controlled reduction in the residence time for chemical reactions, which optimises the yield. For the same reasons the conditions for coke deposition on the turbo-reactor surfaces are unfavourable, leading to an increase in plant availability. This study demonstrates that the mechanical work input into the feedstock can be dissipated through an intense turbulent mixing process which maintains an ideal and controlled pressure level for cracking.

2021 ◽  
Author(s):  
Dylan Rubini ◽  
Liping Xu ◽  
Budimir Rosic ◽  
Harri Johannesdahl

Abstract Decarbonising highly energy-intensive industrial processes is imperative if nations are to comply with anthropogenic greenhouse gas emissions targets by 2050. This is a significant challenge for high-temperature industrial processes, such as hydrocarbon cracking, and there have been limited developments thus far. The novel concept presented in this study aims to replace the radiant section of a hydrocarbon cracking plant with a novel turbo-reactor. This is one of the first major and potentially successful attempts at decarbonising the petrochemical industry. Rather than using heat from the combustion of natural gas, the novel turbo-reactor can be driven by an electric motor powered by renewable electricity. Switching the fundamental energy transfer mechanism from surface heat exchange to mechanical energy transfer significantly increases the exergy efficiency of the process. Theoretical analysis and numerical simulations show that the ultra-high aerodynamic loading rotor is able to impart substantial mechanical energy into the feedstock without excess temperature difference and temperature magnitude. A complex shockwave system then transforms the kinetic energy into internal energy over an extremely short distance. The version of the turbo-reactor developed and presented in this study uses a single rotor row, in which a multi-stage configuration is achieved regeneratively by guiding the flow through a toroidal-shaped vaneless space. This configuration leads to a reduction in reactor volume by more than two orders of magnitude compared with a conventional furnace. A significantly lower wall surface temperature, supersonic gas velocities and a shorter primary gas path enable a controlled reduction in the residence time for chemical reactions, which optimises the yield. For the same reasons, the conditions for coke deposition on the turbo-reactor surfaces are unfavourable, leading to an increase in plant availability. This study demonstrates that the mechanical work input into the feedstock can be dissipated through an intense turbulent mixing process which maintains an ideal and controlled pressure level for cracking. Numerical calculations show that the turbulence intensity increases by nearly an order of magnitude relative to that in a industrial radiant reaction tube, which can be favourable for accelerating the chemical kinetics.


2016 ◽  
Vol 2016 ◽  
pp. 1-18 ◽  
Author(s):  
Y. F. Lao ◽  
A. G. U. Perera

Internal photoemission (IP) correlates with processes in which carriers are photoexcited and transferred from one material to another. This characteristic allows characterizing the properties of the heterostructure, for example, the band parameters of a material and the interface between two materials. IP also involves the generation and collection of photocarriers, which leads to applications in the photodetectors. This review discusses the generic IP processes based on heterojunction structures, characterizing p-type band structure and the band offset at the heterointerface, and infrared photodetection including a novel concept of photoresponse extension based on an energy transfer mechanism between hot and cold carriers.


Author(s):  
Takaharu Tanaka

Fundamental mechanisms of energy transfer, which is caused between impeller blade and fluid particles in centrifugal pumps and water turbines, are discussed together with as a turbomachinery under same theoretical basement. This leads to the result that the fluid flow which directs radial outward in pump and that radial inward in water turbine are neither caused by centrifugal force nor centripetal force, but caused by tangential forward force, which acts on the impeller blade in the direction perpendicular to rotational radius. Hydraulic energies of fluid particles transferred from mechanical to hydraulic energy in pump and that to be transferred from hydraulic to mechanical energy in water turbine appear as centrifugal force FHCF in rotational flow passage.


2017 ◽  
Vol 65 (2) ◽  
pp. 110-120 ◽  
Author(s):  
Zhe Chen ◽  
Jiu-Hui Wu ◽  
A-Dan Ren ◽  
Xin Chen ◽  
Zhen Huang

2021 ◽  
pp. 118082
Author(s):  
Hai Ma ◽  
Xiaodan Wang ◽  
Feifei Chen ◽  
Jiafan Chen ◽  
Xionghui Zeng ◽  
...  

Processes ◽  
2021 ◽  
Vol 9 (2) ◽  
pp. 312
Author(s):  
Yusuf Tutel ◽  
Gökhan Sevinç ◽  
Betül Küçüköz ◽  
Elif Akhuseyin Yildiz ◽  
Ahmet Karatay ◽  
...  

Meso-substituted borondipyrromethene (BODIPY)-porphyrin compounds that include free base porphyrin with two different numbers of BODIPY groups (BDP-TTP and 3BDP-TTP) were designed and synthesized to analyze intramolecular energy transfer mechanisms of meso-substituted BODIPY-porphyrin dyads and the effect of the different numbers of BODIPY groups connected to free-base porphyrin on the energy transfer mechanism. Absorption spectra of BODIPY-porphyrin conjugates showed wide absorption features in the visible region, and that is highly valuable to increase light-harvesting efficiency. Fluorescence spectra of the studied compounds proved that BODIPY emission intensity decreased upon the photoexcitation of the BODIPY core, due to the energy transfer from BODIPY unit to porphyrin. In addition, ultrafast pump-probe spectroscopy measurements indicated that the energy transfer of the 3BDP-TTP compound (about 3 ps) is faster than the BDP-TTP compound (about 22 ps). Since the BODIPY core directly binds to the porphyrin unit, rapid energy transfer was seen for both compounds. Thus, the energy transfer rate increased with an increasing number of BODIPY moiety connected to free-base porphyrin.


2020 ◽  
pp. 1-24
Author(s):  
Zoltán I. Búzás

Abstract Formal racial equality is a key aspect of the current Liberal International Order (LIO). It is subject to two main challenges: resurgent racial nationalism and substantive racial inequality. Combining work in International Relations with interdisciplinary studies on race, I submit that these challenges are the latest iteration of struggles between two transnational coalitions over the LIO's central racial provisions, which I call racial diversity regimes (RDRs). The traditional coalition has historically favored RDRs based on racial inequality and racial nationalism. The transformative coalition has favored RDRs based on racial equality and nonracial nationalism. I illustrate the argument by tracing the development of the liberal order's RDR as a function of intercoalitional struggles from one based on racial nationalism and inequality in 1919 to the current regime based on nonracial nationalism and limited equality. Today, racial nationalists belong to the traditional coalition and critics of racial inequality are part of the transformative coalition. The stakes of their struggles are high because they will determine whether we will live in a more racist or a more antiracist world. This article articulates a comprehensive framework that places race at the heart of the liberal order, offers the novel concept of “embedded racism” to capture how sovereignty shields domestic racism from foreign interference, and proposes an agenda for mainstream International Relations that takes race seriously.


Sign in / Sign up

Export Citation Format

Share Document