The Performance of Creep-Strengthened Ferritic Steels in Power Generating Plant

Author(s):  
Jonathan Parker ◽  
Jeff Henry

Creep-strengthened ferritic steels, such as Grade 91, offer the potential for excellent high-temperature performance. To realize the benefits for these alloys requires careful control of original composition and manufacturing processes, such as welding and bending, as well as the associated heat treatments. Laboratory tests indicate that long-term lives may be below the original estimates made based on Larson Miller extrapolation. Furthermore, accelerated rates of damage accumulation in in-service Grade 91 components can occur due to a number of factors including: • Problems associated with design, for example with reinforcement at nozzles and with stress concentrations in piping systems. • Incorrect heat treatment, in addition to proper instrumentation appropriate heat treatment schedules should consider specific compositions. • Bending, problems may be introduced following both hot or cold bending. • High-temperature operation in tubing leading to excessive scale formation and overheating. • Type IV cracking in welds which results from the local reduction in the heat affected zone strength resulting from welding thermal cycles. Review of key information regarding the high-temperature performance of creep strengthened ferritic steels shows that the long-term creep strength may not achieve the levels expected from simple extrapolation of short term data. The problems experienced are highlighted with reference to actual case histories. The additional challenges associated with the development of creep-fatigue damage in high-temperature plant operated in a cyclic mode are also discussed.

Author(s):  
Kenji Kako ◽  
Susumu Yamada ◽  
Masatsugu Yaguchi ◽  
Yusuke Minami

Type IV damage has been found at several ultra-supercritical (USC) plants that used high-chromium martensitic steels in Japan, and the assessment of the remaining life of the steels is important for electric power companies. The assessment of the remaining life needs long-term creep data for over 10 years, but such data are limited. We have attempted to assess the remaining life by creep tests and by microstructural observation of Grade 91 steels welded pipes which were used in USC plants for over 10 years. Following the results of microstructural observation of USC plant pipes, we find that microstructures, especially distribution of MX precipitates, have large effect on the creep life of Grade 91 steels.


2013 ◽  
Vol 275-277 ◽  
pp. 2107-2111
Author(s):  
Qiu Lin Zou ◽  
Jun Li ◽  
Zhen Yu Lai

Barite concrete with density grade of 3 and strength grade of C30 was prepared by mixing with different fineness of fly ash. The workability, mechanical properties and long-term high temperature performance of the prepared barite concrete were researched. Results show that the workability of barite concrete is improved by mixing with fly ash, and no segregation of mixture has been observed. The apparent density and 3d, 28d compressive strength of barite concrete are decreased obviously after mixing with fly ash. But with the increasing of the fineness of fly ash, the apparent density and 3d, 28d compressive strength of barite concrete have a slight increase. High temperature residual compressive strength is decreased with the increasing of temperature. The cycle times of heat treatment at 400°C only has a little effect on residual compressive strength of barite concrete.


Alloy Digest ◽  
2010 ◽  
Vol 59 (4) ◽  

Abstract Kubota alloy HN is an austenitic Fe-Ni-Cr alloy with long-term creep-rupture properties that are intermediate between those of HK40 and HP40 alloys. Carburization resistance is better than that of HK40, but oxidation resistance is generally lower, making the alloy suitable for long service at 1095 deg C (2000 deg F). This datasheet provides information on composition, physical properties, and tensile properties as well as creep. It also includes information on high temperature performance and corrosion resistance as well as casting, machining, and joining. Filing Code: SS-1060. Producer or source: Kubota Metal Corporation, Fahramet Division.


Author(s):  
Chang Che ◽  
Gong Qian ◽  
Xisheng Yang

China has the most supercritical boilers in the world. Grade 91 steels are widely used for high temperature components of supercritical boiler. During high temperature service, microstructural evolution of Grade 91 steel may affect the mechanical properties, including creep strength. However, there are very few studies on quantitative assessment of microstructural evolution for Grade 91 steel, especially on precipitates content. In this article, microstructural evolution of Grade 91 was studied. A quantitative assessment of microstructure evolution was given during long-term creep, focusing on the precipitated phase content in Grade 91 steel. The results show, the precipitates content of Grade 91 steel has a corresponding relationship with creep damage.


