scholarly journals Supplemental Material: Zircon and monazite geochronology in the Palmer zone of transpression, south-central New England, USA: Constraints on timing of deformation, high-grade metamorphism, and lithospheric foundering during late Paleozoic oblique collision in the Northern Appalachian orogen

2020 ◽  
Author(s):  
David Moecher ◽  
et al.

Analytical methods for Zircon U-Pb and monazite Th-Pb SIMS geochronology, zircon U-Pb LA-ICP-MS geochronology; data tables and supporting previous work.

Author(s):  
D.P. Moecher ◽  
J.K. McCulla ◽  
M.A. Massey

Middle to late Paleozoic high-angle (45°) oblique convergence between Laurentia and composite Avalon terranes resulted in crustal shortening of ∼5:1 across the Central Maine and Bronson Hill zones of the southern New England Appalachians (USA). The Palmer zone of transpression illustrates the midcrustal expression of magmatism, metamorphism, and ductile deformation that developed in response to oblique convergence in the apparent absence of subduction. Secondary ion mass spectrometry zircon U-Pb and monazite Th-Pb ages, supplemented by zircon laser-ablation−inductively coupled plasma−single-collector mass spectrometry U-Pb ages, expand the geochronology constraining the evolution of the Palmer zone of transpression system and potential models for transcurrent collisional tectonics. Ordovician, Silurian, and Early Devonian plutons, and regional high-grade metapelitic country rocks that comprise the pre-transpressional crustal infrastructure are the same age as lithologic equivalents to the north and northeast along the orogen that did not experience high-angle oblique convergence. All plutons within the Palmer zone of transpression and adjoining areas were deformed (flattened, boudinaged, attenuated, folded, and/or ductilely sheared) by the regional transpression system. The most widespread magmatic event in the study area, which is not observed elsewhere in the Northern Appalachians, is intrusion of a diorite-tonalite suite at 370−360 Ma, the oldest rocks of which contain granulite-facies mineral assemblages and all of which are deformed. Leucopegmatites that intrude pelitic paragneisses, which likely formed in response to high-grade metamorphism and which are all deformed, are 370−355 Ma in age. All metapelitic paragneisses contain foliations and lineations that are synkinematic with retrograde garnet + K-feldspar → sillimanite + biotite assemblages and fabrics that formed during vertical and lateral crustal escape in response to extreme shortening. Contemporaneous diorite-tonalite magmatism and regional high-grade metamorphism are interpreted to reflect regional-scale heating of the crust preceding inception of the transpressional system. Transpressional deformation of both plutons and paragneisses indicates shortening commenced after crustal thermal conditions peaked (ca. 355 Ma). Monazite in paragneiss, the formation of which in most samples is linked texturally to formation of transpressional fabrics, yielded a continuum of Th-Pb ages of ca. 360−330 Ma, indicating transpression continued after peak thermal conditions. The extreme crustal shortening of the Bronson Hill and Central Maine zones from Maine to southern New England, pre-transpressional magmatism, and high-grade metamorphism overprint an Acadian (ca. 400−370 Ma) magmatic-metamorphic infrastructure that occurred in the absence of subduction. The transpressional system exhibits all predicted thermal, magmatic, deformation, metamorphic, and exhumation/erosion characteristics of mantle lithospheric foundering (delamination, detachment, or drip) in response to extreme lithospheric shortening and vertical stretching at ca. 375−370 Ma, leading to advection of heat to the lower continental crust and attendant magmatic and metamorphic responses over the time span 370−355 Ma.


Minerals ◽  
2019 ◽  
Vol 9 (4) ◽  
pp. 244 ◽  
Author(s):  
Keyser ◽  
Ciobanu ◽  
Cook ◽  
Feltus ◽  
Johnson ◽  
...  

