Structural features influencing the activity of bis-biguanide ligands in the Suzuki–Miyaura cross-coupling reaction in neat water

2020 ◽  
Vol 98 (9) ◽  
pp. 547-553
Author(s):  
Solène Fortun ◽  
Philippe Beauclair ◽  
Andreea R. Schmitzer

Catalytic reactions play an integral role in the development of green chemistry. Herein, we report new bis-biguanide compounds containing alkyl and aryl spacers as ligands for the Suzuki–Miyaura cross-coupling reaction in water. These ligands show similar catalytic activity to metformin independently of the nature of the spacer between the two biguanide units.

RSC Advances ◽  
2015 ◽  
Vol 5 (95) ◽  
pp. 78026-78029 ◽  
Author(s):  
Young-O Kim ◽  
Hyung-Seok Jang ◽  
Yo-han Kim ◽  
Jae Myoung You ◽  
Yong-Sun Park ◽  
...  

​Flower-like palladium nanostructure (Pd nano-flower) induced by tyrosine-rich peptide, Tyr-Tyr-Ala-His-Ala-Tyr-Tyr (YYAHAYY), showed excellent catalytic activities in copper-free Sonogashira cross-coupling reaction in water.


2016 ◽  
Vol 1 (15) ◽  
pp. 4721-4725 ◽  
Author(s):  
Bhaskaran Savitha ◽  
Ayyiliath M. Sajith ◽  
Eeda Koti Reddy ◽  
C. S. Ananda Kumar ◽  
M. Syed Ali Padusha

2019 ◽  
Vol 1 (4) ◽  
pp. 1380-1386 ◽  
Author(s):  
Supriya Sasmal ◽  
Mintu Debnath ◽  
Sujay Kumar Nandi ◽  
Debasish Haldar

Urea modified tryptophan has been used as anin situreducing and stabilizing agent for the fabrication of gold nanoparticles and the gold nanoparticles efficiently catalyzed the Suzuki–Miyaura cross-coupling reaction in water.


ChemSusChem ◽  
2020 ◽  
Vol 13 (19) ◽  
pp. 5133-5133
Author(s):  
Valentin Lacanau ◽  
Françoise Bonneté ◽  
Patrick Wagner ◽  
Martine Schmitt ◽  
Daniel Meyer ◽  
...  

RSC Advances ◽  
2015 ◽  
Vol 5 (48) ◽  
pp. 38085-38092 ◽  
Author(s):  
Tahshina Begum ◽  
Manoj Mondal ◽  
Pradip K. Gogoi ◽  
Utpal Bora

A novel Pd@imine-SiO2 catalyst was prepared and found to exhibit excellent catalytic activity in a Suzuki-Miyaura cross-coupling reaction under aqueous media at room temperature.


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