Towards the Biobeneficiation of PGMs: Reviewing the Opportunities

Conventional beneficiation of the Platinum Group of Metals (PGMs) relies on the use of inorganic chemicals. With the depreciation of high grade deposits, these conventional processes are becoming less economically viable. Furthermore, the use of chemicals has serious negative impacts on the environment. To address the challenges of conventional PGM beneficiation, biobeneficiation has been proposed. In conventional flotation, the flotation behavior of the associated sulphides determines overall PGM recovery. The same principle may also be applied for the bio-beneficiation of PGMs. Therefore, this paper discusses the biobeneficiation behavior of sulphides closely associated with PGMs with the aim of postulating the bio-beneficiation behavior of PGMs associated with the same base metal sulphides. Conventional PGM processes are briefly discussed, as bio-beneficiation of PGMs is governed by similar underlying principles. Potential microorganisms for the biobeneficiation of PGMs are highlighted, as well as the corresponding conditions for their effectiveness. The use of both single cultures and mixed cultures is discussed. Depending on conditions, PGMs associated with pyrite and/or chalcopyrite were projected to be biofloatable with B. polymyxa, P. polymyxa, A. ferrooxidans, L. ferrooxidans, B. pumilus, B. subtilis, halophilic bacteria, Alicyclobacillus ferrooxidans, sulphate reducing bacteria, and mixed cultures of A. ferrooxidans, A. thiooxidans and L. ferrooxidans. Pyrite-associated PGMsare expected to be generally prone to biodepression, whereas chalcopyrite-associated PGMs are expected to be generally recovered as the floatable phase. Sulphate-reducing bacteria were reported to have a dual role on the bioflotation of sulphide ores (flotation and depression), depending on the conditions. Therefore, this type of microorganism may serve as both a depressant or a collector in the recovery of PGMs. Based on the bioflotation response of pyrrhotite to L. ferrooxidans, it is anticipated that pyrrhotite-associated PGMS can be biodepressed using L. ferrooxidans. In terms of bioflocculation, PGMs associated with chalcopyrite may be recovered using L. ferrooxidans, whereas A. ferrooxidans, A. thiooxidans, B. polyxyma and B. subtilis can be used in the bioflocculation of pyrite-associated PGMs. M. phlei can be employed in the reverse bioflocculation of pyrite-associated PGMs. Although no information was found on the biobeneficiation of pentlandite, postulations were made based on other sulphide minerals. It was postulated that biobeneficiation (biodepression and bioflotation) with pentlandite-associated PGMs should be possible using A. ferrooxidans. It is also projected that sulphate-reducing bacteria will be suitable for the bioflotation of PGMs associated with pentlandite. The removal of gangue species such as silicates and chromites associated with PGM concentrates was also discussed. A. ferrooxidans, P. polymyxa and B. mucilaginous are candidates for the removal of gangue species. Furthermore, the need to control process conditions was highlighted. The most suitable conditions for biobeneficiation of the various base metal sulphide minerals associated with PGMs are presented in the paper. Most of the challenges associated with biobeneficiation of PGMs are already common to conventional methods, and the means of circumventing them are already well established. Developments in genetic engineering and the advent of new data science techniques are tools that could make the biobeneficiation of PGMs a possibility.

A new screening test to evaluate the presence of oxidizable sulphide minerals in coarse aggregates

A simple screening test was proposed in order to test coarse aggregates for their potential to cause damage when used in concrete due to the oxidation of sulphide phases. The test involves submerging an aggregate sample in an oxidizing agent and measuring the mass loss. Samples with no known oxidizable sulphides showed a mass loss of <1.0% after one week of testing at room temperature. Samples of oxidizable sulphides showed a mass loss higher than 3.5% and changes in the colour of the test solution. It is proposed that aggregates which achieve a mass loss of less than 0.50% and no colour change in the test solution be accepted.

