Influence of Oxidation on Long-Term Creep Strength of ASME Grade 23 Steel

Author(s):  
Kazuhiro Kimura ◽  
Kota Sawada ◽  
Masakazu Fujitsuka ◽  
Hideaki Kushima

Creep test of ASME Grade 23 steel has been conducted at 625 and 650°C in helium gas atmosphere. Long-term creep strength of the steel in helium gas was compared with that in air and the influence of oxidation on long-term creep strength was investigated. Creep rupture strength drop was observed in the long-term at 625 and 650°C in air, and the same creep rupture strength drop was observed also in helium gas at 625°C. On the other hand, although creep rupture strength drop was observed in the long-term at 650°C in helium gas, creep rupture life in the long-term in helium gas was slightly longer than that in air at 650°C. Creep rupture life in the long-term at 650°C in air is reduced by not only degradation due to microstructural change, but also marked oxidation, however, that at 625°C is considered to be shortened mainly by a degradation caused by microstructural change. Long-term creep strength of ASME Grade 23 steel at 600°C and above should be reevaluated in consideration of strength drop due to microstructural change.

Author(s):  
Masatsugu Yaguchi ◽  
Takuaki Matsumura ◽  
Katsuaki Hoshino

Creep rupture data of welded joints of ASME Grades 91, 92 and 122 type steels have been collected and long-term creep rupture strength of the materials has been evaluated. Similar study was conducted by the SHC Committee in 2004 and 2005, therefore, the evaluation of the creep rupture strength was conducted with emphasis on the long-term creep rupture data obtained after the previous study, in addition to discussion of the effects of product form, welding procedure and test temperature etc. on the creep strength. Almost the same results were obtained on the welded joint of Grade 92 as the previous study, however, the master creep life equations for the welded joints of Grades 91 and 122 were lower than the previous results, especially in the case of Grade 122. Furthermore, the creep strength reduction factor obtained from 100,000 hours creep strength of welded joints and base metal was given as a function of temperature.


Author(s):  
Kazuhiro Kimura ◽  
Hideaki Kushima ◽  
Kota Sawada ◽  
Yoshiaki Toda

Overestimation of long-term creep strength of creep strength enhanced ferritic steels is caused by inflection of a relation between stress and time to rupture. Creep rupture strength of those steels has been re-evaluated by a region splitting analysis and allowable tensile stress of some steels regulated in METI (Ministry of Economy, Trade and Industry) Thermal Power Standard Code in Japan has been reduced. A region splitting analysis method evaluates creep rupture strength in the short- and the long-term individually, which is separated by 50% of 0.2% offset yield stress. Inflection of stress vs. time to rupture curve is attributable to longer creep rupture life with a stabilized microstructure of creep strength enhanced ferritic steels, since tensile strength property, which determines short-term creep rupture strength, remains the same level. Accuracy of creep rupture strength evaluation is improved by region splitting analysis. Delta ferrite produces concentration gap due to difference in equilibrium composition of austenite and ferrite at the normalizing temperature. It increases driving force for diffusion and promotes recovery of tempered martensite adjacent to delta-ferrite. Concentration gap may be produced also in heat affected zone (HAZ), especially in fine grain HAZ similar to that in dual phase steel, and it has possibilities to promote recovery and, therefore, to decrease creep strength.


Author(s):  
Kazuhiro Kimura ◽  
Yukio Takahashi

Creep rupture data of ASME Grades 91, 92 and 122 type steels have been collected and long-term creep rupture strength of the steels has been evaluated. Similar study was conducted by the SHC committee in 2004 and 2005, therefore, the evaluation of long-term creep rupture strength was conducted with emphasis on the long-term creep rupture data obtained after the previous study. Creep rupture strength was analyzed by means of region splitting analysis method in consideration of 50% of 0.2% offset yield strength, in the same way as the previous study. Almost the same results were obtained on base metal of Grade 92 as the previous study, however, evaluated 100,000 hours creep rupture strength of base metal of Grades 91 and 122 were lower than the previous results. For Grades 91 and 122 type steels, moreover, creep rupture strength of the plate steel were lower than those of pipe and forging steels. Tendency to decrease with increase in nickel content was observed on long-term creep rupture strength of tube steel of Grade 91 at 600°C. According to the evaluation of long-term creep strength of the steels, allowable tensile stress was reviewed and proposed revision was concluded.


2017 ◽  
Vol 139 (5) ◽  
Author(s):  
K. Maruyama ◽  
N. Sekido ◽  
K. Yoshimi

Predictions as to 105 h creep rupture strength of grade 91 steel have been made recently. The predicted values are examined with long-term creep rupture data of the steel. Three creep rupture databases were used in the predictions: data of tube products of grade 91 steel reported in National Institute for Materials Science (NIMS) Creep Data Sheet (NIMS T91 database), data of T91 steel collected in Japan, and data of grade 91 steel collected by an American Society of Mechanical Engineers (ASME) code committee. Short-term creep rupture data points were discarded by the following criteria for minimizing overestimation of the strength: selecting long-term data points with low activation energy (multiregion analysis), selecting data points crept at stresses lower than a half of proof stress (σ0.2/2 criterion), and selecting data points longer than 1000 h (cutoff time of 1000 h). In the case of NIMS T91 database, a time–temperature parameter (TTP) analysis of a dataset selected by multiregion analysis can properly describe the long-term data points and gives the creep rupture strength of 68 MPa at 600 °C. However, TTP analyses of datasets selected by σ0.2/2 criterion and cutoff time of 1000 h from the same database overestimate the data points and predict the strength over 80 MPa. Datasets selected by the same criterion from the three databases provide similar values of the strength. The different criteria for data selection have more substantial effects on predicted values of the strength of the steel than difference of the databases.


