The high-resolution infrared spectrum of cyanobutadiyne, HC5N: The ν7 band centered at 642 cm

1994 ◽  
Vol 72 (11-12) ◽  
pp. 1165-1178 ◽  
Author(s):  
Sybille Haas ◽  
Gisbert Winnewisser ◽  
Koichi M.T. Yamada
Keyword(s):  
High Resolution ◽  
Infrared Spectrum ◽  
Ftir Spectroscopy ◽  
Electric Discharge ◽  
Infrared Band ◽  
Millimetre Wave ◽  
Fundamental Band ◽  
Molecular Parameters ◽  
Wave Data ◽  
First Time

The ν7 infrared band of cyanobutadiyne (HC5N) was recorded for the first time with high resolution by FTIR spectroscopy using a sample produced by gas electric discharge. The fundamental band and the hot bands arising from the ν11 = and 2 states are identified. The molecular parameters, including the rotational and vibrational ℓ-type doubling constants, have been determined accurately by analyzing the spectra together with the available microwave and millimetre wave data. The intensity perturbation caused by the ℓ-type resonance in the (ν7,ν11) = (1,1) state has been clearly observed and discussed.

Infrared spectrum of the fundamental ν1 of deutero-isocyanic acid

1981 ◽  
Vol 59 (10) ◽  
pp. 1313-1326 ◽  
Author(s):  
D. A. Steiner ◽  
S. R. Polo ◽  
T. K. McCubbin Jr. ◽  
K. A. Wishah
Keyword(s):  
High Resolution ◽  
Infrared Spectrum ◽  
Isocyanic Acid ◽  
Centrifugal Distortion ◽  
Rotational Constants ◽  
Fundamental Band ◽  
Band Origin ◽  
Stretching Vibration ◽  
Centrifugal Distortion Constants ◽  
First Time

The ν1 fundamental band of DNCO has been observed for the first time under high resolution. The band origin for this deuterium–nitrogen stretching vibration is found to be at 2637.198 cm−1, rather distant from the previously reported value of 2634.9 cm−1. Eighteen subbands have been analyzed and term values for both ground and ν1 states with K up to 6 have been obtained. Effective rotational constants Bν and centrifugal distortion constants Dν and Hν have also been determined. Interaction is observed with the 2ν3 vibration which has a band origin around 2640 cm−1. Interesting perturbations are observed for the K = 0 and K = 4 levels of ν1.

Ground state molecular parameters of phosphine, PH3, from the simultaneous analysis of the high-resolution infrared, microwave and submillimeterwave spectra

1985 ◽  
Vol 50 (11) ◽  
pp. 2480-2492 ◽  
Author(s):  
Soňa Přádná ◽  
Dušan Papoušek ◽  
Jyrki Kauppinen ◽  
Sergei P. Belov ◽  
Andrei F. Krupnov ◽  
...  
Keyword(s):  
Fourier Transform ◽  
High Resolution ◽  
Ground State ◽  
Unitary Transformation ◽  
Point Of View ◽  
Acoustic Detection ◽  
Molecular Parameters ◽  
Microwave Spectrometer ◽  
Fourier Transform Spectra ◽  
First Time

Fourier transform spectra of the ν2 band of PH3 have been remeasured with 0.0045 cm-1 resolution. Ground state combination differences from these data have been fitted simultaneously with the microwave and submillimeterwave data to determine the ground state spectroscopical parameters of PH3 including the parameters of the Δk = ± 3n interactions. The correlation between the latter parameters has been discussed from the point of view of the existence of two equivalent effective rotational operators which are related by a unitary transformation. The ΔJ = 0, +1, ΔK = 0 (A1 ↔ A2, E ↔ E) rotational transitions in the ν2 and ν4 states have been measured for the first time by using a microwave spectrometer and a radiofrequency spectrometer with acoustic detection.

