Gas-phase proton-transfer reactions of the hydronium ion at 298 K
1979 ◽
Vol 57
(12)
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pp. 1518-1523
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Keyword(s):
Rate constants measured with the flowing afterglow technique at 298 ± 2 K are reported for the proton-transfer reactions of H3O+ with CH2O, CH3CHO, (CH3)2CO, HCOOH, CH3COOH, HCOOCH3, CH3OH, C2H5OH, (CH3)2O, and CH2CO. Dissociative proton-transfer was observed only with CH3COOH. The rate constants are compared with the predictions of various theories for ion–molecule collisions. The protonation is discussed in terms of the energetics and mechanisms of various modes of dissociation.
Keyword(s):
1992 ◽
Vol 3
(6)
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pp. 624-630
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Keyword(s):
1981 ◽
Vol 59
(11)
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pp. 1615-1621
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Keyword(s):
2018 ◽
Vol 122
(43)
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pp. 9947-9955
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Keyword(s):
1995 ◽
Vol 6
(6)
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pp. 529-532
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Keyword(s):
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1989 ◽
Vol 85
(11)
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pp. 1813-1818
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Keyword(s):
2016 ◽
Vol 88
(24)
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pp. 12354-12362
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1991 ◽
Vol 94
(11)
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pp. 7164-7180
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Keyword(s):
1996 ◽
Vol 153
(1)
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pp. 37-48
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