Room Temperature Oxidation of the Surface of Highly Oriented Pyrolytic Graphite (HOPG) with Nitrogen Dioxide in the Presence of Supported Palladium Particles

2020 ◽  
Vol 61 (4) ◽  
pp. 637-645 ◽  
Author(s):  
M. Yu. Smirnov ◽  
A. V. Kalinkin ◽  
A. M. Sorokin ◽  
V. I. Bukhtiyarov
1983 ◽  
Vol 27 ◽  
Author(s):  
G. Braunstein ◽  
B.S. Elman ◽  
M.S. Dresselhaus ◽  
G. Dresselhaus ◽  
T. Venkatesan

ABSTRACTIn previous studies it was found that when highly oriented pyrolytic graphite (HOPG) is implanted at room temperature, the damage caused by the implantation could be completely annealed by heating the sample to temperatures higher than ∼ 2500°C. However at these high temperatures, the implanted species was found to diffuse out of the sample, as evidenced by the disappearance of the impurity peak in the Rutherford backscattering (RBS) spectrum. If, on the other hand, the HOPG crystal was held at a high temperature (≥ 600°C) during the implantation, partial annealing could be observed. The present work further shows that it is possible to anneal the radiation damage and simultaneously to retain the implants in the graphite lattice by means of high temperature implantation (Ti ≥ 450°C) followed by annealing at 2300°C.


Crystals ◽  
2019 ◽  
Vol 9 (7) ◽  
pp. 350
Author(s):  
Andrey K. Gatin ◽  
Maxim V. Grishin ◽  
Nadezhda V. Dokhlikova ◽  
Sergey Yu. Sarvadii ◽  
Boris R. Shub

The features of deuterium adsorption on the surface of gold nanoparticles deposited on highly oriented pyrolytic graphite (HOPG) were determined. The results showed that deuterium adsorption on gold nanoparticles takes place at room temperature. The results also showed that the filling of the nanoparticles’ surfaces with the adsorbate occurs from the graphite–gold interface until the entire surface is covered by deuterium. The results of quantum chemical simulations are used to explain the experimental data. A simple model of the observed effects is proposed.


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