REARRANGEMENT STUDIES WITH C14: XV. ETHYL-2-C14 IODIDE FROM THE IRRADIATION OF ETHYL-1-C14 IODIDE WITH COBALT-60 GAMMA RAYS
Irradiation of ethyl-1-C14 iodide gave ethyl-2-C14 iodide with Gr of 0.27–0.28 for samples that were either deaerated or not deaerated. Addition of 1% by weight of iodine before irradiation decreased the extent of rearrangement to nearly zero. The occurrence of 1,2-hydrogen shifts in ethyl radicals outside of the spurs, which may be susceptible to scavenger action, is suggested as a possible path which would lead to the ethyl-2-C14 iodide.
1967 ◽
Vol 31
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pp. 469-471
1994 ◽
Vol 144
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pp. 635-639
Keyword(s):
1974 ◽
Vol 35
(C6)
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pp. C6-185-C6-192
1987 ◽
Vol 48
(C9)
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pp. C9-823-C9-826
1987 ◽
Vol 48
(C9)
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pp. C9-835-C9-837
1964 ◽
Vol 83
(5)
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pp. 3-34
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