Electrochemical Corrosion Behavior of Heat Treated HVOF Coatings on ASTM SA213-T22 steel

Herein we report the electrochemical corrosion behavior of pre and post heat-treated composite coatings of NiCrMoFeCoAl-30%SiO2 and NiCrMoFeCoAl-30%Cr2O3 on ASTM SA213-T22 boiler tube steel by high velocity oxygen fuel (HVOF) spraying technique. The samples were subjected to hot molten salt (Na2SO4–60%V2O5) corrosion environment in a tubular furnace at 7000C under thermocyclic conditions. The microscopic, structural and electrochemical investigations of post-heat treated specimens reveal NiCrMoFeCoAl-30%Cr2O3 composite HVOF coating exhibits a superior corrosion resistance compared to NiCrMoFeCoAl-30%SiO2 composite coating and bare ASTM SA213-T22 steel boiler tube steel in neutral electrolyte. The room temperature potentiodynamic and impedance investigations of heat-treated samples suggest high interfacial charge transfer resistance for HVOF coatings over a wide anodic potential window. This could be ascribed to the protective nature of the chromium oxide containing coatings on high temperature treatment. AC impedance analysis reveals NiCrMoFeCoAl-30%Cr2O3 coating exhibits very high resistive behaviour with very high charge transfer resistance, in the order of 106 Ohm higher than the NiCrMoFeCoAl-30%SiO2 coating and uncoated ASTM SA213-T22 steel boiler tube steel. Furthermore, the high temperature induced formation of metal chromates/chromites along with the presence of Cr2O3 provides good resistance towards corrosion.

Hot corrosion behaviour of CNT-reinforced ZrO2-Y2O3 composite coatings on boiler tube steel at 900°C

Purpose In Indian thermal power plants, the main cause of boiler tube failure is the presence of molten sulphates and vanadates, which deteriorate the tube material at high temperatures. To combat the hot corrosion failure of metals, thermal spray technology is adopted. This study aims to investigate and study the effect of hot corrosion behaviour of carbon nanotube (CNT)-reinforced ZrO2-Y2O3 composite coatings on T-91 boiler tube steel in a molten salt environment at 900 °C for 50 cycles. Design/methodology/approach A plasma spray technique was used for development of the coatings. The samples were exposed to hot corrosion in a silicon tube furnace at 900 °C for 50 cycles. After testing, the test coupons were analysed by X-ray diffraction, scanning electron microscopy/energy dispersive spectroscopy and cross-sectional analysis techniques to aid understanding the kinetics of the corrosion reaction. Findings CNT-based reinforced coatings showed lower weight gain along with the formation of protective oxide scales during the experimentation. Improvement in protection against hot corrosion was observed with increase in CNT content in the coating matrix. Originality/value It is pertinent to mention here that the high temperature behaviour of CNT-reinforced ZrO2-Y2O3 composite on T-91 steel at 900°C temperature in molten salt environment has never been studied. Thus, the present research was conducted to provide useful results for the application of CNT-reinforced composite coatings at elevated temperature.

Case Study to Evaluate Stresses in Welded Endplates in Structural Steel

Endplates are widely used in the industry to attach supplementary steel structures to main building frames. These endplates can be attached to the building steel using a bolted connection or a welded connection. Industry often favors bolted connections due to ease of installation and availability of qualification methods per AISC 360 Design Guides. However, there are some applications where a welded connection is preferable, such as, cases requiring reduction of number of parts supplied or applications with higher chance of vibration causing loosening of bolts. The present case study discusses evaluation of stresses in welded endplates due to forces and moments from the attaching supplementary steel members. The study considers various welded connection scenarios including an endplate welded on two opposite sides and an endplate welded on all four sides. The stress distribution in the plate is studied using finite element analysis with wide flange and tube steel members attaching to it. ANSYS mechanical is used to perform the finite element analysis. Multiple combinations of plate sizes, weld patterns, and attaching member sizes are analyzed to provide a well-rounded solution. An analytical model is developed for the stress evaluation as well and the results are compared with the finite element model. The study is intended to provide an efficient methodology for plate evaluation and qualification.

