Infrared absorption and resonance Raman scattering of photochromic triphenylformazans

1984 ◽  
Vol 62 (8) ◽  
pp. 1476-1476
Author(s):  
Hubert Langbein ◽  
Ulrich-Walter Grummt

not available




1983 ◽  
Vol 61 (5) ◽  
pp. 809-816 ◽  
Author(s):  
J. W. Lewis ◽  
C. Sandorfy

The infrared and resonance Raman spectra of the two long-lived forms of triphenylformazan and several of its derivatives have been examined. The spectra of unsymmetrically 15N-labelled derivatives suggest that two tautomers exist for each of the two forms. This observation is confirmed by the spectra of 1-(p-halophenyl)-3,5-diphenylformazans. The spectra of the non-chelate forms of these latter compounds demonstrate that the position of the tautomeric equilibrium is influenced by the electron-attracting ability of the para-halo-substituent. A comparison of the resonance Raman spectra of the two forms leads to the conclusion that excited state proton transfer is the initial photoevent in the photochromism of the triphenylformazans.



2021 ◽  
Vol 103 (4) ◽  
Author(s):  
Rafael N. Gontijo ◽  
Andreij Gadelha ◽  
Orlando J. Silveira ◽  
Ricardo W. Nunes ◽  
Marcos A. Pimenta ◽  
...  




2021 ◽  
Vol 330 ◽  
pp. 115433
Author(s):  
Cettina Bottari ◽  
Sara Catalini ◽  
Paolo Foggi ◽  
Ines Mancini ◽  
Andrea Mele ◽  
...  


1975 ◽  
Vol 14 (11) ◽  
pp. 2703 ◽  
Author(s):  
H. Rosen ◽  
P. Robrish ◽  
O. Chamberlain






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