High-Resolution Fourier Transform Infrared Spectrum of the ν12 Fundamental Band of Ethylene (C2H4)

2000 ◽  
Vol 203 (2) ◽  
pp. 310-313 ◽  
Author(s):  
T.L. Tan ◽  
S.Y. Lau ◽  
P.P. Ong ◽  
K.L. Goh ◽  
H.H. Teo
Keyword(s):  
Fourier Transform ◽  
High Resolution ◽  
Infrared Spectrum ◽  
Fourier Transform Infrared ◽  
Fundamental Band

scholarly journals Integrated Band Intensities of Ethylene (C212H4) by Fourier Transform Infrared Spectroscopy

2012 ◽  
Vol 2012 ◽  
pp. 1-5 ◽  
Author(s):  
G. B. Lebron ◽  
T. L. Tan
Keyword(s):  
Fourier Transform ◽  
Infrared Spectroscopy ◽  
Ambient Temperature ◽  
Ftir Spectroscopy ◽  
Fourier Transform Infrared ◽  
Vapor Pressures ◽  
Infrared Band ◽  
Combination Bands ◽  
First Time ◽  
Absorbance Spectra

The integrated band intensities of ethylene (12C2H4) in the 640–3260 cm−1 region were determined by Fourier transform infrared (FTIR) spectroscopy. The infrared absorbance spectra of the ν7 and ν10, ν12, ν7+ν8, ν6+ν10, v11, and ν9 and ν2+ν12 bands of ethylene recorded at a resolution of 0.5 cm−1 were measured at an ambient temperature of 296 K at various vapor pressures ranging from 3×10−5 to 1×10−3 atm to obtain respective Beer-Lambert's law plots. The measured integrated band intensities in cm−1/cm atm were S(ν9andν2+ν12)=112.20±0.24, S(ν11)=55.35±0.14, S(ν12)=41.22±0.30, and S(ν7andν10)=328.66±16.55. In addition, the measured infrared band intensities of the ν7+ν8 and ν6+ν10 combination bands of ethylene are reported for the first time: S(ν7+ν8)=21.701±0.028 cm−1/cm atm and S(ν6+ν10)=2.568±0.025 cm−1/cm atm.

High-resolution infrared spectrum of chlorine dioxide: The ν1 fundamental band

1980 ◽  
Vol 83 (2) ◽  
pp. 373-390 ◽  
Author(s):  
Yoshiaki Hamada ◽  
Masamichi Tsuboi
Keyword(s):  
High Resolution ◽  
Infrared Spectrum ◽  
Chlorine Dioxide ◽  
Fundamental Band

High resolution FTIR spectroscopy of CH279BrF: Analysis of the ν8 fundamental band

2008 ◽  
Vol 251 (1-2) ◽  
pp. 123-128 ◽  
Author(s):  
A. Baldacci ◽  
P. Stoppa ◽  
S. Giorgianni ◽  
R. Wugt Larsen
Keyword(s):  
High Resolution ◽  
Ftir Spectroscopy ◽  
Fundamental Band

High-resolution infrared spectrum of hydrogen peroxide: The ν6 fundamental band

1986 ◽  
Vol 117 (1) ◽  
pp. 46-59 ◽  
Author(s):  
J.J. Hillman ◽  
D.E. Jennings ◽  
W.B. Olson ◽  
Aaron Goldman
Keyword(s):  
Hydrogen Peroxide ◽  
High Resolution ◽  
Infrared Spectrum ◽  
Fundamental Band

Revised molecular parameters for and from high resolution study of the infrared spectrum in the wavelength region

2008 ◽  
Vol 109 (15) ◽  
pp. 2491-2510 ◽  
Author(s):  
Jes Henningsen ◽  
Alain Barbe ◽  
Marie-Renée De Backer-Barilly
Keyword(s):  
High Resolution ◽  
Infrared Spectrum ◽  
Wavelength Region ◽  
Molecular Parameters ◽  
Resolution Study

High-Resolution Fourier Transform Infrared Spectrum of the ν5 Fundamental Band System of Cyanogen, NCCN

1993 ◽  
Vol 159 (2) ◽  
pp. 534-550 ◽  
Author(s):  
J.C. Grecu ◽  
B.P. Winnewisser ◽  
M. Winnewisser
Keyword(s):  
Fourier Transform ◽  
High Resolution ◽  
Infrared Spectrum ◽  
Band System ◽  
Fourier Transform Infrared ◽  
Fundamental Band

The far infrared spectrum of naphthalene characterized by high resolution synchrotron FTIR spectroscopy and anharmonic DFT calculations

2013 ◽  
Vol 15 (25) ◽  
pp. 10141 ◽  
Author(s):  
O. Pirali ◽  
M. Goubet ◽  
T. R. Huet ◽  
R. Georges ◽  
P. Soulard ◽  
...  
Keyword(s):  
High Resolution ◽  
Infrared Spectrum ◽  
Dft Calculations ◽  
Ftir Spectroscopy ◽  
Far Infrared
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