Phosphate content influence on structural, spectroscopic, and lasing properties of Er,Yb-doped potassium-lanthanum phosphate glasses

2016 ◽  
Vol 55 (4) ◽  
pp. 047102 ◽  
Author(s):  
Jan Šulc ◽  
Richard Švejkar ◽  
Helena Jelínková ◽  
Karel Nejezchleb ◽  
Karel Nitsch ◽  
...  
2000 ◽  
Author(s):  
Richard K. Brow ◽  
Ezz Metwalli ◽  
David L. Sidebottom

2002 ◽  
Vol 297 (2-3) ◽  
pp. 263-274 ◽  
Author(s):  
Uwe Hoppe ◽  
EzzEldin Metwalli ◽  
Richard K Brow ◽  
Jörg Neuefeind

2015 ◽  
Vol 17 (35) ◽  
pp. 22855-22861 ◽  
Author(s):  
Keiga Kawaguchi ◽  
Takuya Yamaguchi ◽  
Takahisa Omata ◽  
Toshiharu Yamashita ◽  
Hiroshi Kawazoe ◽  
...  

Phase separation and crystallization forming H3PO4 occurred in sodium lanthanum phosphate glasses after electrochemical substitution of sodium ions with protons, although the glass exhibited significant proton conductivity.


2000 ◽  
Vol 15 (11) ◽  
pp. 2463-2467 ◽  
Author(s):  
Nancy E. Rashid ◽  
Brian L. Phillips ◽  
Subhash H. Risbud

Lanthanum phosphate glasses were synthesized by melt quenching and characterized by x-ray diffraction, electron microprobe analysis, and solid-state nuclear magnetic resonance spectroscopy. A range of compositions near the metaphosphate composition (75 mol% P2O5) was examined. Comparison of 31P chemical shifts and shielding anisotropies of glasses with those of the crystalline phases of La(PO3)3 (metaphosphate) and LaP5O14 (pentaphosphate) were consistent with the presence of primarily chainlike Q2 phosphate groups.


2014 ◽  
Vol 392-393 ◽  
pp. 31-38 ◽  
Author(s):  
Armando Mandlule ◽  
Franziska Döhler ◽  
Leo van Wüllen ◽  
Toshihiro Kasuga ◽  
Delia S. Brauer

2005 ◽  
Vol 19 (0) ◽  
pp. 284-287
Author(s):  
KOUSUKE UOE ◽  
TOSHIYUKI MIYAUCHI ◽  
HIDEHIKO MORI ◽  
MAKOTO WATANABE ◽  
YOSHIHIRO ABE

1999 ◽  
Vol 10 (0) ◽  
pp. 527-533
Author(s):  
NANCY E. MYERS ◽  
BRIAN L. PHILLIPS ◽  
SUBHASH H. RISBUD

Author(s):  
J. C. Wheatley ◽  
J. M. Cowley

Rare-earth phosphates are of particular interest because of their catalytic properties associated with the hydrolysis of many aromatic chlorides in the petroleum industry. Lanthanum phosphates (LaPO4) which have been doped with small amounts of copper have shown increased catalytic activity (1). However the physical and chemical characteristics of the samples leading to good catalytic activity are not known.Many catalysts are amorphous and thus do not easily lend themselves to methods of investigation which would include electron microscopy. However, the LaPO4, crystals are quite suitable samples for high resolution techniques.The samples used were obtained from William L. Kehl of Gulf Research and Development Company. The electron microscopy was carried out on a JEOL JEM-100B which had been modified for high resolution microscopy (2). Standard high resolution techniques were employed. Three different sample types were observed: 669A-1-5-7 (poor catalyst), H-L-2 (good catalyst) and 27-011 (good catalyst).


1979 ◽  
Vol 7 (1) ◽  
pp. 229-229
Author(s):  
HARRY MATTHEWS
Keyword(s):  

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