Binders Used for the Manufacturing of Composite Materials by Liquid Composite Molding

Binders, or tackifiers, have become widespread in the production of new composites materials by liquid composite molding (LCM) techniques due to their ability to stabilize preforms during laying-up and impregnation, as well as to improve fracture toughness of the obtained composites, which is very important in aviation, automotive, ship manufacturing, etc. Furthermore, they can be used in modern methods of automatic laying of dry fibers into preforms, which significantly reduces the labor cost of the manufacturing process. In this article, we review the existing research from the 1960s of the 20th century to the present days in the field of creation and properties of binders used to bond various layers of preforms in the manufacturing of composite materials by LCM methods to summarize and synthesize knowledge on these issues. Different binders based on epoxy, polyester, and a number of other resins compatible with the corresponding polymer matrices are considered in the article. The influence of binders on the preforming process, various properties of obtained preforms, including compaction, stability, and permeability, as well as the main characteristics of composite materials obtained by various LCM methods and the advantages and disadvantages of this technology have been also highlighted.

RANCANG BANGUN ALAT CETAK KOMPOSIT SAMPAH PLASTIK DENGAN SABUT KELAPA

The plastic waste composite molding tool with coconut fiber is designed with the aim of converting HDPE plastic waste, especially drink bottle covers mixed with coconut fiber into a product in the form of a composite board (panel) that is more useful. The dimensions of the mold are 410 x 540 mm, the tool height is 850 mm, the width is 600 mm, the length is 600 mm, the temperature of the installed heating elements is around 200-250 degrees for 12 pieces, 220 V 1000 watts, while the press uses a 10 ton hydraulic jack. While the heating temperature for pressing the composite board is set in the range of 130 – 180 oC. From the results of the first printing press with iron plate material, the resulting product is sticky on the plate surface, the second test is coated with aluminum foil, the resulting product is less than perfect because the surface is uneven. , while the third test was coated with a stainless steel plate, the resulting product was better than the previous results. This research needs to be improved in order to assist the government in handling plastic waste. In addition, the results of products with this tool will help improve people's skills and improve the economy of the products of this tool.

Transparent Fiber-Reinforced Composites Based on a Thermoset Resin Using Liquid Composite Molding (LCM) Techniques

In this study, optically transparent glass fiber-reinforced polymers (tGFRPs) were produced using a thermoset matrix and an E-glass fabric. In situ polymerization was combined with liquid composite molding (LCM) techniques both in a resin transfer molding (RTM) mold and a lite-RTM (L-RTM) setup between two glass plates. The RTM specimens were used for mechanical characterization while the L-RTM samples were used for transmittance measurements. Optimization in terms of the number of glass fabric layers, the overall degree of transparency of the composite, and the mechanical properties was carried out and allowed for the realization of high mechanical strength and high-transparency tGFRPs. An outstanding degree of infiltration was achieved maintaining up to 75% transmittance even when using 29 layers of E-glass fabric, corresponding to 50 v. % fiber, using an L-RTM setup. RTM specimens with 44 v. % fiber yielded a tensile strength of 435.2 ± 17.6 MPa, and an E-Modulus of 24.3 ± 0.7 GPa.

Compression Resin Transfer Molding Using Inflatable Seals

Compression resin transfer molding using inflatable seals is a new variant of LCM (“Liquid composite molding”) processes, which uses the inflatable seals to compress the fiber reinforcements and drive the resin to impregnate the fabric preform, resulting to fill the entire mold cavity. During resin injection, the preform is relaxed. Consequently, the resin enters easily and quickly into the mold cavity. After, the necessary resin is injected into the mold cavity, the compression stage takes place, in a stepwise manner, by swelling the inflatable seals. The objective of this paper is to present this new process and study the effect of the number of inflatable seals on the filling time.

Development of a Reactive Polyurethane Foam System for the Direct Sandwich Composite Molding (D-SCM) Process

Sandwich structures utilize the geometric stiffening effect by increasing the area moment of inertia. This reduces carbon fiber (CF) material within CF-reinforced plastic (CFRP) components, and thus, the CO2 footprint. A suitable material combination for lightweight design is the use of continuous fiber-reinforced face sheets with a light foam core. CFRP sandwich structures with foam core are manufactured by combining a prefabricated foam core with fiber-reinforced cover layers in a two-step press process. Besides the reduction of the used CFRP material, more efficient manufacturing processes are needed. The aim of this paper is to develop a novel polyurethane foam system to enable the direct sandwich composite molding (D‑SCM) process for the production of CFRP sandwich structures by utilizing the resulting foaming pressure during the reactive polyurethane (PUR) foam system expansion for the impregnation of the CF reinforced face sheets. The developed formulation enables D-SCM structures with 150–250 kg/m3 foam density and 44–47.5% fiber volume content, based on a preliminary evaluation.

Modeling and Simulation of the Robotic Layup of Fibrous Preforms for Liquid Composite Molding

In recent years, the concepts of industry 4.0 are widely spreading in many different sectors, from agriculture to home automation, from transportation systems to manufacturing processes. One of the pillars of this concept is related to the use of robotic cells. The focus of the present work is the robotic automated layup of dry fibrous preforms to be employed in liquid composite molding (LCM) processes. In particular, the article describes a software tool developed to simulate the automated placement and layup of fiber fabrics and tissues on complex shape molds by means of a robotic system. The tool has been coded in Matlab language. An end-effector has been appositely designed for the fiber layup and it has been included in the model. The simulation provides as output the path generation and the configuration of the robotic arm and of end effector along the entire layup process. The implemented code has been compared with the commercial software RoboDK.

Modeling the reactive PA6 flow for LCM processes

Fiber reinforced thermoplastic composites have shown to be attractive for industry as they can be reused, reshaped, welded and repaired, while keeping mechanical properties on par with thermoset composites. Since thermoplastics usually have high melt viscosities unsuitable for liquid composite molding processes, in-situ synthesis of PA6 from ε-caprolactam is considered. Its reactive mix has low viscosity which allows impregnation. However, the coupled crystallization and polymerization affects the resin viscosity and its flow is altered by the dual-scale permeability of the fiber preform. Thus, to predict the local differences in the thermoplastics properties, a coupled polymerization crystallization model needs to be integrated in the LCM processing simulation at representative scales. This study aims to propose a reliable simulation of the resin flow through a fibrous preform. Hence, viscosity measurements on the reactive mix are achieved using a rheometer with parallel-plate geometry, aiming to associate a viscosity model with the Hillier coupled polymerization-crystallization model previously determined by Vicard. The full chemorheological model will then be integrated into a simulation of LCM process in OpenFOAM®, an open source CFD software in order to follow the extent of the synthesis in the resin flow during the process. As a future work, simulations including microscale tow information extracted from a real textile specimen will permit to investigate the effect of permeability and double scale porosity in fibrous preforms on the final polymerization rate and crystallinity.