A study of the Ca2+ – Arsenazo III system and its application to the spectrophotometric determination of free calcium in solution
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A two-wavelength method was applied to the determination of free, ionic calcium with Arsenazo III in solutions containing calcium-binding ligands. By this procedure impurities in the indicator can be corrected for, thereby allowing the use of commercial indicator preparations with purities as low as 80%. Only a 1:1 complex with a conditional log stability constant of 4.28 ± 0.13 at pH 4.6 and ionic strength 0.1 was found under the conditions studied. Key words: free metal ion determination, calcium ion speciation, spectrophotometry, arsenazo III, ion increment method for speciation.
2013 ◽
Vol 689
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pp. 276-283
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2008 ◽
Vol 26
(3)
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pp. 301-320
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2009 ◽
Vol 631
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pp. 129-141
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2005 ◽
Vol 528
(2)
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pp. 205-218
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2015 ◽
Vol 87
(12)
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pp. 6071-6078
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1987 ◽
Vol 19
(3-4)
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pp. 439-448
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1974 ◽
Vol 63
(3)
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pp. 374-388
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