Rapid cooling of the Rustenburg Layered Suite of the Bushveld Complex (South Africa): Insights from biotite 40Ar/39Ar geochronology

Geology ◽  
2020 ◽  
Vol 48 (8) ◽  
pp. 834-838
Author(s):  
Jacob B. Setera ◽  
Jill A. VanTongeren ◽  
Brent D. Turrin ◽  
Carl C. Swisher

Abstract Despite their importance to understanding magma chamber processes and the formation of economically viable precious metal deposits, the cooling histories of layered mafic intrusions remain enigmatic due to limited geochronologic constraints. We provide a comprehensive 40Ar/39Ar study of biotite throughout the Rustenburg Layered Suite (RLS) of the Bushveld Complex, South Africa. Analyses of individual biotite grains from 10 samples, encompassing ∼5.5 km of RLS stratigraphy, yielded weighted mean plateau ages that all overlap at 2σ (α-95% confidence level) and range from 2056.3 ± 3.2 Ma to 2052.0 ± 7.6 Ma (2σ). A weighted mean of all biotite plateau ages yielded an age of 2054.47 ± 0.84 Ma (2σ, n = 30, mean square of weighted deviates = 0.23, P = 1.00; ±21 Ma fully propagated). The overlap between our 40Ar/39Ar biotite and published U-Pb zircon ages suggests that the RLS cooled rapidly to the closure temperature of biotite, with cooling rates on the order of 1000 °C m.y.–1 throughout the stratigraphy. Thermal modeling requires enhanced heat loss, due to the hydrothermal system associated with the emplacement of the RLS, to produce the inferred rapid cooling rates. Previously reported young 40Ar/39Ar biotite ages from the UG-2 and MG-1 chromitite seams and the Merensky Reef are likely a product of localized late-stage circulation of hydrothermal fluids. The lack of similarly young 40Ar/39Ar biotite ages from the remainder of the stratigraphy suggests that late-stage hydrothermal events were potentially localized to chromitites and the Merensky Reef.

Geology ◽  
2021 ◽  
Author(s):  
Haoyang Zhou ◽  
Robert B. Trumbull ◽  
Ilya V. Veksler ◽  
Ilya N. Bindeman ◽  
Johannes Glodny ◽  
...  

There is abundant evidence for significant H2O in evolved melts from the platinum-rich UG2 chromitite and the Merensky Reef of the Bushveld Complex (South Africa), but there is no consensus about the source of H2O. We report triple-oxygen and hydrogen isotope ratios of interstitial, late-magmatic phlogopite from three localities of the UG2 layer. The phlogopite yielded δD values of –43‰ to –23‰, which is >30‰ higher than previously known from Bushveld rocks and far above the mantle values of ~–75‰. The phlogopite triple-oxygen isotope ratios are the first to be reported for Bushveld rocks, with values of Δ′17O0.5305 (17O excess relative to the reference line 0.5305) from –0.069‰ to –0.044‰ (δ18O 5.2‰–6.2‰). The oxygen data support existing models of as much as 30%–40% contamination of mantlederived magmas in the lower to middle crust. However, the high δ values require a second step of contamination, which we attribute to brines from the marine sediments in the Transvaal Basin at the emplacement level.


1993 ◽  
Vol 106 (1-2) ◽  
pp. 171-186 ◽  
Author(s):  
D.L. Reid ◽  
R.G. Cawthorn ◽  
F.J. Kruger ◽  
M. Tredoux

2021 ◽  
Author(s):  
W.D. Maier ◽  
◽  
Qun-Ke Xia ◽  

Layered intrusions host some of the world’s most important ore deposits, yet their global distribution, age, and petrogenesis remain poorly known. Here we provide an update on our current understanding and highlight some key outstanding research questions, notably on the potential importance of reactive flow. We present some preliminary data on water contents of Bushveld orthopyroxenes from which we calculated the water contents of the magma. The analysed Bushveld rocks, including the Merensky Reef, crystallised from relatively water-poor magma, similar to many other continental basalts.


2020 ◽  
Vol 61 (7) ◽  
Author(s):  
Halley A Keevil ◽  
Olivier Namur ◽  
Marian B Holness

Abstract Replacive symplectites (vermicular intergrowths of two or more minerals) are an important feature of layered igneous intrusions, recording evidence of late-stage reactions between interstitial liquid and crystals. They are common throughout the Layered Series of the 564 Ma Sept Iles layered intrusion in Quebec, Canada, and fall into three types: oxy-symplectites, ‘Type I’ symplectites, and ‘Type II’ symplectites. Oxy-symplectites are comprised of magnetite and orthopyroxene, nucleate on olivine primocrysts, and form via the reaction Olivine + O2 → Orthopyroxene + Magnetite; Type I symplectites (of which there are 3 distinct categories) are comprised of anorthitic plagioclase with pyroxene, amphibole, or olivine vermicules, grow from primocryst oxide grains, and replace primocryst plagioclase; and Type II symplectites (of which there are 2 distinct categories) are comprised of anorthitic plagioclase with orthopyroxene ± amphibole vermicules, grow from primocryst olivine grains, and replace primocryst plagioclase. Rare symplectites composed of biotite and plagioclase are also present. Symplectite growth occurred at 700–1030°C with pressure constraints of 1–2 kbar. We propose that Type I symplectites, and some Type II symplectites, formed from the interaction of primocrysts with residual Fe-rich liquid as a consequence of differential loss of an immiscible Si-rich liquid conjugate from the crystal mush. However, redistribution and concentration of hydrous fluids in incompletely solidified rock, or an increase in water activity of the interstitial melt, may be more plausible processes responsible for the formation of replacive symplectites comprising abundant hydrous mineral assemblages.


Author(s):  
Sofya Chistyakova ◽  
Rais Latypov ◽  
Kirsten Youlton

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