Influence of Hydrogen Addition on Lean Premixed Methane-Air Flame Statistics

Author(s):  
Baris Yilmaz ◽  
Sibel O¨zdogan ◽  
Iskender Go¨kalp

Hydrogenated premixed methane/air flames under lean conditions are simulated in this study. The computational model of the high pressure chamber setup of Orleans - ICARE (France) has been developed. The k-ε turbulence model with Pope-correction is used for turbulence modeling. The laminar flame properties are computed using GRI-Mech 3.0 mechanism with Chemkin software package. The turbulent flame front statistics are investigated with three premixed combustion models, namely Zimont, Coherent Flame Model (CFM) and modified version of CFM model (MCFM) models. It has been observed that increasing the volumetric percentage of hydrogen in the mixture results in reducing the flame-end position. The flame brush thickness becomes thinner as well. Satisfactory results have been obtained compared to experiments.

2006 ◽  
Vol 2006 (0) ◽  
pp. 301-302
Author(s):  
Hideaki Kobayashi ◽  
Hideaki Kaneko ◽  
Soichirou Yata ◽  
Yasuhiro Ogami

2000 ◽  
Vol 124 (1) ◽  
pp. 58-65 ◽  
Author(s):  
W. Polifke ◽  
P. Flohr ◽  
M. Brandt

In many practical applications, so-called premixed burners do not achieve perfect premixing of fuel and air. Instead, fuel injection pressure is limited, the permissible burner pressure drop is small and mixing lengths are curtailed to reduce the danger of flashback. Furthermore, internal or external piloting is frequently employed to improve combustion stability, while part-load operation often requires burner staging, where neighboring burners operate with unequal fuel/air equivalence ratios. In this report, an extension of the turbulent flame speed closure (TFC) model for highly turbulent premixed combustion is presented, which allows application of the model to the case of inhomogeneously premixed combustion. The extension is quite straightforward, i.e., the dependence of model parameters on mixture fraction is accounted for by providing appropriate lookup tables or functional relationships to the model. The model parameters determined in this way are adiabatic flame temperature, laminar flame speed and critical gradient. The model has been validated against a test case from the open literature and applied to an externally piloted industrial gas turbine burner with good success.


Author(s):  
Marissa Brower ◽  
Eric Petersen ◽  
Wayne Metcalfe ◽  
Henry J. Curran ◽  
Marc Füri ◽  
...  

Applications of natural gas and hydrogen co-firing have received increased attention in the gas turbine market, which aims at higher flexibility due to concerns over the availability of fuels. While much work has been done in the development of a fuels database and corresponding chemical kinetics mechanism for natural gas mixtures, there are nonetheless few if any data for mixtures with high levels of hydrogen at conditions of interest to gas turbines. The focus of the present paper is on gas turbine engines with primary and secondary reaction zones as represented in the Alstom and Rolls Royce product portfolio. The present effort includes a parametric study, a gas turbine model study, and turbulent flame speed predictions. Using a highly optimized chemical kinetics mechanism, ignition delay times and laminar burning velocities were calculated for fuels from pure methane to pure hydrogen and with natural gas/hydrogen mixtures. A wide range of engine-relevant conditions were studied: pressures from 1 to 30 atm, flame temperatures from 1600 to 2200 K, primary combustor inlet temperature from 300 to 900 K, and secondary combustor inlet temperatures from 900 to 1400 K. Hydrogen addition was found to increase the reactivity of hydrocarbon fuels at all conditions by increasing the laminar flame speed and decreasing the ignition delay time. Predictions of turbulent flame speeds from the laminar flame speeds show that hydrogen addition affects the reactivity more when turbulence is considered. This combined effort of industrial and university partners brings together the know-how of applied, as well as experimental and theoretical disciplines.


Author(s):  
Wolfgang Polifke ◽  
Peter Flohr ◽  
Martin Brandt

In many practical applications, so-called premixed burners do not achieve perfect premixing of fuel and air. Instead, fuel injection pressure is limited, the permissible burner pressure drop is small and mixing lengths are curtailed to reduce the danger of flashback. Furthermore, internal or external piloting is frequently employed to improve combustion stability, while part-load operation often requires burner staging, where neighboring burners operate with unequal fuel/air equivalence ratios. In this report, an extension of the Turbulent Flame speed Closure (TFC) model for highly turbulent premixed combustion is presented, which allows application of the model to the case of inhomogeneously premixed combustion. The extension is quite straightforward, i.e. the dependence of model parameters on mixture fraction is accounted for by providing appropriate lookup tables or functional relationships to the model. The model parameters determined in this way are adiabatic flame temperature, laminar flame speed and critical gradient. The model has been validated against a test case from the open literature and applied to an externally piloted industrial gas turbine burner with good success.


