Styrene-divinylbenzene polymer oxidation catalyst

1981 ◽  
Vol 46 (11) ◽  
pp. 2657-2662
Author(s):  
Zdeněk Prokop ◽  
Karel Setínek

Some additional data about properties and applicability of a styrene-divinylbenzene polymer catalyst containing acidic and redox functional groups are reported. It is shown that the catalysts of this type can be prepared reproducibly and exhibit catalytic properties comparable to the properties of noble metal catalysts.

1981 ◽  
Vol 46 (5) ◽  
pp. 1237-1247
Author(s):  
Zdeněk Prokop ◽  
Karel Setínek

The catalyst containing redox sites in addition to acid functional groups was prepared by sulphonation of a macroporous chloromethylated styrene-divinylbenzene copolymer with concentrated sulphuric acid at elevated temperatures. Its activity was tested for the oxidation of 2-propanol by molecular oxygen at 120 °C and was found to be comparable to that of the iridium on carbon catalyst.Neutralisation of acid functional groups by alkali metal led to proportional decrease in the oxidation activity. The results of EPR spectroscopic study of these catalysts show that the redox properties of the polymer are caused by carbon clusters which are capable of electron exchange.


2017 ◽  
Vol 60 (3) ◽  
pp. 137-145 ◽  
Author(s):  
Fumihiro Watanabe ◽  
Ikuko Kaburaki ◽  
Naohiro Shimoda ◽  
Akira Igarashi ◽  
Shigeo Satokawa

ChemInform ◽  
2010 ◽  
Vol 24 (27) ◽  
pp. no-no
Author(s):  
F. KAPTEIJN ◽  
S. STEGENGA ◽  
N. J. J. DEKKER ◽  
J. W. BIJSTERBOSCH ◽  
J. A. MOULIJN

2013 ◽  
Vol 52 (33) ◽  
pp. 11544-11551 ◽  
Author(s):  
Yuwei Bie ◽  
Andrea Gutierrez ◽  
Tuula R. Viljava ◽  
Jaana M. Kanervo ◽  
Juha Lehtonen

2017 ◽  
Vol 5 (39) ◽  
pp. 20789-20796 ◽  
Author(s):  
Mingwei Zhang ◽  
Guozhu Li ◽  
Xiaoqing Sun ◽  
Yujiao Jiang ◽  
Xiangwen Zhang

A joint experimental–theoretical study has been conducted to investigate the role of polydopamine as an interface facilitator for supported noble metal catalysts.


2019 ◽  
Vol 25 (20) ◽  
pp. 5113-5127 ◽  
Author(s):  
Jingjie Ge ◽  
Zhijun Li ◽  
Xun Hong ◽  
Yadong Li

2018 ◽  
Vol 3 (10) ◽  
pp. 2527-2532 ◽  
Author(s):  
Xu Lu ◽  
Yueshen Wu ◽  
Xiaolei Yuan ◽  
Ling Huang ◽  
Zishan Wu ◽  
...  

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