TRACE ELEMENTS IN HORNBLENDE REVEAL VARIATIONS IN ENCLAVE-HOST MAGMA INTERACTION IN THE TUOLUMNE INTRUSIVE COMPLEX, SIERRA NEVADA, CA

2018 ◽  
Author(s):  
Calvin G. Barnes ◽  
◽  
Kevin Werts ◽  
Vali Memeti
2021 ◽  
Author(s):  
Susanne Seitz ◽  
Guilherme Gualda ◽  
Luca Caricchi

<p>Zoned minerals preserve information about their growth conditions, by changing their composition as function of temperature, pressure and melt composition. By carefully looking at a zoned minerals we can determine characteristics of the main stages of the evolution of magmatic systems.</p><p>We study alkali feldspar megacrysts from the Tuolumne Intrusive Complex in California, with the aim of deciphering chemical signatures of rejuvenation events. We characterize the chemical zoning of alkali feldspar using X-ray tomography, BSE imaging, EDS-SEM analysis and LA-ICPMS analysis along profiles. We use hierarchical clustering based on major and trace elements to objectively identify compositional groups for each chemical profile. By reducing the complexity of chemical zoning to one dimension (i.e. cluster number) we can trace the evolution of the conditions of growth and identify rejuvenation events.</p><p>Alkali feldspar megacrysts (up to 20 cm in size) from the Cathedral Peak unit of the Tuolumne Intrusive Complex occur predominantly disperse and only make between 8 - 12 % of the total crystal population. They are mostly homogeneous in major element, and markedly oscillatory zoned in trace elements such as Ba, Sr, and Rb. Using hierarchical clustering we identify four different chemical groups within the alkali feldspar crystals. Each chemical group is repeated multiple times in a single crystal. Overall the crystals show a decreasing trend of Ba towards the rim. Extended alkali feldspar crystallization would lead to a depletion of Ba in the melt and consequently to the growth of low Ba-zones of alkali feldspar. In some crystals the sequence of decreasing Ba is repeated twice. We propose that this reflects melt recharge in a melt-rich magmatic system.</p>


2020 ◽  
Vol 105 (1) ◽  
pp. 77-91 ◽  
Author(s):  
Kevin Werts ◽  
Calvin G. Barnes ◽  
Valbone Memeti ◽  
Barbara Ratschbacher ◽  
Dustin Williams ◽  
...  

Abstract Bulk-rock compositions are commonly used as proxies for melt compositions, particularly in silicic plutonic systems. However, crystal accumulation and/or melt loss may play an important role in bulk-rock compositional variability (McCarthy and Hasty 1976; McCarthy and Groves 1979; Wiebe 1993; Wiebe et al. 2002; Collins et al. 2006; Deering and Bachmann 2010; Miller et al. 2011; Vernon and Collins 2011; Lee and Morton 2015; Lee et al. 2015; Barnes et al. 2016a; Schaen et al. 2018). Recognizing and quantifying the effects of crystal accumulation and melt loss in these silicic systems is challenging. Hornblende-melt Fe/Mg partitioning relationships and hornblende (Hbl) chemometry are used here to test for equilibrium with encompassing bulk-rock and/or glass compositions from several plutonic and volcanic systems. Furthermore, we assess the extent to which these tests can be appropriately applied to Hbl from plutonic systems by investigating whether Hbl from the long-lived (~10 Ma) Tuolumne Intrusive Complex preserves magmatic crystallization histories. On the basis of regular zoning patterns, co-variation of both fast- and slow-diffusing trace elements, Hbl thermometry, and compositional overlap with volcanic Hbl we conclude that Hbl from plutons largely preserve records supporting the preservation of a magmatic crystallization history, although many compositional analyses yield calculated temperatures <750 °C, which is unusual in volcanic Hbl. Hornblende is only rarely in equilibrium with host plutonic bulk-rock compositions over a wide range of SiO2 contents (42–78 wt%). Hornblende chemometry indicates that the majority of Hbl from the plutonic systems investigated here is in equilibrium with melts that are typically more silicic (dacitic to rhyolitic in composition) than bulk-rock compositions. These results are consistent with crystal accumulation and/or loss of silicic melts within middle- to upper-crustal plutons. Although the processes by which melts are removed from these plutonic systems is uncertain, it is evident that these melts are either redistributed in the crust (e.g., leucogranite dikes, plutonic roofs, etc.) or are instead erupted. In contrast, Hbl from volcanic rocks is more commonly in equilibrium with bulk-rock and glass compositions. In most cases, where Hbl is out of equilibrium with its host glass, the glasses are more evolved than the calculated melts indicating crystallization from a less fractionated melt and/or mixed crystal populations. Where Hbl is not in equilibrium with volcanic bulk-rocks, the bulk-rock compositions are typically more mafic than the calculated melts. In some intermediate volcanic samples, the occurrence of wide-ranges of calculated melt compositions is indicative of magma mixing. The general absence of Hbl with temperatures <750 °C from volcanic systems suggests that magmatic mushes below this temperature are unlikely to erupt. Our results indicate that bulk-rock compositions of granitic plutonic rocks only rarely approximate melt compositions and that the possibility of crystal accumulation and/or melt loss cannot be ignored. We suggest that detailed assessments of crystal accumulation and melt loss processes in magmatic systems are crucial to evaluating magma differentiation processes and discerning petrogenetic links between plutonic and volcanic systems.


