Further immobile element data from altered volcanic rocks, Timmins mining area, Ontario

1980 ◽  
Vol 17 (3) ◽  
pp. 419-423 ◽  
Author(s):  
J. F. Da Vies ◽  
R. E. S. Whitehead
Keyword(s):  
Trace Elements ◽  
Trace Element ◽  
Volcanic Rocks ◽  
Mining Area ◽  
Trace Element Data ◽  
Element Data ◽  
Lithostratigraphic Units

The relatively immobile trace elements TiO2, Zr, and Y prove useful for determining the original identity of, and for correlating, metamorphosed and metasomatized Archean volcanic rocks. More than 95% of 366 samples from the Timmins area were found to correspond to the lithostratigraphic units determined independently from structural and stratigraphic decisions based on lithology and top determinations. Trace-element data can be used for distinguishing volcanic units and as an aid in correlation regardless of any petrogenetic interpretations.

Immobile trace elements and Archean volcanic stratigraphy in the Timmins mining area, Ontario

1979 ◽  
Vol 16 (2) ◽  
pp. 305-311 ◽  
Author(s):  
J. F. Davies ◽  
R. W. E. Grant ◽  
R. E. S. Whitehead
Keyword(s):  
Trace Elements ◽  
Trace Element ◽  
No Value ◽  
Volcanic Rocks ◽  
Mining Area ◽  
Stratigraphic Correlation ◽  
Trace Element Data ◽  
Volcanic Stratigraphy ◽  
Lithostratigraphic Units ◽  
Hydrolysis Of

Carbonate alteration and hydrolysis of mafic volcanic rocks in the Timmins area have been accompanied by mobilization and redistribution of alkalies, CaO, MgO, and FeO. These major oxides are of dubious value in classifying the volcanic rocks, and are of no value in identifying and correlating lithostratigraphic units. The trace elements Y, Zr, TiO2, and Cr, whose fractionation tendencies parallel those of the alkalies, FeO and MgO, are relatively immobile and display characteristic patterns within different volcanic units. The trace-element patterns are highly diagnostic, and their distribution corresponds to the distribution of lithostratigraphic units. Immobile trace-element data represent a potentially valuable tool in stratigraphic correlation of Archean volcanic rocks, whether altered or unaltered.

Geochemical contrasts between late Caledonian granitoid plutons of northern, central and southern Scotland

1984 ◽  
Vol 75 (2) ◽  
pp. 259-273 ◽  
Author(s):  
W. E. Stephens ◽  
A. N. Halliday
Keyword(s):  
Trace Elements ◽  
Trace Element ◽  
Incompatible Element ◽  
Geochemical Data ◽  
Wide Sense ◽  
Trace Element Data ◽  
Isotopic Data ◽  
Element Data ◽  
High K ◽  
Mantle Component

ABSTRACTNew major- and trace-element data for granitoid plutons from the Grampian Highlands, the Midland Valley and the Southern Uplands of Scotland are presented and discussed. The study is restricted to ‘late granitoids’ (all younger than 430 Ma); the term ‘granitoid’ is used in a wide sense to encompass all plutonic components of a zoned intrusion of this age, sometimes including diorites and ultrabasic cumulate rocks. The data indicate that as a whole the province is chemically high-K calc-alkalic. Other notable enrichments are in Sr and Ba, and a marked geographical difference in these trace-elements is found between plutons of the SW Grampian Highlands and those of the Southern Highlands, the Midland Valley, and the Southern Uplands. Plutons of the NE Highlands tend to be more geochemically evolved than those further SW and those of the Midland Valley and Southern Uplands.When petrographical and geochemical data are considered, three plutonic suites are recognised: (1) the Cairngorm suite comprising plutons of the NE Highlands, (2) the Argyll suite comprising plutons from the SW Highlands, and (3) the S of Scotland suite comprising plutons from the Southern Highlands, Midland Valley and the Southern Uplands excluding Criffell and the Cairnsmore of Fleet. It is proposed that the more acidic granitoids are dominantly the products of I-type crustal sources, but certain diorites and the more basic members of zoned plutons have a substantial mantle component. The elevated Sr and Ba levels in granitoids of the Argyll suite may reflect the influence of incompatible-element-rich fluids from the mantle in the petrogenesis of this suite. The relatively anhydrous pyroxene-mica diorites of the S of Scotland suite are richer in Ni and Cr and appear to represent mantle-derived melts. The relationships between these data and already published isotopic data are discussed.

