Distribution of HDBP in two-phase systems consisting of aqueous nitric acid, organic diluent (with or without TBP), and HDBP or its zirconium salt

2007 ◽  
Vol 49 (4) ◽  
pp. 391-396 ◽  
Author(s):  
B. Ya. Zilberman ◽  
N. D. Goletskii ◽  
O. V. Shmidt ◽  
E. A. Puzikov ◽  
I. V. Blazheva ◽  
...  
MRS Advances ◽  
2016 ◽  
Vol 2 (12) ◽  
pp. 641-647 ◽  
Author(s):  
S.V. Stefanovsky ◽  
I.V. Skvortsov ◽  
E.V. Belova ◽  
A.V. Rodin

ABSTRACTThe two-phase systems of pure diluent FS-13 – aqueous solution of 14 mol/L nitric acid and 0.02 mol/L solution of CMPO in diluent FS-13 – aqueous solution of 14 mol/L HNO3 were studied at autoclave temperatures 170 °C and 200 °C. The effect of pre-irradiation on the kinetics of thermolysis was determined. All samples were irradiated using an electron accelerator at a dose rate of 10 kGy/h up to absorbed doses of 0.1, 0.5 and 1 MGy. The parameters of heat and gas emissions were determined during thermolysis of the studied extraction system in a closed apparatus. It has been shown that the conditions required for the growth of autocatalytic oxidation are not created during heating of the two-phase systems in closed vessels even for the extraction systems contacted with 14 mol/l HNO3 for two weeks.


2008 ◽  
Vol 50 (2) ◽  
pp. 171-175 ◽  
Author(s):  
G. F. Egorov ◽  
E. V. Belova ◽  
G. P. Tkhorzhnitskii ◽  
I. G. Tananaev ◽  
E. R. Nazin ◽  
...  

2013 ◽  
Vol 8 (3) ◽  
pp. 352-362 ◽  
Author(s):  
Paula A. J. Rosa ◽  
Ana M. Azevedo ◽  
S. Sommerfeld ◽  
Martina Mutter ◽  
Werner Bäcker ◽  
...  

2021 ◽  
Vol 60 (15) ◽  
pp. 5403-5410
Author(s):  
Martha Alicia González-Félix ◽  
Luis Alberto Mejía-Manzano ◽  
Bertha A. Barba-Dávila ◽  
Sergio O. Serna-Saldívar ◽  
José González-Valdez

2021 ◽  
Vol 778 ◽  
pp. 146293
Author(s):  
Thivaharan Varadavenkatesan ◽  
Shraddha Pai ◽  
Ramesh Vinayagam ◽  
Arivalagan Pugazhendhi ◽  
Raja Selvaraj

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