A Thermal Chemical Reaction System for Natural Gas Hydrates Exploitation

The methodology of using CO2 to replace CH4 to recover the natural gas hydrates (NGHs) is supposed to avoid geological disasters. However, the reaction path of the CH4–CO2 replacement method is too complex to give satisfactory replacement efficiency. Therefore, this study proposed a thermochemical reaction system that used the heat and the nitrogen released by the thermochemical reactions to recover NGHs. The performance of the thermochemical reaction system (NaNO2 and NH4Cl) regarding heat generation and gas production under low temperature (4°C) conditions was evaluated, and the feasibility of exploiting NGHs with an optimized formula of the thermochemical reaction system was also evaluated in this study. First, the effects of three catalysts (HCl, H₃PO₄, and NH2SO3H) were investigated at the same reactant concentration and catalyst concentration. It was confirmed that HCl as a catalyst can obtain better heat generation and gas production. Second, the effect of HCl concentration on the reaction was investigated under the same reactant concentration. The results showed that the higher the HCl concentration, the faster is the reaction rate. When the concentration of HCl was greater than 14 wt%, side reactions would occur to produce toxic gas; hence, 14 wt% was the optimal catalyst concentration for the reaction of NaNO2 and NH4Cl at low temperatures. Third, the heat generation and gas production of the thermochemical reaction systems were evaluated at different reactant concentrations (1, 2, 3, 4, 5, and 6 mol/L) at 14 wt% HCl concentration. It was found that the best reactant concentration was 5 mol/L. Finally, the feasibility of exploiting NGHs with the optimal system was analyzed from the perspectives of thermal decomposition and nitrogen replacement. The thermochemical reaction system provided by this study is possible to be applied to explore NGHs’ offshore.

A Novel Approach for Near Wellbore Stimulation and Deposits Removal Utilizing Thermochemical Reaction

Organic and inorganic deposits play a major issue and concern in the wellbore of oil wells. This paper discusses the utilization of a new and novel approach utilizing a thermochemical recipe that shows a successful impact on both organic and inorganic deposits, as an elimination agent, and functions as stimulation fluid to improve the permeability of the near wellbore formation. The new recipe consists of mixing nitrite salt with sulfamic acid in the wellbore at the target zone. The product of this reaction includes heat, acidic salt, and nitrogen gas. The heat of the reaction is enough to liquefy the organic deposits, and the acidic salt will tackle the carbonate scale in the tube and will increase the permeability of the near wellbore area. The nitrogen gas is an inert gas; it will not affect the reaction and will help to flow back the well after the treatment. The experimental work shows an increment in the temperature by 65 °C when mixing the two chemicals. The test was conducted at room conditions and the temperature reached around 90 °C. Adding another 65 °C to the wellbore temperature is enough to melt asphaltene and wax, the acidic salt tackles carbonate scale. As a result, the mixture works on eliminating both the organic and inorganic deposits. The permeability of the limestone sample shows an increment of 65% when treated by the mixture of the reaction recipe. The uniqueness of the new thermochemical recipe is the potential of performing three objectives at the same time; the heat of the reaction removes the organic deposits in the wellbore, the acidic salt tackles carbonate scale, and improves the permeability of the near wellbore zone.

Development of the model and the method for determining the influence of the temperature of gunpowder gases in the gun barrel for explaining visualize of free carbon at shot

A phenomenon that is present in almost every shot is highlighted. It manifests itself in the muzzle discharge as a certain amount of free carbon. The thermochemical reaction of Boudouard-Bell (disproportionation of carbon monoxide) was determined, which explains the formation of free carbon in the gunpowder gases during the firing process. A feature of this reaction is the formation of a condensed phase of carbon during the firing process after the gasification of the gunpowder charge. The reason is revealed that does not allow describing the formation of free carbon during firing on the basis of existing models of internal ballistics processes. It is the lack of taking into account the temperature distribution of the gunpowder gases along the length of the gun barrel and its change. A mathematical model is proposed that makes it possible to estimate the temperature distribution during the shot. A method has been developed for solving the problem of internal ballistics with the ability to determine the temperature of gunpowder gases along the length of the gun barrel at different times and at different positions of the projectile in the barrel. The original model is built using generally accepted assumptions. Modeling results can only be estimated. For this reason, the method is based on simple calculations, which makes it possible not to involve high-power computing equipment. The modeling of the temperature distribution of gunpowder gases in the space of the gun barrel between the charging ball and the moving projectile in the model system is carried out. The possibility of changing the length of the zone of the Boudouard-Bell reaction (the zone of formation of free carbon) depending on the initial data is shown. The use of a fresh gunpowder charge and a degraded one is simulated. Full and reduced charges are considered. The simulation results showed the reason for the possibility of initiating a secondary muzzle discharge flash both from the front side and from the side of the muzzle brake.

Catalysis and degradation of phenol in coking wastewater during low-rank coal coke gasification

The thermochemical-reaction characteristics of different concentrations of phenol water and gasification-coke at 1000 °C in a thermochemical reactor were experimentally studied.

Ultrahigh photothermal temperature in a graphene/conducting polymer system enables contact thermochemical reaction

The ultrahigh photothermal temperatures, achieved in a graphene and conducting polymer system, can be used for various contact thermochemical reactions.