Author(s):  
Valbone Memeti ◽  
Scott R. Paterson ◽  
Roland Mundil

The initiation of pluton formation is rarely preserved as the rock record is typically overprinted by younger intruding pulses. An exception is the 80 km2 Kuna Crest lobe, which marks the initiation of the 95−85 Ma, 1100 km2 Tuolumne Intrusive Complex in the Sierra Nevada, California, USA. We present a detailed map of the lithologies and structure of the Kuna Crest lobe, associated sheeted complex and satellite plutons, and their host rocks, using chemical abrasion−isotope dilution−thermal ionization mass spectrometry and laser ablation−inductively coupled plasma−mass spectrometry U-Pb zircon geochronology, element and isotope geochemistry, and Al-in-hornblende thermobarometry to conclude the following: (a) The 94.91 ± 0.53 Ma to 92.75 ± 0.11 Ma Kuna Crest lobe and its marginal sheeted complex preserved the oldest intrusive pulses and most mantle-like compositions of the entire Tuolumne Intrusive Complex. (b) Emplacement began with magma wedging of low volume magma pulses resulting in a sheeted complex that is compositionally heterogeneous at outcrop scales, but isotopically homogeneous. (c) These early magmas established a pre-heated pathway within just a few hundreds of thousands of years that gave way to the formation of the ∼1.5 million-year-long active, compositionally more homogeneous but isotopically more heterogeneous magma mush across the Kuna Crest lobe. The host rocks and previously intruded magma were displaced largely vertically through downward flow. (d) The melt-interconnected mush zone in the lobe allowed for magma mixing and crystal-liquid separation at the emplacement level. We interpret this lobe to represent an upper- to mid-crustal, vertical magma transfer zone that likely fed shallower plutons and potentially volcanic eruptions. We propose a filter pressing mechanism driven by vertical magma transport through the lobe resulting in margin-parallel fabrics, plagioclase-rich crystal cumulates, inward draining and upward loss (of up to 40%) of interstitial melts. Some inward drained melts hybridized with later intruding Half Dome magmas at the transition to the main Tuolumne Intrusive Complex. Some of the lobe magmas, including fractionated melts, drained laterally into the strain shadow of the lobe to form the satellite plutons, further contributing to cumulate formation in the lobe. This study documents that within only a few hundreds of thousands of years, arc magma plumbing systems are capable of establishing a focused magma pathway to build up to increasingly larger magma bodies that are capable of undergoing magma differentiation and feeding shallower plutons and volcanic eruptions.


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