Differential recovery of δ13C in multiple tissues of white sucker across age classes after the closure of a pulp mill

2014 ◽  
Vol 71 (5) ◽  
pp. 747-755 ◽  
Author(s):  
T.J. Arciszewski ◽  
A.J. Farwell ◽  
M.R. Servos ◽  
T.D. Jardine ◽  
K.R. Munkittrick

Techniques to document recovery after the closure of pulp mills that discharge enriching effluents are not well established, but δ13C may be a useful tool. In the 1990s, the muscle tissue of white sucker (Catostomus commersonii) collected downstream of two pulp and paper mills discharging into separate streams (Mattagami and Kapuskasing rivers) was enriched in 13C compared with upstream fish, suggesting uptake of pulp-derived C. The Mattagami River mill was closed in 2006, and analysis of muscle and gonad for δ13C was performed in 2011. As expected, fish captured in 2011 downstream of the operational Kapuskasing mill still showed the influence of the pulp-derived C in muscle and gonad tissue. After the closure of the Mattagami River mill, muscle tissue of white sucker was still enriched in 13C compared with upstream fish, while gonad tissue was not. The patterns observed in the Mattagami River were, however, related to age; the oldest fish showed enrichment of δ13C in both muscle and gonad tissue, suggesting the residual occurrence of pulp-derived C. This study suggests that measurements of stable isotopes in fish across a broad age range may indicate ecosystem improvements. These techniques may also be useful where no data prior to the upgrade or closure are available for comparison.

Cerâmica ◽  
2018 ◽  
Vol 64 (371) ◽  
pp. 443-453 ◽  
Author(s):  
L. Simão ◽  
D. Hotza ◽  
F. Raupp-Pereira ◽  
J. A. Labrincha ◽  
O. R. K. Montedo

Abstract The production of pulp and paper is increasing worldwide, and wastes are therefore being generated in appreciable amounts. Various materials are generated in pulp and paper mills, such as ash, dregs, grits, lime mud and pulp mill sludge. Over the years, these wastes have typically been sent to landfills or incinerated. However, with increased environmental awareness new alternatives have been investigated, especially the valorization of these materials. In this review, the characteristics of the manufacturing process, generated wastes, main destinations and recycling alternatives are addressed. The state of the art indicates that dregs are useful in agriculture as soil amendments, while lime mud can be used in agriculture and in environmental technology, mainly in wastewater treatment. Grits are commonly employed in construction, and pulp mill sludge shows applications in agriculture, construction and energy processes. In conclusion, this review shows several successful cases of recycling wastes from pulp and paper mills.


1999 ◽  
Vol 121 (3) ◽  
pp. 394-400 ◽  
Author(s):  
E. D. Larson ◽  
T. G. Kreutz ◽  
S. Consonni

Kraft pulp and paper mills generate large quantities of black liquor and byproduct biomass suitable for gasification. These fuels are used today for onsite cogeneration of heat and power in boiler/steam turbine systems. Gasification technologies under development would enable these fuels to be used in gas turbines. This paper reports results of detailed full-load performance modeling of pulp-mill cogeneration systems, based on gasifier/gas turbine technologies and, for comparison, on conventional steam-turbine cogeneration technologies. Pressurized, oxygen-blown black liquor gasification, the most advanced of proposed commercial black liquor gasifier designs, is considered, together with three alternative biomass gasifier designs under commercial development (high-pressure air-blown, low-pressure air-blown, and low-pressure indirectly-heated). Heavy-duty industrial gas turbines of the 70-MWe and 25-MWe class are included in the analysis. Results indicate that gasification-based cogeneration with biomass-derived fuels would transform a typical pulp mill into a significant power exporter and would also offer possibilities for net reductions in emissions of carbon dioxide relative to present practice.


Author(s):  
Eric D. Larson ◽  
Thomas G. Kreutz ◽  
Stefano Consonni

Kraft pulp and paper mills generate large quantities of black liquor and byproduct biomass suitable for gasification. These fuels are used today for onsite cogeneration of heat and power in boiler/steam turbine systems. Gasification technologies under development would enable these fuels to be used in gas turbines. This paper reports results of detailed full-load performance modeling of pulp-mill cogeneration systems based on gasifier/gas turbine technologies and, for comparison, on conventional steam-turbine cogeneration technologies. Pressurized, oxygen-blown black liquor gasification, the most advanced of proposed commercial black liquor gasifier designs, is considered, together with three alternative biomass gasifier designs under commercial development (high-pressure air-blown, low-pressure air-blown, and low-pressure indirectly-heated). Heavy-duty industrial gas turbines of the 70-MWe and 25-MWe class are included in the analysis. Results indicate that gasification-based cogeneration with biomass-derived fuels would transform a typical pulp mill into a significant power exporter and would also offer possibilities for net reductions in emissions of carbon dioxide relative to present practice.


