scholarly journals Gradient dynamics model for drops spreading on polymer brushes

2020 ◽  
Vol 229 (10) ◽  
pp. 1819-1832 ◽  
Author(s):  
Uwe Thiele ◽  
Simon Hartmann
2017 ◽  
Vol 835 ◽  
pp. 540-574 ◽  
Author(s):  
André v. B. Lopes ◽  
Uwe Thiele ◽  
Andrew L. Hazel

We consider steady solutions of the Stokes equations for the flow of a film of fluid on the outer or inner surface of a cylinder that rotates with its axis perpendicular to the direction of gravity. We find that previously unobserved stable and unstable steady solutions coexist over an intermediate range of rotation rates for sufficiently high values of the Bond number (ratio of gravitational forces relative to surface tension). Furthermore, we compare the results of the Stokes calculations to the classic lubrication models of Pukhnachev (J. Appl. Mech. Tech. Phys., vol 18, 1977, pp. 344–351) and Reisfeld & Bankoff (J. Fluid Mech., vol. 236, 1992, pp. 167–196); an extended lubrication model of Benilov & O’Brien (Phys. Fluids, vol. 17, 2005, 052106) and Evans et al. (Phys. Fluids, vol. 16, 2004, pp. 2742–2756); and a new lubrication approximation formulated using gradient dynamics. We quantify the range of validity of each model and confirm that the gradient-dynamics model is most accurate over the widest range of parameters, but that the new steady solutions are not captured using any of the simplified models because they contain features that can only be described by the full Stokes equations.


1990 ◽  
Vol 51 (8) ◽  
pp. 701-707 ◽  
Author(s):  
D.F.K. Shim ◽  
M. E. Cates
Keyword(s):  

2002 ◽  
Vol 727 ◽  
Author(s):  
Denys Usov ◽  
Manfred Stamm ◽  
Sergiy Minko ◽  
Christian Froeck ◽  
Andreas Scholl ◽  
...  

AbstractWe investigated the interplay between different mechanisms of the lateral and vertical segregation in the synthesized via “grafting from” approach symmetric A/B (where A and B are poly(styrene-co-2,3,4,5,6-pentafluorostyrene) and poly(methylmethacrylate), respectively) polymer brushes upon exposure to different solvents. We used X-ray photoemission electron spectroscopy and microscopy (X-PEEM), AFM, water contact angle measurements, and oxygen plasma etching to study morphology of the brushes. The ripple morphology after toluene (nonselective solvent) revealed elongated lamellar-like domains of A and B polymers alternating across the surface. The dimple-A morphology consisting of round clusters of the polymer A was observed after acetone (selective solvent for B). The top layer was enriched with the polymer B showing that the brush underwent both the lateral and vertical phase segregation. A qualitative agreement with predictions of SCF theory was found.


Sign in / Sign up

Export Citation Format

Share Document