Processing and Characterization of Hybrid Nanoparticle Infused Structural Fiber Composites

Materials ◽  
2005 ◽  
Author(s):  
Oladapo Akinyede ◽  
Ram Mohan ◽  
Ajit Kelkar ◽  
Jag Sankar ◽  
Ashish Pandya

Effective conventional manufacturing techniques are required to integrate the nanomaterial configurations into material systems at a larger component and structural level to obtain the enhanced benefits offered by the material configurations at the nano length scale. A low cost manufacturing process based on vacuum assisted resin transfer molding (VARTM) is demonstrated for the effective processing of fiber composite laminates using modified epoxy resin systems dispersed with nano and sub-micron alumina oxide particles. The effect of alumina oxide particles on the thermo physical properties (glass transition temperature, etc), are studied via differential scanning calorimetry and thermal gravimetric analysis. Higher glass transition temperatures with the alumina oxide and other nano particulate systems provide an opportunity to use conventional resin systems in high temperature applications. Ultrasonic mixing is employed to uniformly disperse the particles into an epoxy resin system. The flow characteristics of the modified resin system are not significantly different than the neat resin system and allowed the use of traditional VARTM processes successfully. The details of the resin modification and current studies on particulate modification for better interfacial bond are discussed in this paper. Wear performance for reinforced plastics are also investigated in this paper. Composite laminates with S2 glass and modified resins are fabricated. The mechanical behavior of the fabricated composite laminates with the neat and modified resin system using different sized and loading of alumina oxide particles are presented and discussed.

Author(s):  
Peter Owuor ◽  
Alfred Tcherbi-Narteh ◽  
Mahesh Hosur ◽  
Shaik Jeelani

Objective An experimental study was carried out to investigate the solvent uptake in E-glass/Carbon Fiber composites with two types of epoxy systems: SC-15 and 635 epoxy resins in water, saltwater and antifreeze. These resins were infused into carbon, E glass and a hybrid of carbon and E-glass fabrics. Unconditioned samples with 635 epoxy resin system showed better flexural properties in case of both carbon fiber and hybrid composites but poor response when used as a matrix for E-glass fibers compared to SC-15 epoxy resin. Flexural properties for conditioned samples were determined after an immersion period of 8 weeks at room temperature and results showed that the 635 epoxy resin has a poor retention of flexural properties compared to SC-15 epoxy resin with highest degradation recorded for samples fabricated using E-glass fabrics. Moisture absorption curves did not follow the Fick’s law of diffusion except for first week of immersion. Lowest solvent uptake was recorded in antifreeze while highest was recorded in saltwater. Low operation temperature was exhibited by 635 epoxy resin with lower values of glass transition temperature compared to SC-15 epoxy resin. Storage modulus and glass transition temperatures determined from dynamic mechanical analysis (DMA) showed that composites with 635 epoxy resin system had better storage modulus while those with SC-15 had higher glass transition temperatures. Highest degradation in storage modulus was seen in E-glass-635 epoxy samples when conditioned with salt water while the maximum reduction in the glass transition temperature was seen for E-glass-635 epoxy samples conditioned with water.


2015 ◽  
Vol 1101 ◽  
pp. 8-14
Author(s):  
Qing Qing Wu ◽  
Jia Yu Xiao ◽  
Jun Liu ◽  
Su Li Xing ◽  
Jing Shui Yang

The properties of heat resistance and manufacturability of epoxy resin system are contradictory to each other. In order to maintain the balance of both properties, this article studied the heat resistance (testing the glass-transition temperature using differential scanning calorimetry) and the manufacturability (characterizing the variation trend of viscosity at molding temperature using AR2000EX rotational rheometer) of two kinds of epoxy resin systems by means of designing orthogonal table. Studies show that when the mass ratio of hydantoin epoxy resin, MF-4101 epoxy resin, anhydride and accelerant is 100:20:150:1.5, the glass transition temperature of the epoxy resin system can reach over 180°C. What’s more, the initial viscosity of the epoxy resin at 40°C is about 230mPa•s, and the viscosity can maintain no more than 800mPa•s in approximately 3 hours, which meets the requirements of liquid composite molding.


2010 ◽  
Vol 92 (9) ◽  
pp. 2252-2257 ◽  
Author(s):  
Celeste M.C. Pereira ◽  
Paulo Nóvoa ◽  
Marta Martins ◽  
Stefan Forero ◽  
Felicitas Hepp ◽  
...  

1997 ◽  
Vol 13 (09) ◽  
pp. 848-852
Author(s):  
Chen Tong-Hui ◽  
◽  
Bai Yao-Wen ◽  
Sun Ren-Hui

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