A new screening test to evaluate the presence of oxidizable sulphide minerals in coarse aggregates

A simple screening test was proposed in order to test coarse aggregates for their potential to cause damage when used in concrete due to the oxidation of sulphide phases. The test involves submerging an aggregate sample in an oxidizing agent and measuring the mass loss. Samples with no known oxidizable sulphides showed a mass loss of <1.0% after one week of testing at room temperature. Samples of oxidizable sulphides showed a mass loss higher than 3.5% and changes in the colour of the test solution. It is proposed that aggregates which achieve a mass loss of less than 0.50% and no colour change in the test solution be accepted.

A new screening test to evaluate the presence of oxidizable sulphide minerals in coarse aggregates

A simple screening test was proposed in order to test coarse aggregates for their potential to cause damage when used in concrete due to the oxidation of sulphide phases. The test involves submerging an aggregate sample in an oxidizing agent and measuring the mass loss. Samples with no known oxidizable sulphides showed a mass loss of <1.0% after one week of testing at room temperature. Samples of oxidizable sulphides showed a mass loss higher than 3.5% and changes in the colour of the test solution. It is proposed that aggregates which achieve a mass loss of less than 0.50% and no colour change in the test solution be accepted.

The role of unsaturated soil mechanics in unconventional tailings deposition

Desiccation (water loss by drying or freeze-thaw sufficient to generate matric suction), can influence the performance of a tailings deposit both positively and negatively. The significance of desiccation is largest in tailings that have been dewatered prior to deposition, by thickening or filtration. Such tailings can be “stacked” or deposited with a significant slope, which usually implies that a substantial volume of tailings remain above water. Under such conditions the tailings, by accident or by design, may undergo desiccation before burial by fresh tailings. Desiccation can contribute substantially to strength, above and beyond the contribution arising from increase in density, through stress history effects. For some deposits, it is required practice that at least some tailings undergo desiccation to improve, particularly when those tailings for a structural part of a deposit. If, however, tailings remain exposed to the atmosphere in an unsaturated state for some period of time, this may have potential negative consequences through oxidation of sulphide minerals and the formation of acid drainage. This paper describes previous research on the strength gained through desiccation in tailings, and on modelling work that incorporates unsaturated soil phenomena into consolidation analysis. Both types of research are applied to a real field site, providing an example of how novel improvements to tailings management can arise out of application of principles of unsaturated soil mechanics.

Selected Grain-Size and Geochemical Analyses of the Loess-Paleosol Sequence of Pécel (Northern Hungary): An Attempt to Determine Sediment Accumulation Conditions and the Source Area Location

The loess-paleosol profile near the settlement of Pécel has a notable size among the loess-paleosol sequences of the Northern Carpathian territories. Therefore, comprehensive sedimentological examinations were performed to understand the profile and the information preserved in it. The past periodicity and intensity of winds were showed by particle composition studies (GSI, U-ratio). At least two source areas can be presumed based on geochemical indices (CIA, CIW, Rb/Sr, Zr/Rb). Based on the characteristics of the chemical composition of sulphide minerals (P, S, Pb, Ni, As sulphides), the lower 10 m of the profile was supposed to be transported from the NW direction (Buda Thermal Karst, Börzsöny, Cserhát). Sufficient information is not yet available in order to determine the source area of the upper 10 m. By using the mentioned indexes, major developing and weathering horizons also could be identified.

Integration of geophysics and remote sensing techniques in mapping zones mineralised with disseminated gold and sulphide minerals in Lolgorien, Narok County, Kenya

Even though ground geophysical surveys (especially Induced polarization and resistivity) are applied in mineral exploration, their effectiveness in identification of mineralised zones is often enhanced by integrating other mineral exploration techniques such as remote sensing and geological investigations. Integrating different techniques helps in reducing uncertainty that is often associated with mineral exploration. The methods being integrated also depend on characteristics of mineralisation and those of host rock. In this study, geophysical survey methods (induced polarization and resistivity) were integrated with remote sensing and geological methods to delineate mineralised zones in Lolgorien beyond reasonable doubt. By integrating these methods, it was found that Lolgorien’s gold and sulphide minerals (disseminated minerals) are hosted in massive quartz veins and auriferous quartz veins hosted in Banded Iron Formations. It was also found that this mineralisation was controlled by faults which mainly trend in two directions (NW-SE) and (NE-SW). Keywords: hydrothermal alteration, chargeability, resistivity, band ratio, lineament density