Author(s):  
F. Abe

Critical issues for the development of high-Cr ferritic steels for USC power plant at 650°C are described in terms of long-term creep strength and oxidation resistance. Creep tests were carried out for 9Cr-3W-3Co-VNb steel at 650°C for up to about 6 × 104 h. The addition of boron as high as 100ppm or more in combination with minimized nitrogen, which causes no formation of boron nitride (BN) during normalizing heat treatment, is essential for the improvement of long-term creep strength of base metal and welded joints. The addition of nitrogen causes the precipitation of fine MX carbonitrides, which significantly improves the creep strength. However, excess addition of nitrogen promotes not only the formation of BN during normalizing heat treatment and of Z phase during creep in base metal but also the formation of fine grained heat affected zone in welded joints. Therefore, the boron and nitrogen contents should be optimized for the improvement of long term creep strength of base metal and welded joints. On the other hand, the candidate steels for boiler at 650°C should exhibit oxidation resistance in steam at 650°C better than that of Gr.91 in steam at 600°C, because Gr.91 is being now used for long duration in power plants operating at 600°C. However, existing 9 to 12Cr steels, such as P92 and P122, cannot satisfy the criterion for oxidation resistance in steam at 650°C. The formation of Cr-rich oxide scale is achieved by pre-treatments such as pre-oxidation treatment and coating, which significantly improves oxidation resistance in steam at 650°C and satisfies the criterion for oxidation resistance. The assessment of resistance to exfoliation is a key issue for the Cr-rich oxide scale.


Alloy Digest ◽  
1993 ◽  
Vol 42 (10) ◽  

Abstract ALTEMP HX is an austenitic nickel-base alloy designed for outstanding oxidation and strength at high temperatures. The alloy is solid-solution strengthened. Applications include uses in the aerospace, heat treatment and petrochemical markets. This datasheet provides information on composition, physical properties, elasticity, and tensile properties as well as fracture toughness and creep. It also includes information on low and high temperature performance, and corrosion resistance as well as forming, heat treating, and joining. Filing Code: Ni-442. Producer or source: Allegheny Ludlum Corporation.


Alloy Digest ◽  
1992 ◽  
Vol 41 (5) ◽  

Abstract INCO ALLOY 330 is a nickel/iron/chromium austenitic alloy, not hardenable by heat treatment. It is a solid solution strengthened high-temperature alloy. This datasheet provides information on composition, physical properties, elasticity, and tensile properties as well as creep. It also includes information on high temperature performance and corrosion resistance as well as forming, heat treating, machining, and joining. Filing Code: Ni-403. Producer or source: Inco Alloys International Inc..


Alloy Digest ◽  
1974 ◽  
Vol 23 (4) ◽  

Abstract ALUMINUM 3004 is nominally an aluminum-manganese-magnesium alloy which cannot be hardened by heat treatment; however, it can be strain hardened by cold working. It has higher strength than Aluminum 3003 and good workability, weldability and resistance to corrosion. This datasheet provides information on composition, physical properties, hardness, elasticity, tensile properties, and compressive and shear strength as well as fatigue. It also includes information on low and high temperature performance, and corrosion resistance as well as forming, heat treating, machining, and joining. Filing Code: Al-51. Producer or source: Various aluminum companies. Originally published June 1957, revised April 1974.


Alloy Digest ◽  
1963 ◽  
Vol 12 (1) ◽  

Abstract ALX is a composition of nonferrous materials with a cobalt base containing chromium, tungsten and carbon. This alloy is commonly supplied in the cast-to-shape form, having an as-cast hardness of Rockwell C60-62 and requiring no further heat treatment. ALX is also supplied as cast tool bit material and is useful where conventional high-speed steels or carbides do not function effectively. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties. It also includes information on high temperature performance and corrosion resistance as well as casting, forming, heat treating, and machining. Filing Code: Co-35. Producer or source: Allegheny Ludlum Corporation.


Sign in / Sign up

Export Citation Format

Share Document