A tephrochronologic method based on apatite trace-element chemistry

2011 ◽  
Vol 76 (1) ◽  
pp. 157-166 ◽  
Author(s):  
Bryan Keith Sell ◽  
Scott Douglas Samson
Keyword(s):  
Trace Element ◽  
Electron Microprobe ◽  
Glass Composition ◽  
Volcanic Rocks ◽  
Trace Element Data ◽  
Element Data ◽  
Element Concentrations ◽  
Ash Fall ◽  
Trace Element Chemistry ◽  
Stratigraphic Record

AbstractGeochemical correlation of ash-fall beds with conventional tephrochronologic methods is not feasible when original glass composition is altered. Thus, alternative correlation methods may be required. Initial studies of heavily altered Paleozoic tephra (K-bentonites) have suggested the potential for employing trace-element concentrations in apatite as ash-fall bed discriminators. To further test the utility of apatite trace-element tephrochronology, we analyzed apatite phenocrysts from unaltered volcanic rocks with an electron microprobe: nine samples from rocks erupted during the Quaternary and one sample from a rock erupted during the Paleogene. The resulting apatite trace-element data provide unique bed discriminators despite within-crystal variability. Each of the volcanic rocks studied possesses unique trends in Mg, Cl, Mn, Fe, Ce and Y concentrations in apatite. The results from this study establish an important tephrochronologic method that can be applied to nearly all portions of the Phanerozoic stratigraphic record and greatly assist development of an advanced timescale. In addition to establishing a fingerprint for a particular eruption, apatite chemistry provides useful information about the source magma.

Metabentonites in the Moffat Shale Group, Southern Uplands of Scotland: Geochemical evidence of ensialic marginal basin volcanism

1990 ◽  
Vol 127 (3) ◽  
pp. 259-271 ◽  
Author(s):  
R. J. Merriman ◽  
B. Roberts
Keyword(s):  
Trace Elements ◽  
Trace Element ◽  
Late Ordovician ◽  
Trace Element Data ◽  
Geochemical Evidence ◽  
Sialic Crust ◽  
Element Data ◽  
High Concentrations ◽  
Arc Setting ◽  
Back Arc

AbstractMetabentonites occur extensively in the Moffat Shale Group of the Southern Uplands of Scotland. At Dob's Linn 135 metabentonite beds, 1–50 cm thick, occur in Ashgill to Llandovery strata, representing an aggregate thickness of 6 m of compacted ash accumulated over approximately 25 Ma. The metabentonites are characterized by relatively high concentrations of trace elements, including Ba, Cs, Hf, Nb, Rb, Ta, Th, U, Y, Zr and REEs, which were inherited from evolved vitric ash. Immobile trace element data indicate that a spectrum of silicic ash compositions accumulated, ranging from subalkaline to mildly peralkaline. In the late Ordovician N. gracilis to G. persculptus biozones, subalkaline ash falls predominated, whereas peralkaline ash falls predominated in the Llandovery (Silurian) P. acuminatus to M. convolutes biozones, giving way to predominantly subalkaline ash falls during accumulation of the M. sedgwickii to R. maximus biozones. Changeovers in the dominant ash types are marked by increased proportions of ash. The magmas from which the ash types evolved were generated in an ensialic arc transitional to a back-arc setting, and involved attenuated sialic crust and mantle characterized by variable depletion in HFS elements. Lithological, petrological and REE characteristics suggest that the Moffat Shale Group is not exclusively pelagic in origin and probably accumulated in a back-arc basin bordering an ensialic arc terrane.

scholarly journals Petrogenesis of Magnesian High-K Granitoids From Bitkine (Centrechad Massif): Major and Trace Elements Constraints

2020 ◽  
Vol 1 (5) ◽  
Author(s):  
Mbaihoudou Diontar ◽  
Jean Claude Doumnang ◽  
Maurice Kwékam ◽  
Zagalo Al-hadj Hamid ◽  
Armand Kagou Dongmo ◽  
...  
Keyword(s):  
Trace Elements ◽  
Trace Element ◽  
Fractional Crystallization ◽  
Major And Trace Elements ◽  
Trace Element Data ◽  
Calc Alkaline ◽  
Element Data ◽  
High K ◽  
Microgranular Enclaves ◽  
Mantle Magma

Major and trace element data were used to constrain the nature and origin of the Bitkine gabbro-diorite magma.The gabbro-diorites of Bitkine within the Guéra Massif, and associated microgranular enclaves consist of plagioclase, k-feldspar, clinopyroxene, amphibole, biotite and quartz. Gabbro-diorites and enclaves are basic to intermediate rocks. They are high-K magnesian calc-alkaline with shoshonite affinity. ΣREE range from 132 to 436 ppm in gabbro-diorites, while they are from 134 to 207 ppm in enclaves. LREE are weakly enriched compared to HREE (La/Yb)N = (12.23 -41.40) and (6.20-31.86) respectively in gabbro-diorites and enclaves. These rocks show a weak negative anomaly in europium (Eu/Eu* = 0.78-1.07). They are rich in Ba and Sr, and show negative anomalies in Nb, Ta and Ti. The Nb/Ta, Rb/Cs and Ba/Nb ratios of the Bitkine gabbro-diorites and their enclaves indicate that they are derived from mantle magma modified by subducted fluids. This magma during its evolution by fractional crystallization was contaminated by crustal materials.

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