Zirconium is an element of considerable petrogenetic significance but is rarely found in hematite at concentrations higher than a few parts-per-million (ppm). Coarse-grained hematite ore from the metamorphosed Peculiar Knob iron deposit, South Australia, contains anomalous concentrations of Zr and has been investigated using microanalytical techniques that can bridge the micron- to nanoscales to understand the distribution of Zr in the ore. Hematite displays textures attributable to annealing under conditions of high-grade metamorphism, deformation twins (r~85˚ to hematite elongation), relict magnetite and fields of sub-micron-wide inclusions of baddeleyite as conjugate needles with orientation at ~110˚/70˚. Skeletal and granoblastic zircon, containing only a few ppm U, are both present interstitial to hematite. Using laser-ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) spot analysis and mapping, the concentration of Zr in hematite is determined to be ~260 ppm on average (up to 680 ppm). The Zr content is, however, directly attributable to nm-scale inclusions of baddeleyite pervasively distributed throughout the hematite rather than Zr in solid solution. Distinction between nm-scale inclusions and lattice-bound trace element substitutions cannot be made from LA-ICP-MS data alone and requires nanoscale characterization. Scandium-rich (up to 0.18 wt. % Sc2O3) cores in zircon are documented by microprobe analysis and mapping. Using high-angle annular dark field scanning transmission electron microscopy imaging (HAADF-STEM) and energy-dispersive spectrometry STEM mapping of foils prepared in-situ by focused ion beam methods, we identify [011]baddeleyite epitaxially intergrown with [22.1]hematite. Lattice vectors at 84–86˚ underpinning the epitaxial intergrowth orientation correspond to directions of r-twins but not to the orientation of the needles, which display a ~15˚ misfit. This is attributable to directions of trellis exsolutions in a precursor titanomagnetite. U–Pb dating of zircon gives a 206Pb/238U weighted mean age of 1741 ± 49 Ma (sensitive high-resolution ion microprobe U–Pb method). Based on the findings presented here, detrital titanomagnetite from erosion of mafic rocks is considered the most likely source for Zr, Ti, Cr and Sc. Whether such detrital horizons accumulated in a basin with chemical precipitation of Fe-minerals (banded iron formation) is debatable, but such Fe-rich sediments clearly included detrital horizons. Martitization during the diagenesis-supergene enrichment cycle was followed by high-grade metamorphism during the ~1.73–1.69 Ga Kimban Orogeny during which martite recrystallized as granoblastic hematite. Later interaction with hydrothermal fluids associated with ~1.6 Ga Hiltaba-granitoids led to W, Sn and Sb enrichment in the hematite. By reconstructing the evolution of the massive orebody at Peculiar Knob, we show how application of complimentary advanced microanalytical techniques, in-situ and on the same material but at different scales, provides critical constraints on ore-forming processes.


2020 ◽  
Author(s):  
C. Busby ◽  
et al.

Item S1: Analytical methods, including XRF and ICP-MS whole-rock geochemical analysis, <sup>40</sup>Ar-<sup>39</sup>Ar geochronological analytical methods, and zircon isotopic methods. Item S2: Excel spreadsheet of whole-rock geochemical data, including XRF and LA-ICPMS data. Item S3: <sup>40</sup>Ar-<sup>39</sup>Ar geochronological data: Summary table, and data tables and plots for each sample. Item S4: U-Pb zircon data. Item S5. Hf-isotope zircon data. Item S6: Outcrop photos. Item 7: Photomicrographs, including examples of all samples dated by <sup>40</sup>Ar-<sup>39</sup>Ar. Item S8: Summary of published definitions of adakites and high magnesium andesites. Item S9: KMZ files for geologic maps.


2016 ◽  
Vol 52 ◽  
pp. 169
Author(s):  
David P West ◽  
Dwight Bradley ◽  
Raymond Coish

The Litchfield pluton is a poorly exposed 7 km2 composite alkalic intrusive complex that cuts previously deformed and metamorphosed Silurian turbidites in south-central Maine.  The pluton includes a variety of alkaline syenites, including the type locality of “litchfieldite”, a coarse-grained cancrinite, sodalite, and lepidomelane bearing nepheline syenite first recognized over 150 years ago and common in many petrologic collections.  A new U-Pb zircon age of 321 ± 2 Ma from the nepheline syenite is interpreted to represent the crystallization age of the plutonic complex.  A new biotite 40Ar/39Ar age of 239 ± 1 Ma from the syenite is similar to previously published mica ages from the surrounding country rocks and dates the time of regional cooling in the area below ~ 300°C.  Whole rock geochemical analyses from rocks of the Litchfield pluton are compatible with strongly alkaline A-type granitoid rocks that formed in a within plate or continental rift tectonic setting.  The age and geochemical characteristics of the alkalic igneous rocks near Litchfield are consistent with a model that invokes the generation of a small volume of alkalic magma beneath south-central Maine during a period of Carboniferous transcurrent tectonism in the northern Appalachian orogen.       


2020 ◽  
Author(s):  
C. Busby ◽  
et al.

Item S1: Analytical methods, including XRF and ICP-MS whole-rock geochemical analysis, <sup>40</sup>Ar-<sup>39</sup>Ar geochronological analytical methods, and zircon isotopic methods. Item S2: Excel spreadsheet of whole-rock geochemical data, including XRF and LA-ICPMS data. Item S3: <sup>40</sup>Ar-<sup>39</sup>Ar geochronological data: Summary table, and data tables and plots for each sample. Item S4: U-Pb zircon data. Item S5. Hf-isotope zircon data. Item S6: Outcrop photos. Item 7: Photomicrographs, including examples of all samples dated by <sup>40</sup>Ar-<sup>39</sup>Ar. Item S8: Summary of published definitions of adakites and high magnesium andesites. Item S9: KMZ files for geologic maps.


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