scholarly journals A quantification of the effect of diagenesis on the paleoredox record in mid-Proterozoic sedimentary rocks

Geology ◽  
2021 ◽  
Author(s):  
Alec M. Hutchings ◽  
Alexandra V. Turchyn
Keyword(s):  
Iron Sulfide ◽  
Sedimentary Rocks ◽  
Total Iron ◽  
Total Iron Content ◽  
Geological Time ◽  
Iron Minerals ◽  
Reactive Iron ◽  
Time Period ◽  
Geological Past ◽  
Iron Sulfide Minerals

Iron speciation in ancient sedimentary rocks is widely used to reconstruct oceanic redox conditions over geological time, specifically to assess the extent of oxic, euxinic (anoxic containing sulfide), and ferruginous (anoxic containing iron) conditions. We explore how post-depositional sedimentary processes can skew particular geochemical signals in the rock record. One such process is when aqueous sulfide—including that produced in the sediment column—reacts with sedimentary iron, converting non-sulfide, highly reactive iron minerals to iron-sulfide minerals; this can lead to increased preservation of iron as pyrite and an overestimation of seafloor euxinia. We show that sedimentary rocks with higher (>5 wt%) total iron content are more buffered to this effect and thus are a more reliable indicator of true water-column euxinia. When considering this effect in the geological past, we estimate that true euxinia in the mid-Proterozoic may have been as much as fourfold less than previously thought—more in line with other recent paleoredox proxies not based on iron minerals. Marine iron and sulfate concentrations were more equivalent in Proterozoic–Neoproterozoic oceans, suggesting this time period was particularly susceptible to this post-depositional alteration, explaining the extent of euxinia suggested for this geological interval.

Clay mineralogy of parent materials derived from uppermost Cretaceous and Tertiary sedimentary rocks in southern Saskatchewan

1993 ◽  
Vol 73 (4) ◽  
pp. 447-457 ◽  
Author(s):  
W. E. Dubbin ◽  
A. R. Mermut ◽  
H. P. W. Rostad
Keyword(s):  
Organic Carbon ◽  
Iron Content ◽  
Sedimentary Rocks ◽  
Clay Mineralogy ◽  
Total Iron ◽  
Total Iron Content ◽  
Parent Materials ◽  
Surface Areas ◽  
General Chemical ◽  
Detailed Chemical

Soils developed from parent materials derived from uppermost Cretaceous and Tertiary sedimentary rocks have been delineated from those which do not contain any of these younger sediments. The present study was initiated to determine the validity of this delineation. Parent materials from six locations in southwestern Saskatchewan were collected to determine their general chemical and physical properties. Clay fractions from each of these six parent materials were then subjected to detailed chemical and mineralogical analyses. The two parent materials containing the greatest amount of post-Bearpaw bedrock sediments (Jones Creek, Scotsguard) were characterized by substantially more organic carbon and less CaCO3. The presence of coal and the absence of carbonates in local bedrocks were considered to be the source of these deviations. In general, fine clays were comprised of 64–69% smectite, 14–21% illite and 10–13% kaolinite and coarse clay contained 32–39% smectite, 25–34% illite and 11–14% kaolinite. An exception was found in two fine clays which had less smectite but 3–6% vermiculite. Total iron content of the fine clays ranged from 7.16 to 8.11% expressed as Fe2O3. However, only a small fraction of this iron was extractable using the CDB technique. There were no substantial differences in surface areas or CECs of the clay fractions. Despite minor differences in the chemistry and mineralogy of these six parent materials, a separation of the soil associations does not appear to be warranted. Key words: Parent materials, uppermost Cretaceous, Tertiary, bedrock, clay mineralogy

Stabilizing pyritic material

1989 ◽  
Vol 4 ◽  
pp. 244-248 ◽  
Author(s):  
Donald L. Wolberg
Keyword(s):  
Significant Contribution ◽  
Organic Materials ◽  
Sedimentary Rocks ◽  
Iron Sulfides ◽  
Decomposition Products ◽  
Iron Minerals ◽  
Pyrite Formation ◽  
Organic Sediments ◽  
Freshwater Environments

The minerals pyrite and marcasite (broadly termed pyritic minerals) are iron sulfides that are common if not ubiquitous in sedimentary rocks, especially in association with organic materials (Berner, 1970). In most marine sedimentary associations, pyrite and marcasite are associated with organic sediments rich in dissolved sulfate and iron minerals. Because of the rapid consumption of sulfate in freshwater environments, however, pyrite formation is more restricted in nonmarine sediments (Berner, 1983). The origin of the sulfur in nonmarine environments must lie within pre-existing rocks or volcanic detritus; a relatively small, but significant contribution may derive from plant and animal decomposition products.

