Nucleation rates of methane hydrate from water in oil emulsions

2015 ◽  
Vol 93 (8) ◽  
pp. 882-887 ◽  
Author(s):  
Andrey S. Stoporev ◽  
Andrey Yu. Manakov ◽  
Lubov’ K. Altunina ◽  
Larisa A. Strelets ◽  
Viktor I. Kosyakov
Keyword(s):  
Crude Oil ◽  
Methane Hydrate ◽  
Water Surface ◽  
Organic Liquid ◽  
Methane Diffusion ◽  
Oil Emulsions

Nucleation of methane hydrate from water emulsions in five different kinds of crude oil and in decane have been studied with the use of isothermal methods. The experiments were conducted at a temperature of –5 °C and pressure of 12 MPa. It is shown that the nucleation rates tend to decrease with the increase in the density of the organic liquid used to make the emulsion. It is most likely that the observed regularities are related to the rate of methane diffusion to water surface.

Demulsification of a Water-in-crude Oil Emulsion with a Corn Oil BasedDemulsifier using the Response Surface Methodology: Modelling and Optimization

2021 ◽  
Vol 14 ◽  
Author(s):  
Abed Saad ◽  
Nour Abdurahman ◽  
Rosli Mohd Yunus
Keyword(s):  
Response Surface Methodology ◽  
Crude Oil ◽  
Water Content ◽  
Response Surface ◽  
Separation Efficiency ◽  
Corn Oil ◽  
Oil Emulsion ◽  
Optimal Values ◽  
Input Variables ◽  
Oil Emulsions

: In this study, the Sany-glass test was used to evaluate the performance of a new surfactant prepared from corn oil as a demulsifier for crude oil emulsions. Central composite design (CCD), based on the response surface methodology (RSM), was used to investigate the effect of four variables, including demulsifier dosage, water content, temperature, and pH, on the efficiency of water removal from the emulsion. As well, analysis of variance was applied to examine the precision of the CCD mathematical model. The results indicate that demulsifier dose and emulsion pH are two significant parameters determining demulsification. The maximum separation efficiency of 96% was attained at an alkaline pH and with 3500 ppm demulsifier. According to the RSM analysis, the optimal values for the input variables are 40% water content, 3500 ppm demulsifier, 60 °C, and pH 8.

scholarly journals Visual Appearance of Oil on the Sea

2021 ◽  
Vol 9 (1) ◽  
pp. 97
Author(s):  
Merv Fingas
Keyword(s):  
Water Surface ◽  
Oil Spills ◽  
Discharge Rate ◽  
Physical Explanation ◽  
Visual Appearance ◽  
Oil In Water ◽  
Other Information ◽  
Surface Discharges ◽  
Oil Emulsions ◽  
Spilled Oil

The visual appearance of oil spills at sea is often used as an indicator of spilled oil properties, state and slick thickness. These appearances and the oil properties that are associated with them are reviewed in this paper. The appearance of oil spills is an estimator of thickness of thin oil slicks, thinner than a rainbow sheen (<3 µm). Rainbow sheens have a strong physical explanation. Thicker oil slicks (e.g., >3 µm) are not correlated with a given oil appearance. At one time, the appearance of surface discharges from ships was thought to be correlated with discharge rate and vessel speed; however, this approach is now known to be incorrect. Oil on the sea can sometimes form water-in-oil emulsions, dependent on the properties of the oil, and these are often reddish in color. These can be detected visually, providing useful information on the state of the oil. Oil-in-water emulsions can be seen as a coffee-colored cloud below the water surface. Other information gleaned from the oil appearance includes coverage and distribution on the surface.

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