1959 ◽  
Vol 37 (3) ◽  
pp. 339-343 ◽  
Author(s):  
D. Brewer

Physiological studies of six isolates of Phialophora fastigiata and two isolates of P. richardsiae from pulp mills have been made to determine conditions for growth. Isolates of P. fastigiata grew from at about 3 °C to 30–35 °C, with optimum conditions at 20 to 25 °C and pH 4 to 9. The temperatures for P. richardsiae were somewhat higher. No vitamins were required by P. fastigiata in a basal glucose mineral medium with ammonium tartrate. Ability to metabolize 11 carbohydrates as monosaccharides and oligosaccharides, but not D-arabinose, has been demonstrated. Likewise 16 sources of nitrogen as ammonia, nitrate, and various amino acids, but not cysteine, were utilized unequally. The differences between isolates of P. fastigiata from the same slime were as great as between isolates from different mills.


TAPPI Journal ◽  
2018 ◽  
Vol 17 (03) ◽  
pp. 167-178 ◽  
Author(s):  
Xin Tong ◽  
Jiao Li ◽  
Jun Ma ◽  
Xiaoquan Chen ◽  
Wenhao Shen

Studies were undertaken to evaluate gaseous pollutants in workplace air within pulp and paper mills and to consider the effectiveness of photo-catalytic treatment of this air. Ambient air at 30 sampling sites in five pulp and paper mills of southern China were sampled and analyzed. The results revealed that formaldehyde and various benzene-based molecules were the main gaseous pollutants at these five mills. A photo-catalytic reactor system with titanium dioxide (TiO2) was developed and evaluated for degradation of formaldehyde, benzene and their mixtures. The experimental results demonstrated that both formaldehyde and benzene in their pure forms could be completely photo-catalytic degraded, though the degradation of benzene was much more difficult than that for formaldehyde. Study of the photo-catalytic degradation kinetics revealed that the degradation rate of formaldehyde increased with initial concentration fitting a first-order kinetics reaction. In contrast, the degradation rate of benzene had no relationship with initial concentration and degradation did not conform to first-order kinetics. The photo-catalytic degradation of formaldehyde-benzene mixtures indicated that formaldehyde behaved differently than when treated in its pure form. The degradation time was two times longer and the kinetics did not reflect a first-order reaction. The degradation of benzene was similar in both pure form and when mixed with formaldehyde.


2012 ◽  
Vol 11 (1) ◽  
pp. 81-85 ◽  
Author(s):  
Dan Gavrilescu ◽  
Adrian Catalin Puitel ◽  
Gheorghe Dutuc ◽  
Grigore Craciun

1988 ◽  
Vol 20 (1) ◽  
pp. 37-48 ◽  
Author(s):  
L. Panneerselvam

In order to reduce the demand for the forest based raw materials by the organised industrial sectors like the large integrated pulp and paper mills, the Government of India started promoting several small-scale pulp and paper mills based on non-wood agricultural residue raw materials. However promotion of these small mills has created another environmental problem i.e. severe water pollution due to non-recovery of chemicals. Because of the typical characteristics like high silica content etc. of the black liquor produced and the subsequent high capital investment needed for a recovery system, it is not economically feasible for the small Indian mills to recover the chemicals. While the quantity of wastewater generated per tonne of paper produced by a small mill is same as from a large integrated pulp and paper mill with a chemical recovery system, their BOD load is four times higher, due to non recovery of chemicals. However the existing wastewater disposal standards are uniform for large and small mills for e.g. 30 mg BOD/l. To meet these standards, the small mills have to install a capital intensive wastewater treatment plant with heavy recurring operating costs. Therefore the feasible alternative is to implement various pollution abatement measures, with the objective of not only reducing the fibre/chemical loss but also to reduce the investment and operating costs of the final wastewater treatment system. To illustrate this approach, a case study on water pollution abatement and control in a 10 TPD mill, will be discussed.


1997 ◽  
Vol 35 (2-3) ◽  
pp. 101-108
Author(s):  
X. Wang ◽  
T. H. Mize ◽  
F. M. Saunders ◽  
S. A. Baker

Research is focused on an integrated way to simultaneously optimize the bleaching operations and subsequent wastewater treatment for pulp and paper mills. Bleach wastewaters from ClO2-bleached pulping studies at Institute of Paper Science and Technology (IPST) were used as the feed for batch reactors to test and rank the treatability and kinetics. The key aspect of the system is the use of sequential anaerobic/aerobic phases to enhance reductive dehalogenation of chloro-organic materials. Two continuous reactor systems, one operated in an anaerobic-aerobic mode and a second in an aerobic-aerobic mode, received bleaching wastewater obtained from a full-scale plant. Acclimated cultures from both continuous reactors were used to quantify the AOX (Adsorbable Organic Halide) and COD removal from various bleaching wastewaters. In general, the sequential anaerobic/aerobic treatment of bleach wastewater can improve both biotreatability and degradation rates.


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