scholarly journals Isotopically “heavy” pyrite in marine sediments due to high sedimentation rates and non-steady-state deposition

Geology ◽  
2021 ◽  
Author(s):  
Jiarui Liu ◽  
Gilad Antler ◽  
André Pellerin ◽  
Gareth Izon ◽  
Ingrid Dohrmann ◽  
...  
Keyword(s):  
Critical Role ◽  
Global Ocean ◽  
Sedimentation Rates ◽  
Geological Time ◽  
Near Surface ◽  
Reactive Iron ◽  
Depositional Processes ◽  
Pyrite Formation ◽  
Ocean Chemistry ◽  
Sedimentary Pyrite

Sedimentary pyrite formation links the global biogeochemical cycles of carbon, sulfur, and iron, which, in turn, modulate the redox state of the planet’s surficial environment over geological time scales. Accordingly, the sulfur isotopic composition (δ34S) of pyrite has been widely employed as a geochemical tool to probe the evolution of ocean chemistry. Characteristics of the depositional environment and post-depositional processes, however, can modify the δ34S signal that is captured in sedimentary pyrite and ultimately preserved in the geological record. Exploring sulfur and iron diagenesis within the Bornholm Basin, Baltic Sea, we find that higher sedimentation rates limit the near-surface sulfidization of reactive iron, facilitating its burial and hence the subsurface availability of reactive iron for continued and progressively more 34S-enriched sediment-hosted pyrite formation (δ34S ≈ –5‰). Using a diagenetic model, we show that the amount of pyrite formed at the sediment-water interface has increased over the past few centuries in response to expansion of water-column hypoxia, which also impacts the sulfur isotopic signature of pyrite at depth. This contribution highlights the critical role of reactive iron in pyrite formation and questions to what degree pyrite δ34S values truly reflect past global ocean chemistry and biogeochemical processes. This work strengthens our ability to extract local paleoenvironmental information from pyrite δ34S signatures.

In search of possible causes of mass extinctions

2004 ◽  
Author(s):  
Tony Hallam
Keyword(s):  
Science Fiction ◽  
High Rate ◽  
Mass Extinctions ◽  
Geological Time ◽  
Steven Spielberg ◽  
Geological Past ◽  
History Of ◽  
The Subject ◽  
Cretaceous Period ◽  
Land Vertebrates

When the subject of extinctions in the geological past comes up, nearly everyone’s thoughts turn to dinosaurs. It may well be true that these long-extinct beasts mean more to most children than the vast majority of living creatures. One could even go so far as to paraphrase Voltaire and maintain that if dinosaurs had never existed it would have been necessary to invent them, if only as a metaphor for obsolescence. To refer to a particular machine as a dinosaur would certainly do nothing for its market value. The irony is that the metaphor is now itself obsolete. The modern scientific view of dinosaurs differs immensely from the old one of lumbering, inefficient creatures tottering to their final decline. Their success as dominant land vertebrates through 165 million years of the Earth’s history is, indeed, now mainly regarded with wonder and even admiration. If, as is generally thought, the dinosaurs were killed off by an asteroid at the end of the Cretaceous, that is something for which no organism could possibly have been prepared by normal Darwinian natural selection. The final demise of the dinosaurs would then have been the result, not of bad genes, but of bad luck, to use the laconic words of Dave Raup. In contemplating the history of the dinosaurs it is necessary to rectify one widespread misconception. Outside scientific circles the view is widely held that the dinosaurs lived for a huge slice of geological time little disturbed by their environment until the final apocalypse. This is a serious misconception. The dinosaurs suffered quite a high evolutionary turnover rate, and this implies a high rate of extinction throughout their history. Jurassic dinosaurs, dominated by giant sauropods, stegosaurs, and the top carnivore Allosaurus, are quite different from those of the Cretaceous period, which are characterized by diverse hadrosaurs, ceratopsians, and Tyrannosaurus. Michael Crichton’s science-fiction novel Jurassic Park, made famous by the Steven Spielberg movies, features dinosaurs that are mainly from the Cretaceous, probably because velociraptors and Tyrannosaurus could provide more drama.

Sign in / Sign up

Export Citation Format

Share Document