H—N3 and CH3—N3 bond dissociation energies
Keyword(s):
The thermal emission of negative azide ions from a heated filament operating in gases of both HN3 and CH3N3 has been studied in a magnetron cell and the temperature variation of this current used to deduce the C—N bond dissociation energies in both molecules. Results indicate higher values than previous estimates. They are: D0(H—N3) = 90 ± 8 kcal/mole and D0(CH3—N3) = 88 ± 8 kcal/mole at 0°K.
1951 ◽
Vol 209
(1096)
◽
pp. 110-131
◽
1953 ◽
Vol 216
(1126)
◽
pp. 361-374
◽
1953 ◽
Vol 219
(1138)
◽
pp. 353-366
◽
1970 ◽
Vol 48
(17)
◽
pp. 2745-2754
◽
1951 ◽
Vol 209
(1096)
◽
pp. 97-110
◽
Keyword(s):
1952 ◽
Vol 214
(1117)
◽
pp. 273-280
◽
2017 ◽
Vol 417
◽
pp. 69-75
◽
Keyword(s):