The efficacy of an adsorbent agnostic machine-learning surrogate model for rapid design and optimization of a Skarstrom cycle vacuum swing adsorption (VSA) process is experimentally validated. The surrogate model is trained to predict the process performance using adsorbent features that include hypothetical Langmuir adsorption isotherm parameters, particle density, porosity and bed voidage, and process variables such as pressure, step duration and feed velocity. The training data was generated from a detailed process model for 20,000 unique combinations of the training variables. The model shows high accuracy of R2adj>0.99 for predicting key performance parameters such as product purity, recovery and productivity. The ability of this surrogate to predict the experimental performance for the purification of O2 from the air on two adsorbents, namely 13X and LiX zeolites, was studied. Two separate multi-objective optimization studies, to maximize purity and recovery, and to maximize productivity and purity were performed. For these optimization studies, the volumetrically measured isotherms of N2 and O2 were used as inputs to the surrogate model. Note that these isotherms were not a part of the dataset used to train the model. Nine points were chosen from the Parteo curves and the corresponding decision variables were used as set-points in a two-column lab-scale rig. The average difference between the calculated and experimentally measured purity, recovery and productivity was 3%, 5% and 9%, respectively. This study provides the necessary confidence to use surrogate-based process models for adsorbent screening and adsorption process optimization.
Hydrogen Separation and Purification from Various Gas Mixtures by Means of Electrochemical Membrane Technology in the Temperature Range 100–160 °C
