Rotational analysis of the BaI C2Π–X2Σ+ (0,0) band

1984 ◽  
Vol 62 (12) ◽  
pp. 1467-1477 ◽  
Author(s):  
Mark A. Johnson ◽  
Chifuru Noda ◽  
John S. McKillop ◽  
Richard N. Zare
Keyword(s):  
Significant Interaction ◽  
Molecular Beam ◽  
Band System ◽  
Spectroscopic Techniques ◽  
Spin Orbit ◽  
Rotational Analysis ◽  
Local Perturbations ◽  
State Spin ◽  
Laser Spectroscopic ◽  
Π State

Rotational analysis of the BaI C2Π–X2Σ+ (0,0) band system has been performed using molecular beam and laser spectroscopic techniques. This band is free from local perturbations, although significant interaction of the C2Π state with several other 2Σ+ states is indicated. The spin-orbit ordering of the C state is confirmed to be regular, while the Λ-doubling parameters p and q are opposite in sign. Apparent anomalies in the line strengths of various rotational branches in the two spin-orbit sub-bands are related to observed differences in the hyperfine structure of the C-state spin-orbit components.

Rotational analysis of four bands of the γ′(B3Π–X3Δ) system of TiO

1979 ◽  
Vol 57 (1) ◽  
pp. 54-68 ◽  
Author(s):  
William H. Hocking ◽  
M. C. L. Gerry ◽  
A. J. Merer
Keyword(s):  
Ground State ◽  
Spin Orbit ◽  
Rotational Analysis ◽  
Centrifugal Distortion ◽  
Molecular Constants ◽  
Full Matrix ◽  
Ground State Spin ◽  
State Spin ◽  
Distortion Parameters ◽  
Π State

The (0,0), (1,0), (0,1), and (1,1) bands of the γ′(B3Π–X3Δ) system of TiO have been rotationally analysed up to J = 55. Accurate molecular constants have been determined for the ν = 0and ν = 1 levels of the B3Π and X3Δ states. The three substates of the B3Π state all show significant Λ-type doubling, which has been analysed using a full matrix treatment. Our new results give corrected values for the ground state spin–orbit splittings; they also illustrate very clearly the problem of the correlation of the various centrifugal distortion parameters appearing in the Hamiltonian for a triplet electronic state.

ROTATIONAL ANALYSIS OF THE β BANDS OF PHOSPHORUS MONOXIDE

1959 ◽  
Vol 37 (2) ◽  
pp. 136-143 ◽  
Author(s):  
Nand Lal Singh
Keyword(s):  
Ground State ◽  
Band System ◽  
Electronic States ◽  
Rotational Analysis ◽  
Rotational Constants ◽  
Fine Structures ◽  
Π State

The fine structures of three of the β bands of PO which occur near 3200 Å have been analyzed. The analysis shows that the upper state of this band system is a 2Σ and not a 2Π state as previously believed. The rotational constants of both electronic states have been determined and it is found that the ground state constants, previously determined from the γ bands, are incorrect.

A study of the A2Π/B2Σ+ – X2Σ+ band systems of calcium monohydride (CaH) using a supersonic molecular beam source and laser-induced fluorescence detection

2004 ◽  
Vol 82 (6) ◽  
pp. 779-790 ◽  
Author(s):  
T C Steimle ◽  
Jamie Gengler ◽  
Jinhai Chen
Keyword(s):  
Molecular Beam ◽  
Band System ◽  
Energy Levels ◽  
Laser Induced Fluorescence ◽  
Effective Hamiltonian ◽  
Beam Source ◽  
Supersonic Molecular Beam ◽  
Laser Induced Fluorescence Detection ◽  
Local Perturbations ◽  
Beam Sample

The high-resolution laser-induced fluorescence spectrum of a molecular beam sample of calcium monohydride (CaH) in the region of the strongly overlapped (1,0) A2Π – X2Σ+ and (0,0) B2Σ+ –  X2Σ+ band systems near 630 nm and the (0,0) A2Π –  X2Σ+ band system near 690 nm have been recorded and analyzed. The spectral features exhibit a small splitting that is attributed to proton magnetic hyperfine interaction in the X2Σ+ (v = 0) state. The energy levels of the A2Π(v = 0) vibronic state were modeled using a traditional "effective" Hamiltonian approach, whereas those for the interacting A2Π(v = 1)/B2Σ+(v = 0) vibronic levels were modeled by augmenting the traditional effective Hamiltonian with terms to account for local perturbations. An interpretation of the field-free parameters is presented.Key words: calcium monohydride, molecular beam, fluorescence.

First rotational analysis of the A2Π-X2Π system of the P35Cl+ cation

1987 ◽  
Vol 65 (5) ◽  
pp. 980-983 ◽  
Author(s):  
John A. Coxon ◽  
Stavros Naxakis ◽  
Utpal K. Roychowdhury
Keyword(s):  
Least Squares ◽  
Band System ◽  
Coupling Constants ◽  
Orbit Coupling ◽  
Spin Orbit Coupling ◽  
Spin Orbit ◽  
Rotational Analysis ◽  
Entire Data

The visible A2Π → X2Π band system of PCl+ has been recorded photoelectrically with a resolution of 0.006 nm. Fourteen 2Π1/2–2Π1/2 and six 2Π3/2–2Π3/2 sub-bands of P35Cl+ in the ν′ = 0 and 1 progressions with 10 ≤ ν″ ≤ 20 have been rotationally analysed. The measured positions of 1214 lines have been fitted directly by least squares to obtain a set of reliable constants for the two states that reproduce the entire data. These constants include the first estimated spin–orbit coupling constants for both states. The reliability of these estimates is discussed. The equilibrium internuclear separations are re(X) = 0.1900 and re(A) = 0.2334 nm.