2010 ◽  
Vol 96 (10) ◽  
pp. 620-628 ◽  
Author(s):  
Masahiko Arai ◽  
Kentaro Asakura ◽  
Hiroyuki Doi ◽  
Hirotsugu Kawanaka ◽  
Toshihiko Koseki ◽  
...  

2007 ◽  
Vol 345-346 ◽  
pp. 553-556 ◽  
Author(s):  
Hassan Ghassemi Armaki ◽  
Kouichi Maruyama ◽  
Mitsuru Yoshizawa ◽  
Masaaki Igarashi

Recent researches have shown the premature breakdown of creep rupture strength in long term creep region of advanced high Cr ferritic steels. As safe operation of power plants becomes a serious problem we should be able to detect and predict the breakdown transition of creep rupture strength. Some methods for detecting the breakdown transition have been presented till now like the measurement of reduction of area after creep rupture and particle size of laves phase. However it will be more economic if we make use of non-destructive tests, for example, hardness testing. In this paper 3 types of ferritic steels with different Cr concentration have been studied. The results suggest that the hardness of aged structures is constant independently of exposure time in short term region, whereas the hardness breaks down in long term region. The boundary of breakdown in hardness coincides with that of breakdown in creep rupture strength.


Author(s):  
Walter Bendick ◽  
Jean Gabrel ◽  
Bruno Vandenberghe

The application of new heat resistant steels in power plants requires reliable long term creep rupture strength values as basis for design. Modern martensitic 9% Cr-steels have complex microstructures that change with service exposure. That is why extrapolations of long term strength properties will be most difficult. Due to new long term test results, re-assessments became necessary for grades 911 and 92. Different methods have been used. Good agreement was obtained between a graphical and the numerical ISO 6303 method. In both cases a two-step assessment procedure was used. First the raw data was prepared in a suitable way, which was followed by mathematical averaging procedures. For comparison a Larson-Miller analysis on the raw data was performed, too. The results turned out to be too optimistic at temperatures higher than 575°C (1050°F). It is shown that a suitable preparation of data can improve the Larson-Miller assessment. As a result of the new assessments the design values had to be reduced for both grades. With respect to previous assessments the new values are up to almost 10% lower. In the case of grade 92 the difference from the former ASME values are even higher. Consequences concerning design and service operation are discussed.


Author(s):  
Masatsugu Yaguchi ◽  
Kaoru Nakamura ◽  
Sosuke Nakahashi

Creep rupture data of welded joints of ASME Grade 91 type steel have been collected from Japanese plants, milling companies and institutes, and the long-term creep rupture strength of the material has been evaluated. This evaluation of welded joints of Grade 91 steel is the third one in Japan as similar studies were conducted in 2004 and 2010. The re-evaluation of the creep rupture strength was conducted with emphasis on the long-term creep rupture data obtained since the previous study, with durations of the new data of up to about 60000h. The new long-term data exhibited lower creep strength than that obtained from the master creep life equation for welded joints of Grade 91 steel determined in 2010, then the master creep life equation was again reviewed on the basis of the new data using the same regression method as that used in 2010. Furthermore, the weld strength reduction factors obtained from 100000h creep strength of welded joints and the base metals are given as a function of temperature, where the master creep equations of the base metals are also redetermined in this study.


Author(s):  
Kazuhiro Kimura ◽  
Kota Sawada ◽  
Hideaki Kushima

Creep rupture strength and ductility of Creep Strength Enhanced Ferritic steels of Grades 23, 91, 92 and 122 was investigated with particular emphasis on remarkable drop in the long-term. Large difference in creep rupture strength and ductility was observed on three heats of Grade 23 steels. Remarkable drop of creep rupture strength in the long-term of T91 was comparable to those of Grades 92 and 122. Remarkable drop in creep rupture ductility in a stress regime below 50% of 0.2% offset yield stress was observed on Grade T23 steel, however, that of Grade P23 steel did not indicate any degradation of creep rupture ductility. Higher creep rupture ductility of Grade P23 steel was considered to be caused by its lower creep strength than that of T23 steels. Creep rupture ductility of Grades 92 and 122 steels indicated rapid and drastic decrease with decrease in stress at 50% of 0.2% offset yield stress. Stress dependence of creep rupture ductility of Grades 92 and 122 steels was well described by a ratio of stress to 0.2% offset yield stress, regardless of temperature. On the other hand, large drop in creep rupture ductility of Grade 91 steel was observed only in the very low stress regime at 650°C. Alloying elements including impurities and changes in precipitates may influence on creep rupture ductility, however, remarkable drop in ductility of the steels cannot be explained by chemical composition and precipitates. High ductility in the high stress regime above 50% of 0.2% offset yield stress should be provided by easy plastic deformation, and it has been concluded that a remarkable drop in ductility in the low stress regime is derived from a concentration of creep deformation into a tiny recovered region formed at the vicinity of grain boundary.


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