Connections of Precipitable Water Vapor and Total Ozone Anomalies over European Russia with the North Atlantic Oscillation: Specific Features of Summer 2010

2017 ◽  
Vol 53 (9) ◽  
pp. 885-893 ◽  
Author(s):  
S. A. Sitnov ◽  
I. I. Mokhov ◽  
V. A. Bezverkhny
2014 ◽  
Vol 14 (14) ◽  
pp. 21065-21099
Author(s):  
I. Petropavlovskikh ◽  
R. Evans ◽  
G. McConville ◽  
G. L. Manney ◽  
H. E. Rieder

Abstract. Continuous measurements of total ozone (by Dobson spectrophotometers) across the contiguous United States (US) began in the early 1960s. Here, we analyze temporal and spatial variability and trends in total ozone from the five US sites with long-term records. While similar long-term ozone changes are detected at all five sites, we find differences in the patterns of ozone variability on shorter time scales. In addition to standard evaluation techniques, STL-decomposition methods (Seasonal Trend decomposition of time series based on LOcally wEighted Scatterplot Smoothing, LOESS) are used to address temporal variability and trends in the Dobson data. The LOESS-smoothed trend components show a decline of total ozone between the 1970s and 2000s and a "stabilization" at lower levels in recent years, which is also confirmed by linear trend analysis. Methods from statistical extreme value theory (EVT) are used to characterize days with high and low total ozone (termed EHOs and ELOs, respectively) at each station and to analyze temporal changes in the frequency of ozone extremes and their relationship to dynamical features such as the North Atlantic Oscillation and El Niño Southern Oscillation. A comparison of the "fingerprints" detected in the frequency distribution of the extremes with those for standard metrics (i.e., the mean) shows that more "fingerprints" are found for the extremes, particularly for the positive phase of the NAO, at all five US monitoring sites. Results from the STL-decomposition support the findings of the EVT analysis. Finally, we analyze the relative influence of low and high ozone events on seasonal mean column ozone at each station. The results show that the influence of ELOs and EHOs on seasonal mean column ozone can be as much as ±5%, or about twice as large as the overall long-term decadal ozone trends.


2003 ◽  
Vol 3 (6) ◽  
pp. 2053-2066 ◽  
Author(s):  
J. K. Creilson ◽  
J. Fishman ◽  
A. E. Wozniak

Abstract. Using the empirically-corrected tropospheric ozone residual (TOR) technique, which utilizes coincident observations of total ozone from the Total Ozone Mapping Spectrometer (TOMS) and stratospheric ozone profiles from the Solar Backscattered Ultraviolet (SBUV) instruments, the seasonal and regional distribution of tropospheric ozone across the North Atlantic from 1979-2000 is examined. Its relationship to the North Atlantic Oscillation (NAO) is also analyzed as a possible transport mechanism across the North Atlantic. Monthly climatologies of tropospheric ozone for five different regions across the North Atlantic exhibit strong seasonality. The correlation between these monthly climatologies of the TOR and ozonesonde profiles at nearby sites in both eastern North America and western Europe are highly significant (R values of +0.98 and +0.96 respectively) and help to validate the use of satellite retrievals of tropospheric ozone. Distinct springtime interannual variability over North Atlantic Region 5 (eastern North Atlantic-western Europe) is particularly evident and exhibits similar variability to the positive phase of the NAO (R=+0.61, r=<0.01). Positive phases of the NAO are indicative of a stronger Bermuda-Azores high and a stronger Icelandic low and thus faster more zonal flow across the North Atlantic from west to east. This flow regime appears to be causing the transport of tropospheric ozone across the North Atlantic and onto Europe. The consequence of such transport is the impact on a downwind region's ability to meet their ozone attainment goals. This link between the positive phase of the NAO and increased tropospheric ozone over Region 5 could be an important tool for prediction of such pollution outbreaks.


2003 ◽  
Vol 3 (4) ◽  
pp. 4431-4460 ◽  
Author(s):  
J. K. Creilson ◽  
J. Fishman ◽  
A. E. Wozniak

Abstract. Using the empirically-corrected tropospheric ozone residual (TOR) technique, which utilizes coincident observations of total ozone from the Total Ozone Mapping Spectrometer (TOMS) and stratospheric ozone profiles from the Solar Backscattered Ultraviolet (SBUV) instruments, the seasonal and regional distribution of tropospheric ozone across the North Atlantic from 1979–2000 is examined. Its relationship to the North Atlantic Oscillation (NAO) is also analyzed as a possible transport mechanism across the North Atlantic. Monthly climatologies of tropospheric ozone for five different regions across the North Atlantic exhibit strong seasonality. The correlation between these monthly climatologies of the TOR and adjacent ozonesonde profiles in both Region 1 (eastern North America-western North Atlantic) and Region 5 (eastern North Atlantic-western Europe) are highly significant (R values of +0.98 and +0.96, respectively) and help to validate the use of satellite retrievals of tropospheric ozone. Distinct springtime interannual variability over North Atlantic Region 5 (eastern North Atlantic-western Europe) is particularly evident and exhibits similar variability to the positive phase of the NAO (R=+0.61, ρ =<0.01). Positive phases of the NAO are indicative of a stronger Bermuda-Azores high and a stronger Icelandic low and thus faster more zonal flow across the North Atlantic from west to east. This flow regime appears to be causing the transport of tropospheric ozone across the North Atlantic and onto Europe. The consequence of such transport is the impact on a downwind region's ability to meet their ozone attainment goals. This link between the positive phase of the NAO and increased tropospheric ozone over Region 5 could be an important tool for prediction of such pollution outbreaks.


2021 ◽  
Author(s):  
Pedro Jiménez-Guerrero ◽  
Nuno Ratola

AbstractThe atmospheric concentration of persistent organic pollutants (and of polycyclic aromatic hydrocarbons, PAHs, in particular) is closely related to climate change and climatic fluctuations, which are likely to influence contaminant’s transport pathways and transfer processes. Predicting how climate variability alters PAHs concentrations in the atmosphere still poses an exceptional challenge. In this sense, the main objective of this contribution is to assess the relationship between the North Atlantic Oscillation (NAO) index and the mean concentration of benzo[a]pyrene (BaP, the most studied PAH congener) in a domain covering Europe, with an emphasis on the effect of regional-scale processes. A numerical simulation for a present climate period of 30 years was performed using a regional chemistry transport model with a 25 km spatial resolution (horizontal), higher than those commonly applied. The results show an important seasonal behaviour, with a remarkable spatial pattern of difference between the north and the south of the domain. In winter, higher BaP ground levels are found during the NAO+ phase for the Mediterranean basin, while the spatial pattern of this feature (higher BaP levels during NAO+ phases) moves northwards in summer. These results show deviations up to and sometimes over 100% in the BaP mean concentrations, but statistically significant signals (p<0.1) of lower changes (20–40% variations in the signal) are found for the north of the domain in winter and for the south in summer.


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