Preparations and Photovoltaic Properties of Thin Films Using Soluble Fulleropyrrolidine Derivatives for Organic Solar Cells

Author(s):  
Mi-Ra Kim ◽  
Won Suk Shin ◽  
Sung-Ho Jin ◽  
Kastuhiko Fujida ◽  
Testuo Tsutsui ◽  
...  

Organic solar cells made from bi-layer thin-film heterojunctions having poly((2-methoxy-5-(2′-ethylhexyloxy)-p-phenylene)vinylene) (MEH-PPV) as an electron donor and fulleropyrrolidine derivatives as an electron acceptor were investigated. We synthesized soluble fulleropyrrolidine derivatives substituted different chain lengths for the organic solar cell. Due to the high solubility and sufficiently long chain length of fulleropyrrolidine derivatives, though those are monomers, a thin film (about 50 nm) could be fabricated individually by the spin-coating method. The fill factor of the bi-layer device was achieved to be 0.40, which is higher than that of the single-layer device by a polymer/fulleropyrrolidine derivative blend film of 0.29, due to the decrease of the recombination.

2013 ◽  
Vol 46 (43) ◽  
pp. 435502 ◽  
Author(s):  
Yun-Shiuan Li ◽  
Chih-Hung Tsai ◽  
Shao-Hsuan Kao ◽  
I-Wen Wu ◽  
Jian-Zhang Chen ◽  
...  

Green ◽  
2011 ◽  
Vol 1 (1) ◽  
Author(s):  
Yongbo Yuan ◽  
Jinsong Huang ◽  
Gang Li

AbstractTandem structures can boost the efficiency of organic solar cell to more than 15%, compared to the 10% limit of single layer bulk heterojunction devices. Design and fabricating of intermediate layers plays a very important role to achieve high device performance. This article will review the main experimental progresses of tandem organic solar cells, and focus on the intermediate layers (charge recombination layers) in both thermal evaporated and solution processed organic tandem solar cell devices.


2020 ◽  
Vol 530 ◽  
pp. 147164
Author(s):  
Hatem Taha ◽  
Khalil Ibrahim ◽  
M Mahbubur Rahman ◽  
David J. Henry ◽  
Chun-Yang Yin ◽  
...  

2014 ◽  
Vol 16 (29) ◽  
pp. 15107-15110 ◽  
Author(s):  
K. D. M. Rao ◽  
Christoph Hunger ◽  
Ritu Gupta ◽  
Giridhar U. Kulkarni ◽  
Mukundan Thelakkat

We study the incorporation of a highly transparent and highly conducting Ag metallic network obtained using a cracked polymer template, in a thin film organic solar cell for the first time.


2020 ◽  
Vol 44 (27) ◽  
pp. 11441-11447 ◽  
Author(s):  
Pablo Simón Marqués ◽  
José María Andrés Castán ◽  
Pierre Josse ◽  
Martin Blais ◽  
Amir Hossein Habibi ◽  
...  

The synthesis of two N,N-bis(4-biphenylyl)aniline (BPA) based push–pull is reported herein. Evaluation as donor materials in all-small-molecule planar-heterojunction organic solar cells lead to impressive fill factor (>73%) and promising power conversion efficiencies.


2019 ◽  
Author(s):  
Matthew Morgan ◽  
Maryam Nazari ◽  
Thomas Pickl ◽  
J. Mikko Rautiainen ◽  
Heikki M. Tuononen ◽  
...  

The electrophilic borylation of 2,5-diarylpyrazines results in the formation of boron-nitrogen doped dihydroindeno[1,2-<i>b</i>]fluorene which can be synthesized via mildly air-sensitive techniques and the end products handled readily under atmosphereic conditions. Through transmetallation via diarylzinc reagents a series of derivatives were sythesized which show broad absorption profiles that highlight the versatility of this backbone to be used in organic solar cell devices. These compounds can be synthesized in large yields, in alow number of steps and functionalized at many stages along the way providing a large depth of possibilities. Exploratory device paramaters were studied and show PCE of 2%.


Author(s):  
Jie Lv ◽  
Hua Tang ◽  
Jiaming Huang ◽  
Cenqi Yan ◽  
Kuan Liu ◽  
...  

Due to the barrierless free charge generation, low charge trapping, and high charge mobilities, the PM6:Y6 organic solar cell (OSC) achieves excellent power conversion efficiency (PCE) of 15.7%. However, the...


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