2002 ◽  
Vol 462 ◽  
pp. 209-243 ◽  
Author(s):  
JUNICHI FURUKAWA ◽  
YOSHIKI NOGUCHI ◽  
TOSHISUKE HIRANO ◽  
FORMAN A. WILLIAMS

The density change across premixed flames propagating in turbulent flows modifies the turbulence. The nature of that modification depends on the regime of turbulent combustion, the burner design, the orientation of the turbulent flame and the position within the flame. The present study addresses statistically stationary turbulent combustion in the flame-sheet regime, in which the laminar-flame thickness is less than the Kolmogorov scale, for flames stabilized on a vertically oriented cylindrical burner having fully developed upward turbulent pipe flow upstream from the exit. Under these conditions, rapidly moving wrinkled laminar flamelets form the axisymmetric turbulent flame brush that is attached to the burner exit. Predictions have been made of changes in turbulence properties across laminar flamelets in such situations, but very few measurements have been performed to test the predictions. The present work measures individual velocity changes and changes in turbulence across flamelets at different positions in the turbulent flame brush for three different equivalence ratios, for comparison with theory.The measurements employ a three-element electrostatic probe (EP) and a two-component laser-Doppler velocimeter (LDV). The LDV measures axial and radial components of the local gas velocity, while the EP, whose three sensors are located in a vertical plane that passes through the burner axis, containing the plane of the LDV velocity components, measures arrival times of flamelets at three points in that plane. From the arrival times, the projection of flamelet orientation and velocity on the plane are obtained. All of the EP and LDV sensors are located within a fixed volume element of about 1 mm diameter to provide local, time-resolved information. The technique has the EP advantages of rapid response and good sensitivity and the EP disadvantages of intrusiveness and complexity of interpretation, but it is well suited to the type of data sought here.Theory predicts that the component of velocity tangent to the surface of a locally planar flamelet remains constant in passing through the flamelet. The data are consistent with this prediction, within the accuracy of the measurement. The data also indicate that the component of velocity normal to the flamelet, measured with respect to the flamelet, tends to increase in passing through the flamelet, as expected. The flamelets thereby can generate anisotropy in initially isotropic turbulence. They also produce differences in turbulent spectra conditioned on unburnt or burnt gas. Local modifications of turbulence by flamelets thus are demonstrated experimentally. The modifications are quantitatively different at different locations in the turbulent flame brush but qualitatively similar in that the turbulence is enhanced more strongly in the radial direction than in the axial direction at all positions in these flames.


Author(s):  
Marissa Brower ◽  
Eric L. Petersen ◽  
Wayne Metcalfe ◽  
Henry J. Curran ◽  
Marc Füri ◽  
...  

Applications of natural gas and hydrogen co-firing have received increased attention in the gas turbine market, which aims at higher flexibility due to concerns over the availability of fuels. While much work has been done in the development of a fuels database and corresponding chemical kinetics mechanism for natural gas mixtures, there are nonetheless few if any data for mixtures with high levels of hydrogen at conditions of interest to gas turbines. The focus of the present paper is on gas turbine engines with primary and secondary reaction zones as represented in the Alstom and Rolls Royce product portfolio. The present effort includes a parametric study, a gas turbine model study, and turbulent flame speed predictions. Using a highly optimized chemical kinetics mechanism, ignition delay times and laminar burning velocities were calculated for fuels from pure methane to pure hydrogen and with natural gas/hydrogen mixtures. A wide range of engine-relevant conditions were studied: pressures from 1 to 30 atm, flame temperatures from 1600 to 2200 K, primary combustor inlet temperature from 300 to 900 K, and secondary combustor inlet temperatures from 900 to 1400 K. Hydrogen addition was found to increase the reactivity of hydrocarbon fuels at all conditions by increasing the laminar flame speed and decreasing the ignition delay time. Predictions of turbulent flame speeds from the laminar flame speeds show that hydrogen addition affects the reactivity more when turbulence is considered. This combined effort of industrial and university partners brings together the know-how of applied as well as experimental and theoretical disciplines.


Author(s):  
S. Daniele ◽  
P. Jansohn

There is an obvious lack of data and understanding of the behavior of turbulent flames at high temperature and high pressure, especially concerning hydrogen containing fuels. Among the many relevant parameters, the turbulent flame speed “ST” is one of the most interesting for scientists and engineers. This paper reports an experimental investigation of premixed syngas combustion at gas-turbine like conditions, with emphasis on the determination of ST/SL derived as global fuel consumption per unit time. Experiments at pressures up to 2.00 MPa, inlet temperatures and velocities up to 773K and 150 m/s respectively, u′/SL greater than 100 are presented. Comparison between different syngas mixtures and methane clearly show much higher ST/SL for the former fuel. It is shown that ST/SL is strongly dependent on preferential diffusive-thermal (PDT) effects, co-acting with hydrodynamic effects, even for very high u′/SL. ST/SL increases with rising hydrogen content in the fuel mixture and with pressure. A correlation for ST/SL valid for all investigated fuel mixtures, including methane, is proposed in terms of turbulence properties (turbulence intensity and integral length scale), combustion properties (laminar flame speed and laminar flame thickness) and operating conditions (pressure and inlet temperature). The correlation captures effects of preferential diffusive-thermal and hydrodynamic instabilities.


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