Analyse vibrationnelle et rotationnelle de la transition A2Σ+–X2Πi de la molécule 63Cu80Se

1976 ◽  
Vol 54 (16) ◽  
pp. 1664-1668 ◽  
Author(s):  
Y. Lefebvre ◽  
J. L. Bocquet
Keyword(s):  
Band System ◽  
High Dispersion ◽  
Rotational Analysis ◽  
Molecular Constants ◽  
Visible Band ◽  
Π State

High dispersion vibrational and rotational analysis of a 63Cu80Se visible band system has been performed.The presence of a splitting proportional to [Formula: see text] in each observed subsystem indicates that these bands arise from a transition from a 2Σ state (with γ-type doubling) to a 2Π state. This hypothesis allows us to derive specific molecular constants of these two states.

High-resolution studies of the Herzberg band system (C1Σ+ – A1Π]) in the 13C18O molecule

1988 ◽  
Vol 66 (11) ◽  
pp. 1012-1024 ◽  
Author(s):  
R. Kępa
Keyword(s):  
High Resolution ◽  
Band System ◽  
Rotational Analysis ◽  
Rotational Constants ◽  
Combined Analysis ◽  
Isotopic Molecule ◽  
Vibrational Constants ◽  
First Time ◽  
Π State

Seven bands ((0–0) – (0–6)) belonging to the Herzberg system of 13C18O have been recorded in emission using conventional photographic spectroscopy. For the first time, lines of this system have been recorded at high resolution and identified. After the rotational analysis of bands, the rotational constants of the C1Σ+ (ν = 0) and A1Π (ν = 0–6) states, as well as the vibrational constants of the A1Π state, have been determined. A combined analysis of the bands of the Herzberg and Ångström systems have made it possible to determine the constants of the B1Σ+ state more precisely. Numerous rotational perturbations observed in the A1Π state in this isotopic molecule have been analyzed.

Rotational analysis of the forbidden d3 Δi ← X1Σ+ absorption bands of carbon monoxide

1970 ◽  
Vol 48 (24) ◽  
pp. 3004-3015 ◽  
Author(s):  
G. Herzberg ◽  
T. J. Hugo ◽  
S. G. Tilford ◽  
J. D. Simmons
Keyword(s):  
Carbon Monoxide ◽  
High Resolution ◽  
Intensity Distribution ◽  
Vacuum Ultraviolet ◽  
Ultraviolet Region ◽  
Rotational Analysis ◽  
Absorption Bands ◽  
Local Perturbations ◽  
Vacuum Ultraviolet Region ◽  
Π State

The forbidden d3Δi–X1Σ+ transition of CO has been observed in absorption at high resolution in the vacuum ultraviolet region. The intensity distribution in the rotational structure of the observed bands is in conformity with the assumption that the transition occurs on account of the interaction between the d3Δ state and a 1Π state, presumably the A1Π state. Thirteen bands of the d–X system have been analyzed yielding more extensive rotational data for the d3Δi state than were previously known. A discussion of the local perturbations in the d state by the A1Π and a3Π states is included.

Spectrum of SO: Analysis of the B3Σ−–X3Σ− and A3 Π–X3Σ− band systems

1969 ◽  
Vol 47 (9) ◽  
pp. 979-994 ◽  
Author(s):  
R. Colin
Keyword(s):  
Absorption Spectrum ◽  
High Resolution ◽  
Microwave Discharge ◽  
Flash Photolysis ◽  
Band System ◽  
Rotational Analysis ◽  
Rotational Constants ◽  
Π State

The absorption spectrum of SO radicals produced by flash photolysis of a mixture of COS + O2 + Ar is investigated. A partial rotational analysis of the previously known bands of the B3Σ−–X3Σ− transition which lie in the region of 1900 to 2400 Å is presented, and the predissociations and perturbations of the B3Σ−state are discussed. A complex red-degraded band system near 2500 Å, previously observed in emission and attributed to SO2, is shown to be due to a 3Π–X3Σ− transition of the SO molecule. Effective rotational constants of the 3Π state are derived from the analysis of these bands photographed at high resolution. In order to obtain the vibrational numbering of the 3Π–X3Σ− bands, these were also photographed in emission from a microwave discharge through a mixture of S18O2 + S16O2. A general discussion of the currently known states of the SO molecule is given.

Rotational Analysis of the A2Π–X2Σ+ Band System of the BeCl Molecule

1972 ◽  
Vol 50 (2) ◽  
pp. 171-184 ◽  
Author(s):  
R. Colin ◽  
M. Carleer ◽  
F. Prevot
Keyword(s):  
High Resolution ◽  
Microwave Discharge ◽  
Band System ◽  
Opposite Sign ◽  
Electronic Configuration ◽  
Rotational Analysis ◽  
Molecular Constants ◽  
Π State

A rotational analysis has been performed on the 0–0, 1–1, 1–0, and 2–1 bands of the A2Π–X2Σ+ band system of the BeCl molecule photographed at high resolution in emission from a microwave discharge. The following principal molecular constants have been obtained.[Formula: see text]Inspection of the low J value lines shows that the A2Π state is a regular state derived from the electronic configuration σ2σ2π4π although the Λ-doubling constants p and q are of opposite sign.

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