Redox properties of 2,3,7,8-tetramethoxyselenanthrene: a charge-transfer donor

1977 ◽  
Vol 55 (5) ◽  
pp. 766-770 ◽  
Author(s):  
A. W. Addison ◽  
T. H. Li ◽  
L. Weiler
Keyword(s):  
Electron Spin Resonance ◽  
Charge Transfer ◽  
Redox Properties ◽  
Charge Transfer Complexes ◽  
Visible Absorption ◽  
Selenium Compound ◽  
Stable Species ◽  
Spin Resonance ◽  
Potential Applicability ◽  
A Charge

The redox properties of 2,3,7,8-tetramethoxyselenanthrene and 2,3,7,8-tetramethoxythianthrene have been studied in solution in order to compare their potential applicability as charge-transfer donors. The selenium compound is the weaker reductant, yielding a stable radical cation and a reactive dication, the former dimerizing in solution. Electron spin resonance and visible absorption spectra of the stable species were obtained. The 1:1 charge-transfer complexes of the above donors with tetracyanoquinodimethane are found to be insulators.

Conduction-electron spin resonance in Langmuir-Blodgett films of a charge-transfer complex

1994 ◽  
Vol 49 (15) ◽  
pp. 10806-10809 ◽  
Author(s):  
Keiichi Ikegami ◽  
Shin-ichi Kuroda ◽  
Takayoshi Nakamura ◽  
Gen Yunome ◽  
Mutsuyoshi Matsumoto ◽  
...  
Keyword(s):  
Electron Spin Resonance ◽  
Charge Transfer ◽  
Electron Spin ◽  
Conduction Electron ◽  
Charge Transfer Complex ◽  
Langmuir Blodgett ◽  
Spin Resonance ◽  
Langmuir Blodgett Films ◽  
A Charge
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