Experimental Analysis of Hot Corrosion Behaviour of some Composite Coatings on Boiler Steel at Elevated Temperature

Hot corrosion is the main reason of failure of boiler tubes used at high temperature in thermal power plants. This paper is an attempt to investigate the effect of different composite coatings on boiler tube steel in corrosive environment of Na2SO4 – 60%V2O5 at 900°C for 50 cycles. The coatings have been deposited with high velocity oxy fuel process. The samples were exposed to hot corrosion in a Silicon tube furnace at 900°C for 50 cycles. The kinetics of corrosion behaviour were analysed by the weight gain measurements after each cycle. Corrosion products were analysed with weight change statistics, X-ray diffraction, and scanning electron microscopy. It is found that 100Cr3C2 composite coatings provided the higher resistance to corrosion as compared to other types of coatings. Cr carbide layer was formed on the surface and these layers provided the protection from hot corrosion.

Influence of External Action on the Internal Structure of Continuously Cast Slab Produced from Tube Steel

The paper compares the internal structure of two continuously cast slabs with a section of 300 × 2600 mm from a tube steel of the strength class K60, one of which is molded with a soft reduction, and the other is without external influence. A comparative analysis of the structure of two templates showed that the location of areas with an increased metal pickle ness in the axial part of the templates varies. On the template from a slab cast without reduction, this section is below the geometric center of the work-piece in thickness, at a distance of 49.2% from the underside, that is, the "lower" asymmetry of the slab structure is observed. On the template from the slab cast off with soft reduction, the area with an increased pickle-ness is located above the middle of the work-piece: at a distance of 51.7% of the side of the large radius, an "upper" asymmetry of the slab structure is formed. Consequently, as a result of the external action on the cast work-piece, the location of the axial sponginess, relative to the geometric centre of the slab, is changed by moving from the lower to the upper half of the work-piece. The metal of the axial part of the reduced slab has a denser structure, the degree of development of axial looseness in the metallographic evaluation is reduced by an average of 0.5 points. The work shows the change in the content of chemical elements along the thickness of slabs. In the reduced metal, the maximum value of the degree of zonal inhomogeneity of the most impurities is higher than in the metal without external influence. This is explained by the fact that, as a result of reduction, the zone of location of the axial chemical heterogeneity in the slab becomes smaller in width.

Interrelation of CCM (Steel Billet Continuous Casting Machine) Tube Steel Casting Parameters and Hot-Rolled Plate Quality

The quality of the hot-rolled plate up to 36 mm thick was estimated by the percentage of rolled products, sorted due to the presence of a surface defect "Non-metallic inclusions", and internal defects, detected by ultrasonic plate control. The analysis of the data on the total sorting of hot-rolled plates demonstrated that the amount of sorting differs significantly on the melting from which each series of tubular metal casting commenced, compared to all the other melting in the series. The sorting of the sheets rolled from the metal of the first in a series of melting proved to be 1.9 times higher than that of the metal of all other melts. The main reason (in 68% of cases) of sorting is the presence of non-metallic inclusions on the surface of the plates. The effect of sorting of hot-rolled plates on non-metallic inclusions of various parameters has been studied: the duration of the intermediate ladle-heating; the length of time from the end of the heating of the intermediate ladle, prior to the beginning of the casting; lining temperatures of the intermediate ladle before the beginning of casting; duration of filling the intermediate ladle; the filling rate of the intermediate ladle with metal; mass of metal in the intermediate ladle before the beginning of casting into the crystallizer; chemical composition of metal; overheating of the metal over the liquidus point at the beginning, middle and end of the casting. On the sorting of flat products for non-metallic inclusions, of all the parameters considered, a statistically significant effect is due only to the overheating of the metal above the liquidus point, which varies in the range from 19 to 35 ° C. In order to obtain an acceptable quality of both the surface of slabs and the surface of hot-rolled plates for non-metallic inclusions, the first in a series of melts recommends overheating of the metal in the intermediate ladle above the liquidus temperature of 30-35 ° C.

Investigation of Temperature-Time Modes of Rolling of Thick-Sheet Steel and Mechanical Properties of Finished Products

The article is devoted to the study of technological modes of hot rolling of tube steel on a thick-sheet mill and mechanical properties of the finished products. Five slabs were rolled under the experimental regime in accordance with the study plan. The temperature conditions of rolling at the final stage of deformation and the modes of accelerated cooling of rolled products were changed. Dependencies between technological parameters and mechanical properties allowed developing recommendations on improvement of technology of rolling and of the subsequent accelerated cooling of metal.